A Series of Lanthanide Coordination Polymers Constructed from 4-Pyridin-4-ylbenzoate

doi:10.1007/s40242-015-4316-y

高等学校化学研究 ›› 2015, Vol. 31 ›› Issue (2): 187-191.doi: 10.1007/s40242-015-4316-y

A Series of Lanthanide Coordination Polymers Constructed from 4-Pyridin-4-ylbenzoate

FANG Weihui, YANG Guoyu

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China

收稿日期:2014-08-25 修回日期:2014-11-28 出版日期:2015-04-01 发布日期:2014-12-22
通讯作者: YANG Guoyu E-mail:ygy@fjirsm.ac.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.91122028, 21221001, 50872133) and the National Basic Research Program of China(Nos.2014CB932101, 2011CB932504).

A Series of Lanthanide Coordination Polymers Constructed from 4-Pyridin-4-ylbenzoate

FANG Weihui, YANG Guoyu

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China

Received:2014-08-25 Revised:2014-11-28 Online:2015-04-01 Published:2014-12-22
Contact: YANG Guoyu E-mail:ygy@fjirsm.ac.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.91122028, 21221001, 50872133) and the National Basic Research Program of China(Nos.2014CB932101, 2011CB932504).

摘要/Abstract

摘要：

Four lanthanide coordination polymers, LaL₃(H₂O)₂(1), LnL₂(μ₃-OH)(H₂O)[Ln=Eu(2),Tb(3)] and ErL₃·2H₂O(4) were synthesized via hydrothermal reactions of lanthanide oxide with 4-pyridin-4-ylbenzonic acid(HL), and characterized by means of elemental analyses, infrared(IR) spectrometer, powder X-ray diffraction(PXRD), thermogravimetric analyses(TGA) and single-crystal XRD. The results reveal that complex 1 possesses a linear chain structure, complexes 2 and 3 possess isostructural ladder-like chains, while complex 4 possesses a 2D layer with 4-connected sql topology. Furthermore, the luminescence properties and UV-Vis spectra of complexes 2 and 3 were investigated.

关键词: Hydrothermal synthesis, Lanthanide, Luminescence property

Abstract:

Key words: Hydrothermal synthesis, Lanthanide, Luminescence property

FANG Weihui, YANG Guoyu. A Series of Lanthanide Coordination Polymers Constructed from 4-Pyridin-4-ylbenzoate[J]. 高等学校化学研究, 2015, 31(2): 187-191.

FANG Weihui, YANG Guoyu. A Series of Lanthanide Coordination Polymers Constructed from 4-Pyridin-4-ylbenzoate[J]. Chemical Research in Chinese Universities, 2015, 31(2): 187-191.

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A Series of Lanthanide Coordination Polymers Constructed from 4-Pyridin-4-ylbenzoate

A Series of Lanthanide Coordination Polymers Constructed from 4-Pyridin-4-ylbenzoate

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