Carboxylate-induced Various Structures of Ni(Ⅱ) Complexes with Fluorescence Sensing and Bifunctional Electrochemical Properties

doi:10.1007/s40242-019-9015-7

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (4): 549-555.doi: 10.1007/s40242-019-9015-7

Carboxylate-induced Various Structures of Ni(Ⅱ) Complexes with Fluorescence Sensing and Bifunctional Electrochemical Properties

LU Xue, LIU Guocheng, WANG Xiang, LIN Hongyan, WANG Xiuli

Liaoning Province Silicon Materials Engineering Technology Research Centre, Department of Chemistry, Bohai University, Jinzhou 121013, P. R. China

收稿日期:2019-01-14 修回日期:2019-03-28 出版日期:2019-08-01 发布日期:2019-08-01
通讯作者: LIU Guocheng, WANG Xiuli E-mail:wangxiuli@bhu.edu.cn;lgch1004@sina.com
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21671025, 21471021, 21401010).

Carboxylate-induced Various Structures of Ni(Ⅱ) Complexes with Fluorescence Sensing and Bifunctional Electrochemical Properties

LU Xue, LIU Guocheng, WANG Xiang, LIN Hongyan, WANG Xiuli

Liaoning Province Silicon Materials Engineering Technology Research Centre, Department of Chemistry, Bohai University, Jinzhou 121013, P. R. China

Received:2019-01-14 Revised:2019-03-28 Online:2019-08-01 Published:2019-08-01
Contact: LIU Guocheng, WANG Xiuli E-mail:wangxiuli@bhu.edu.cn;lgch1004@sina.com
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21671025, 21471021, 21401010).

摘要/Abstract

摘要： We synthesized three new Ni(Ⅱ) coordination polymers[Ni(L)(HIP)(H₂O)₂]·H₂O(CP1),[Ni(L)(NIP)]·2H₂O(CP2) and[Ni(L)(NDC)(H₂O)₂](CP3)[L=N,N'-bis(pyridine-3-yl)thiophene-2,5-dicarboxamide, H₂HIP=5-hydroxyisophthalic acid, H₂NIP=5-nitroisophthalic acid, H₂NDC=2,6-naphthalenedicarboxylic acid] by hydrothermal method, which were characterized by means of infrared spectra(IR), TG analyses, PXRD and single-crystal X-ray diffraction. The CP1 is a 1D tubular structure based on[Ni-HIP]₂ loops and pairs of L ligands. CP2 is a 2D 3,5-connected architecture, which consists of Ni-L linear chains and (Ni-NIP)₂ double chains. CP3 is a 2D network, which features 4-connected topology. Solid-state luminescent behaviours of CP1-CP3 were investigated. The CP1 can detect Fe³⁺ ions through luminescence quenching. The electrochemical properties of CP1 buk-modified carbon paste electrode(CP1-CPE) has also been investigated, which has bifunctional electrocatalytic activity for oxidation of ascorbic acid and reduction of NO₂^-.

关键词: Carboxylate-induced, Coordination polymer, Fluorescent recognition, Bifunctional electrocatalysis

Abstract: We synthesized three new Ni(Ⅱ) coordination polymers[Ni(L)(HIP)(H₂O)₂]·H₂O(CP1),[Ni(L)(NIP)]·2H₂O(CP2) and[Ni(L)(NDC)(H₂O)₂](CP3)[L=N,N'-bis(pyridine-3-yl)thiophene-2,5-dicarboxamide, H₂HIP=5-hydroxyisophthalic acid, H₂NIP=5-nitroisophthalic acid, H₂NDC=2,6-naphthalenedicarboxylic acid] by hydrothermal method, which were characterized by means of infrared spectra(IR), TG analyses, PXRD and single-crystal X-ray diffraction. The CP1 is a 1D tubular structure based on[Ni-HIP]₂ loops and pairs of L ligands. CP2 is a 2D 3,5-connected architecture, which consists of Ni-L linear chains and (Ni-NIP)₂ double chains. CP3 is a 2D network, which features 4-connected topology. Solid-state luminescent behaviours of CP1-CP3 were investigated. The CP1 can detect Fe³⁺ ions through luminescence quenching. The electrochemical properties of CP1 buk-modified carbon paste electrode(CP1-CPE) has also been investigated, which has bifunctional electrocatalytic activity for oxidation of ascorbic acid and reduction of NO₂^-.

