DNA Induced FePt Bimetallic Nanoparticles on Reduced Graphene Oxide for Electrochemical Determination of Dopamine

doi:10.1007/s40242-015-4515-6

高等学校化学研究 ›› 2015, Vol. 31 ›› Issue (3): 406-411.doi: 10.1007/s40242-015-4515-6

DNA Induced FePt Bimetallic Nanoparticles on Reduced Graphene Oxide for Electrochemical Determination of Dopamine

ZHANG Wenyan, LIU Yang

Beijing Key Laboratory for Microanalytical Methods and Instrumentation, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China

收稿日期:2014-12-31 修回日期:2015-02-13 出版日期:2015-06-01 发布日期:2015-03-16
通讯作者: LIU Yang E-mail:liu-yang@mail.tsinghua.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21235004, 21327806).

DNA Induced FePt Bimetallic Nanoparticles on Reduced Graphene Oxide for Electrochemical Determination of Dopamine

ZHANG Wenyan, LIU Yang

Beijing Key Laboratory for Microanalytical Methods and Instrumentation, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China

Received:2014-12-31 Revised:2015-02-13 Online:2015-06-01 Published:2015-03-16
Contact: LIU Yang E-mail:liu-yang@mail.tsinghua.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21235004, 21327806).

摘要/Abstract

摘要：

FePt bimetallic nanoparticles were formed on reduced graphene oxide(rGO) with the help of double-stranded DNA(dsDNA) via a simple and universal route to obtain a FePt/DNA-rGO composite. The FePt nanoparticles with an average size of about 5 nm were well dispersed on rGO. FePt/DNA-rGO modified glassy carbon electrode(GCE) exhibited excellent electrocatalytic activity for the oxidation of dopamine(DA) with a detection limit of 100 nmol/L(S/N = 3). In addition, the FePt/DNA-rGO based electrochemical sensor showed an excellent selectivity for DA in the presence of ascorbic acid(AA), uric acid(UA) and other interference reagents. The as-prepared electrochemical biosensor shows great promise in the application of clinical diagnostics.

关键词: Reduced graphene oxide, FePt bimetal nanoparticle, DNA, Electroanalysis, Dopamine

Abstract:

Key words: Reduced graphene oxide, FePt bimetal nanoparticle, DNA, Electroanalysis, Dopamine

ZHANG Wenyan, LIU Yang. DNA Induced FePt Bimetallic Nanoparticles on Reduced Graphene Oxide for Electrochemical Determination of Dopamine[J]. 高等学校化学研究, 2015, 31(3): 406-411.

ZHANG Wenyan, LIU Yang. DNA Induced FePt Bimetallic Nanoparticles on Reduced Graphene Oxide for Electrochemical Determination of Dopamine[J]. Chemical Research in Chinese Universities, 2015, 31(3): 406-411.

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DNA Induced FePt Bimetallic Nanoparticles on Reduced Graphene Oxide for Electrochemical Determination of Dopamine

DNA Induced FePt Bimetallic Nanoparticles on Reduced Graphene Oxide for Electrochemical Determination of Dopamine

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