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高等学校化学研究 ›› 2018, Vol. 34 ›› Issue (5): 723-726.doi: 10.1007/s40242-018-8004-6

• Articles • 上一篇    下一篇

(3,3)-Connected Three-dimentional Supramolecular Metal Organic Polyhedral Based on Nanometresized Ligand with Magnetism Properties

ZHOU Xiaojing, LIU Lili, TAI Xishi, ZHANG Hui   

  1. College of Chemical & Chemical Engineering and Enviromental Engineering, Weifang University, Weifang 261061, P. R. China
  • 收稿日期:2018-01-05 修回日期:2018-04-16 出版日期:2018-10-01 发布日期:2018-05-28
  • 通讯作者: ZHOU Xiaojing,Email:zhouxiaojing105@wfu.edu.cn;TAI Xishi,Email:taixs@wfu.edu.cn E-mail:zhouxiaojing105@wfu.edu.cn;taixs@wfu.edu.cn
  • 基金资助:
    Supported by the Weifang Science and Technology Development Plan, China(No.2014GX030), the Research Fund for the Doctoral Program of Weifang University, China(No.2016BS06) and the Natural Science Foundation of Shandong Province of China(No.ZR2017MB056).

(3,3)-Connected Three-dimentional Supramolecular Metal Organic Polyhedral Based on Nanometresized Ligand with Magnetism Properties

ZHOU Xiaojing, LIU Lili, TAI Xishi, ZHANG Hui   

  1. College of Chemical & Chemical Engineering and Enviromental Engineering, Weifang University, Weifang 261061, P. R. China
  • Received:2018-01-05 Revised:2018-04-16 Online:2018-10-01 Published:2018-05-28
  • Contact: ZHOU Xiaojing,Email:zhouxiaojing105@wfu.edu.cn;TAI Xishi,Email:taixs@wfu.edu.cn E-mail:zhouxiaojing105@wfu.edu.cn;taixs@wfu.edu.cn
  • Supported by:
    Supported by the Weifang Science and Technology Development Plan, China(No.2014GX030), the Research Fund for the Doctoral Program of Weifang University, China(No.2016BS06) and the Natural Science Foundation of Shandong Province of China(No.ZR2017MB056).

摘要： A three-dimentinal metal organic framework[Co2(L)Cl(DMF)2(H2O)](DMF)3(H2O)3 based on the nanometresized ligand 4,4',4"-[1,3,5-benzenetriyltris(carbonylimino)]trisbenzoic acid was synthesized, and characterized by means of single-crystal X-ray diffraction, elemental analysis, infrared spectroscopy, thermogravimetry analysis and magnetism. This obtained structure can be considered to be constructed from 2D layer, which displays the topology of hbc based on Co2(COO)3 secondary building unit, and further to be linked into a 3D supramolecular architecture by N-H…O hydrogen bonds. The magnetism of the complex was carried out, which shows ferromagnetic exchange interactions.

关键词: Co complex, C3-Symmetric ligand, Ferromagnetic

Abstract: A three-dimentinal metal organic framework[Co2(L)Cl(DMF)2(H2O)](DMF)3(H2O)3 based on the nanometresized ligand 4,4',4"-[1,3,5-benzenetriyltris(carbonylimino)]trisbenzoic acid was synthesized, and characterized by means of single-crystal X-ray diffraction, elemental analysis, infrared spectroscopy, thermogravimetry analysis and magnetism. This obtained structure can be considered to be constructed from 2D layer, which displays the topology of hbc based on Co2(COO)3 secondary building unit, and further to be linked into a 3D supramolecular architecture by N-H…O hydrogen bonds. The magnetism of the complex was carried out, which shows ferromagnetic exchange interactions.

Key words: Co complex, C3-Symmetric ligand, Ferromagnetic