Key words: Carboxylate-induced, Coordination polymer, Fluorescent recognition, Bifunctional electrocatalysis

LU Xue, LIU Guocheng, WANG Xiang, LIN Hongyan, WANG Xiuli. Carboxylate-induced Various Structures of Ni(Ⅱ) Complexes with Fluorescence Sensing and Bifunctional Electrochemical Properties[J]. 高等学校化学研究, 2019, 35(4): 549-555.

参考文献 42

[1]	Liu X. F., Theil E. C., Acc. Chem. Res., 2005, 38(3), 167
[2]	Liu J. Q., Li G. P., Liu W. C., Liu W. C., Li Q. L., Li B. H., Robert W. G., Hou L., Batten S. R., ChemPlusChem., 2016, 81(12), 1299
[3]	Yan W., Zhang C., Chen S. G., Han L. J., Zheng H. G., ACS Appl. Mater. Inter., 2017, 9(2), 1629
[4]	Dang S., Ma E., Sun Z. M., Zhang H. J., J. Mater. Chem., 2012, 22(33), 16920
[5]	Hider R. C., Kong X. L., Dalton Trans., 2013, 42(9), 3220
[6]	Carter K. P., Young A. M., Palmer A. E., Chem. Rev., 2014, 114(8), 4564
[7]	Wang X. L., Xiong Y., Sha X. T., Liu G. C., Lin H. Y., Cryst. Growth Des., 2017, 17(2), 483
[8]	Kitagawa S., Kitaura R., Noro S., Angew. Chem. Int. Ed., 2004, 43(18), 2334
[9]	Liu Q., Yu L., Wang Y., Ji Y. Z., Horvat J., Cheng M. L., Jia X. Y., Wang G. X., Inorg. Chem., 2013, 52(6), 2817
[10]	Kreno L. E., Leong K., Farha O. K., Allendorf M., van Duyne R. P., Hupp J. T., Chem. Rev., 2012, 112(2), 1105
[11]	Horcajada P., Serre C., Maurin G., Ramsahye N. A., Balas, F., Vallet-Regí M., Sebban M., Francis T., Gérard F., J. Am. Chem. Soc., 2008, 130(21), 6774
[12]	Chen B. L., Xiang S. C., Qian G. D. Acc. Chem. Res., 2010, 43(8), 1115
[13]	Qiao Y., Ma Y. F., Jiang W., Wang X. Y., Guan W. S., Che G. B., Li W. K., Qin F., CrystEngComm., 2018, 20(48), 7782
[14]	Chand S., Pal A., Pal S. C., Das M. C., Eur. J. Inorg. Chem., 2018, 2018(24), 2785
[15]	Mahesh K., Karpagam S., Sens. Actuators B:Chem., 2017, 251, 9
[16]	Rao P. C., Mandal S., Inorg. Chem., 2018, 57(19), 11855
[17]	Li Z., Li R., Li X. Chem. J. Chinese Universities, 2018, 39(11), 2363
[18]	Zhang D. C., Xu Q. W., Li X., Chem. J. Chinese Universities, 2018, 39(12), 2611
[19]	Lee C. H., Huang H. Y., Liu Y. H., Luo T. T., Lee G. H., Peng S. M., Jiang J. C., Chao I., Lu K. L., Inorg. Chem., 2013, 52(7), 3962
