Stabilizing High-voltage Cathode Materials for Next-generation Li-ion Batteries

doi:10.1007/s40242-020-9103-8

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (1): 24-32.doi: 10.1007/s40242-020-9103-8

Stabilizing High-voltage Cathode Materials for Next-generation Li-ion Batteries

ZHU Xiaobo¹, Tobias Schulli^1,2, WANG Lianzhou¹

1. Nanomaterials Centre, School of Chemical Engineering and Australian Institute for Bioengineering and Nanotechnology, The University of Queensland, QLD 4072, Australia;
2. ESRF-The European Synchrotron, 38000 Grenoble, France

收稿日期:2019-12-20 修回日期:2020-01-02 出版日期:2020-02-01 发布日期:2020-01-03
通讯作者: WANG Lianzhou E-mail:l.wang@uq.edu.au
基金资助:
Supported by the Australian Research Council Discovery and Linkage Programs, Queensland-Chinese Academy of Sciences (Q-CAS) Collaborative Science Fund, and BAJC Grant.

Stabilizing High-voltage Cathode Materials for Next-generation Li-ion Batteries

ZHU Xiaobo¹, Tobias Schulli^1,2, WANG Lianzhou¹

1. Nanomaterials Centre, School of Chemical Engineering and Australian Institute for Bioengineering and Nanotechnology, The University of Queensland, QLD 4072, Australia;
2. ESRF-The European Synchrotron, 38000 Grenoble, France

Received:2019-12-20 Revised:2020-01-02 Online:2020-02-01 Published:2020-01-03
Contact: WANG Lianzhou E-mail:l.wang@uq.edu.au
Supported by:
Supported by the Australian Research Council Discovery and Linkage Programs, Queensland-Chinese Academy of Sciences (Q-CAS) Collaborative Science Fund, and BAJC Grant.

摘要/Abstract

摘要： The pressing demand for high-energy/power lithium-ion batteries requires the deployment of cathode materials with higher capacity and output voltage. Despite more than ten years of research, high-voltage cathode mate-rials, such as high-voltage layered oxides, spinel LiNi_0.5Mn_1.5O₄, and high-voltage polyanionic compounds still cannot be commercially viable due to the instabilities of standard electrolytes, cathode materials, and cathode electrolyte interphases under high-voltage operation. This paper summarizes the recent advances in addressing the surface and interface issues haunting the application of high-voltage cathode materials. The understanding of the limitations and advantages of different modification protocols will direct the future endeavours on advancing high-energy/power lithium-ion batteries.

关键词: High voltage, Cathode material, Surface engineering, Cathode electrolyte interphase, Cycling stability, Lithium ion battery

Abstract: The pressing demand for high-energy/power lithium-ion batteries requires the deployment of cathode materials with higher capacity and output voltage. Despite more than ten years of research, high-voltage cathode mate-rials, such as high-voltage layered oxides, spinel LiNi_0.5Mn_1.5O₄, and high-voltage polyanionic compounds still cannot be commercially viable due to the instabilities of standard electrolytes, cathode materials, and cathode electrolyte interphases under high-voltage operation. This paper summarizes the recent advances in addressing the surface and interface issues haunting the application of high-voltage cathode materials. The understanding of the limitations and advantages of different modification protocols will direct the future endeavours on advancing high-energy/power lithium-ion batteries.

Key words: High voltage, Cathode material, Surface engineering, Cathode electrolyte interphase, Cycling stability, Lithium ion battery

ZHU Xiaobo, Tobias Schulli, WANG Lianzhou. Stabilizing High-voltage Cathode Materials for Next-generation Li-ion Batteries[J]. 高等学校化学研究, 2020, 36(1): 24-32.

ZHU Xiaobo, Tobias Schulli, WANG Lianzhou. Stabilizing High-voltage Cathode Materials for Next-generation Li-ion Batteries[J]. Chemical Research in Chinese Universities, 2020, 36(1): 24-32.

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Stabilizing High-voltage Cathode Materials for Next-generation Li-ion Batteries

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