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高等学校化学研究 ›› 2015, Vol. 31 ›› Issue (6): 1046-1050.doi: 10.1007/s40242-015-5341-6

• Articles • 上一篇    下一篇

Characterization of UV-curable Poly(ethylene glycol) Diacrylate Based Hydrogels

QIN Xuzhen, HU Qianqian, GAO Guanghui, GUAN Shuang   

  1. School of Chemistry and Life Science, Advanced Institute of Materials Science, Changchun University of Technology, Changchun 130012, P. R. China
  • 收稿日期:2015-08-25 修回日期:2015-09-28 出版日期:2015-11-01 发布日期:2015-11-02
  • 通讯作者: GUAN Shuang E-mail:guanshuang@mail.ccut.edu.cn
  • 基金资助:

    Supported by the Project of the Jilin Provincial Science and Technology Department, China(No.20150204064G).

Characterization of UV-curable Poly(ethylene glycol) Diacrylate Based Hydrogels

QIN Xuzhen, HU Qianqian, GAO Guanghui, GUAN Shuang   

  1. School of Chemistry and Life Science, Advanced Institute of Materials Science, Changchun University of Technology, Changchun 130012, P. R. China
  • Received:2015-08-25 Revised:2015-09-28 Online:2015-11-01 Published:2015-11-02
  • Contact: GUAN Shuang E-mail:guanshuang@mail.ccut.edu.cn
  • Supported by:

    Supported by the Project of the Jilin Provincial Science and Technology Department, China(No.20150204064G).

摘要:

Poly(ethylene glycol) diacrylate/polyvinyl alcohol(PEGDA/PVA) hydrogels were prepared from PEGDA and PVA as precurors by means of single UV radiation(UV ra.), UV radiation followed by high energy electron beam irradiation(Irra.), UV radiation followed by freeze-thawing(FT) or UV ra. and Irra. followed by FT, respectively. 2-Hydroxy-1-[4-(hydroxyethoxy)phenyl]-2-methyl-1-propanone(Irgacure 2959) was used as a photoinitiator. The effects of the various methods on the swelling and mechanical properties of the hydrogels were investigated. The results show that hydrogels made by UV ra. plus high energy electron beam irradiation followed by FT showed a higher crosslinking density and a larger tensile strength than those made by the other methods.

关键词: Poly(ethylene glycol) diacrylate, Polyvinyl alcohol, Hydrogel, UV radiation

Abstract:

Poly(ethylene glycol) diacrylate/polyvinyl alcohol(PEGDA/PVA) hydrogels were prepared from PEGDA and PVA as precurors by means of single UV radiation(UV ra.), UV radiation followed by high energy electron beam irradiation(Irra.), UV radiation followed by freeze-thawing(FT) or UV ra. and Irra. followed by FT, respectively. 2-Hydroxy-1-[4-(hydroxyethoxy)phenyl]-2-methyl-1-propanone(Irgacure 2959) was used as a photoinitiator. The effects of the various methods on the swelling and mechanical properties of the hydrogels were investigated. The results show that hydrogels made by UV ra. plus high energy electron beam irradiation followed by FT showed a higher crosslinking density and a larger tensile strength than those made by the other methods.

Key words: Poly(ethylene glycol) diacrylate, Polyvinyl alcohol, Hydrogel, UV radiation