[20]	Park M. K., Lim K. S., Park J. H., Song J. H., Kang D. W., Lee W. R., Hong C. S., CrystEngComm., 2016, 18(23), 4349
[21]	Wang X. L., Wu X. M., Liu G. C., Lin H. Y., Wang X., RSC Adv., 2016, 6(88), 85030
[22]	Wang X. L., Chen N. L., Liu G. C., Tian A. X., Sha X. T., Ma K. F., Inorg. Chim. Acta, 2015, 432, 128
[23]	Wang X. L., Wu X. M., Liu G. C., Li Q. M., Lin H. Y., Wang X., J. Solid State Chem., 2017, 249, 51
[24]	Mu Y. J., Zhao Y. F., Xu H., Hou H. W., Fan Y. T., J. Mol. Struct., 2009, 935(1), 144
[25]	Sarkar M., Biradha K., Cryst. Growth Des., 2006, 6(1), 202
[26]	Sheldrick G. M., Acta Crystallogr., Sect. A:Found. Crystallogr., 2008, 64, 112
[27]	Sheldrick G. M., Acta Crystallogr., Sect. A:Found. Crystallogr., 2015, 71, 3
[28]	Dolensky B., Konvalinka R., Jakubek M., Kral V., J. Mol. Struct., 2013, 124, 1035
[29]	Hipler F., Fischer R. A., Müller J., J. Chem. Soc. Perkin Trans., 2002, 2(2), 1620
[30]	Bellamy L. J., The Infrared Spectra of Complex Molecules, Wiley, New York, 1958
[31]	Zhao Y., Wang L., Fan N. N., Han M. L., Yang G. P., Ma L. F., Cryst. Growth Des., 2018, 18(11), 7114
[32]	Heine J., Müller-Buschbaum K., Chem. Soc. Rev., 2013, 42(24), 9232
[33]	Cui Y. J., Yue Y. F., Qian G. D., Chen B. L., Chem. Rev., 2012, 112(2), 1126
[34]	Zou J. P., Peng Q., Wen Z. H., Zeng G. S., Xing Q. J., Guo G. C., Cryst. Growth Des., 2010, 10(6), 2613
[35]	Gong Y., Wu T., Lin J. H., CrystEngComm., 2012, 14(10), 3727
[36]	Jana A. K., Natarajan S., ChemPlusChem., 2017, 82(8), 1153
[37]	Staderini S., Tuci G., D'Angelantonio M., Manoli F., Manet I., Giambastiani G., Rossin A., Chemistry Select., 2016, 6(1), 1123
[38]	Wang X. L., Ying X., Liu G. C., Lin H. Y., Wang X., Dalton Trans., 2018, 47(29), 9903
[39]	Singh A. K., Mukherjee R., Dalton Trans., 2005, (17), 2886
[40]	Pandey S., Das P. P., Singh A. K., Mukherjee R., Dalton Trans., 2011, 40(40), 10758
[41]	Zhang L., Dong S., J. Electroanal. Chem., 2004, 568, 189
[42]	Lin H. Y., Wang X. L., Hu H. L., Chen B. K., Liu G. C., Solid State Sciences, 2009, 11(3), 643

