Porous Organic Frameworks-derived Porous Carbons with Outstanding Gas Adsorption Performance

doi:10.1007/s40242-018-8014-4

高等学校化学研究 ›› 2018, Vol. 34 ›› Issue (3): 338-343.doi: 10.1007/s40242-018-8014-4

Porous Organic Frameworks-derived Porous Carbons with Outstanding Gas Adsorption Performance

YAN Tingting, XING Guolong, DAS Saikat, BEN Teng, QIU Shilun

College of Chemistry, Jilin University, Changchun 130012, P. R. China

收稿日期:2018-01-15 修回日期:2018-03-09 出版日期:2018-06-01 发布日期:2018-04-10
通讯作者: BEN Teng E-mail:tben@jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21390394, 21471065) and the "111" Project of China (No.B07016).

Porous Organic Frameworks-derived Porous Carbons with Outstanding Gas Adsorption Performance

YAN Tingting, XING Guolong, DAS Saikat, BEN Teng, QIU Shilun

College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2018-01-15 Revised:2018-03-09 Online:2018-06-01 Published:2018-04-10
Contact: BEN Teng E-mail:tben@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21390394, 21471065) and the "111" Project of China (No.B07016).

摘要/Abstract

摘要： A series of porous carbon materials was synthesized via high temperature pyrolysis from well-defined and thermally stable precursors, namely porous organic frameworks(POFs), in inert atmosphere. The porous carbon materials showed enhanced gas adsorption capacities together with increased heat of adsorption and stronger affinity between the frameworks and the gases as compared to the precursor materials. To exemplify, sample C-POF-TBBP-1000 with a high BET surface area of 1290 m²/g can adsorb 2.8 mmol/g CH₄(273 K, 101.325 kPa), 5.4 mmol/g CO₂(273 K, 101.325 kPa) and 2.2% H₂(mass fraction, 77 K, 101.325 kPa), thereby surpassing most other porous adsorbent materials reported till date. The study highlights the potential of porous carbons derived from novel porous organic framework structures for gas adsorption applications.

关键词: Porous organic framework, Gas adsorption, Pyrolysis, Porous carbon

Abstract: A series of porous carbon materials was synthesized via high temperature pyrolysis from well-defined and thermally stable precursors, namely porous organic frameworks(POFs), in inert atmosphere. The porous carbon materials showed enhanced gas adsorption capacities together with increased heat of adsorption and stronger affinity between the frameworks and the gases as compared to the precursor materials. To exemplify, sample C-POF-TBBP-1000 with a high BET surface area of 1290 m²/g can adsorb 2.8 mmol/g CH₄(273 K, 101.325 kPa), 5.4 mmol/g CO₂(273 K, 101.325 kPa) and 2.2% H₂(mass fraction, 77 K, 101.325 kPa), thereby surpassing most other porous adsorbent materials reported till date. The study highlights the potential of porous carbons derived from novel porous organic framework structures for gas adsorption applications.

Key words: Porous organic framework, Gas adsorption, Pyrolysis, Porous carbon

YAN Tingting, XING Guolong, DAS Saikat, BEN Teng, QIU Shilun. Porous Organic Frameworks-derived Porous Carbons with Outstanding Gas Adsorption Performance[J]. 高等学校化学研究, 2018, 34(3): 338-343.

YAN Tingting, XING Guolong, DAS Saikat, BEN Teng, QIU Shilun. Porous Organic Frameworks-derived Porous Carbons with Outstanding Gas Adsorption Performance[J]. Chemical Research in Chinese Universities, 2018, 34(3): 338-343.

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Porous Organic Frameworks-derived Porous Carbons with Outstanding Gas Adsorption Performance

Porous Organic Frameworks-derived Porous Carbons with Outstanding Gas Adsorption Performance

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