Carboxylate-induced Various Structures of Ni(Ⅱ) Complexes with Fluorescence Sensing and Bifunctional Electrochemical Properties

Carboxylate-induced Various Structures of Ni(Ⅱ) Complexes with Fluorescence Sensing and Bifunctional Electrochemical Properties

可视化

摘要/Abstract

引用本文

使用本文

参考文献 42

相关文章 15

编辑推荐

Metrics

本文评价

[1]	WANG Yue, WANG Jinling, MA Jianxin, ZHANG Yue, XU Na, WANG Xiuli. Multi-functional Photoelectric Sensor Based on a Three-fold Interpenetrated Cd(II) Coordination Polymer for Sensitively Detecting Different Ions[J]. 高等学校化学研究, 2022, 38(4): 1105-1110.
[2]	HUA Chen, YI Pin, LIU Wencong, WANG Mengfan, NIU Zheng, LANG Jianping. Coordination Polymers with Bipyridyl Diene and Triene Ligands: Synthesis, Structures and Luminescent Properties[J]. 高等学校化学研究, 2022, 38(1): 209-216.
[3]	FU Pengyan, MO Junting, SUN Sisi, YIN Shaoyun, WANG Haiping, PAN Mei. Acid-base Vapor Sensing Enabled by ESIPT-attributed Cd(II) Coordination Polymer with Switchable Luminescence[J]. 高等学校化学研究, 2020, 36(5): 755-759.
[4]	QIAN Binbin, CHANG Ze, BU Xian-He. Zinc-coordination Polymers Based on a Donor-acceptor Mix-ligand System: Syntheses, Crystal Structures and Photophysical Properties[J]. 高等学校化学研究, 2020, 36(1): 74-80.
[5]	ZHONG Liangxuan, LIU Mingyue, ZHANG Bowei, SUN Yaqiu, XU Yanyan. Syntheses, Crystal Structures, Magnetic and Near-infrared Luminescence Properties of 3d-4f Coordination Polymers Cu₂Pr₂, Cu₂Eu₂ and Cu₄Tb₂[J]. 高等学校化学研究, 2019, 35(4): 693-699.
[6]	KANG Dawei, XIE Jingjing, LIU Yingying, MA Jianfang. Four Coordination Polymers Assembled with a New Biscarboxyl-functionalized Schiff Base Ligand[J]. 高等学校化学研究, 2018, 34(5): 839-843.
[7]	ZHANG Qingfen, ZHOU Zhongyuan, WANG Xuan, LU Jing. Syntheses, Structures and Magnetic Properties of Two Coordination Polymers Based on 2, 2-Biphenyldicarboxylate Ligand[J]. 高等学校化学研究, 2016, 32(2): 165-171.
[8]	ZHENG Tianxing, HAN Yide, LIU Ningning. A Cobalt Supramolecular Compound Constructed from 4, 6-Di(1-imidazolyl)-1, 3, 5-triazine-2-one: Synthesis, Characterization and Magnetic Property[J]. 高等学校化学研究, 2016, 32(2): 184-187.
[9]	WANG Jing, LUO Xiaolong, YUAN Yang, ZHANG Lirong. Assembly of Two Coordination Polymers Based on 2,2'-Bipyridyl-4,4'-dicarboxylic Acid Ligand[J]. 高等学校化学研究, 2015, 31(4): 503-507.
[10]	XU Jingyao, ZHANG Lei, SHAO Xueman, PAN Chengling, XU Jiqing. Structure and Fluorescence Property of a Two-fold Interpenetrated Three-dimensional Zn(II) Complex Constructed by Terephthalate and 1,3-Dipyridyl Benzene[J]. 高等学校化学研究, 2015, 31(3): 328-331.
[11]	TIAN Ruijing, WANG Fuxiang, DU Chunyu, FENG Lijuan, LIU Ying, ZHANG Cailing, PAN Qinhe. Template-directed Synthesis of Three Metal Oxalates via 4-Connected Building Units[J]. 高等学校化学研究, 2014, 30(6): 889-893.
[12]	LUO Yanan, XU Xianzhu, SUN Fuxing, YU Xiaoyang, ZHANG Xiao, ZHANG Ting, YU Liying. Synthesis, Structure and Properties of Two New Coordination Polymers Based on 4-[(8-Hydroxy-5-quinolinyl)azo]-benzenesulfonic Acid[J]. 高等学校化学研究, 2014, 30(1): 27-31.
[13]	QU Xue-jian, WANG Shuang, ZHANG Dao-jun, JING Xue-min, ZHANG Li-rong, LI Guang-hua, HUO Qi-sheng, LIU Yun-ling . Temperature-controlled Hydrothermal Synthesis of Copper(I or II) Coordination Polymers via a Variety of Copper Coordination Modes[J]. 高等学校化学研究, 2012, 28(4): 581-584.
[14]	WU Li-li, HE Rong, WEI Zhen and SONG Hui-hua*. Syntheses, Structures, and Properties of Five Coordination Polymers Involving Phthalic Acid[J]. 高等学校化学研究, 2011, 27(5): 724-729.
[15]	WANG Jing*, LIU Zhao-qing and SU Ting-ting. Synthesis, Structure and Luminescent Property of a Zinc(II) Coordination Polymer Incorporating Flexible Cyclohexane-1,2,3,4,5,6-hexacarboxylate Ligand[J]. 高等学校化学研究, 2011, 27(3): 354-357.