Effects of Various Factors on the Modification of Carbon Nanotubes with Polyvinyl Alcohol in Supercritical CO2 and Their Application in Electrospun Fibers

doi:10.1007/s40242-014-3535-y

高等学校化学研究 ›› 2014, Vol. 30 ›› Issue (4): 690-697.doi: 10.1007/s40242-014-3535-y

Effects of Various Factors on the Modification of Carbon Nanotubes with Polyvinyl Alcohol in Supercritical CO₂ and Their Application in Electrospun Fibers

CHEN Zhimin¹, ZHANG Jianan¹, GUO Yuanlong¹, ZHANG Hao¹, CAO Jingjing¹, XU Qun¹, WANG Shuxia¹, WANG Bo¹, LIU Zhaotie²

1. College of Material Science and Engineering, Zhengzhou University, Zhengzhou 450001, P. R. China;
2. Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, Shaanxi Normal University, Xi'an 710062, P. R. China

出版日期:2014-08-01 发布日期:2014-03-24
通讯作者: XU Qun E-mail:qunxu@zzu.edu.cn
基金资助:
Supported by the the National Natural Science Foundation of China(Nos.20804040, 20974102, 50955010, 51173170, 21101141, 51003098), the Program for New Century Excellent Talents in Universities(NCET) and the Open Fund of Key Labo- ratory of Applied Surface and Colloid Chemistry(Shaanxi Normal University) of Ministry of Education of China(No.201201).

Effects of Various Factors on the Modification of Carbon Nanotubes with Polyvinyl Alcohol in Supercritical CO₂ and Their Application in Electrospun Fibers

CHEN Zhimin¹, ZHANG Jianan¹, GUO Yuanlong¹, ZHANG Hao¹, CAO Jingjing¹, XU Qun¹, WANG Shuxia¹, WANG Bo¹, LIU Zhaotie²

1. College of Material Science and Engineering, Zhengzhou University, Zhengzhou 450001, P. R. China;
2. Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, Shaanxi Normal University, Xi'an 710062, P. R. China

Online:2014-08-01 Published:2014-03-24
Contact: XU Qun E-mail:qunxu@zzu.edu.cn
Supported by:
Supported by the the National Natural Science Foundation of China(Nos.20804040, 20974102, 50955010, 51173170, 21101141, 51003098), the Program for New Century Excellent Talents in Universities(NCET) and the Open Fund of Key Labo- ratory of Applied Surface and Colloid Chemistry(Shaanxi Normal University) of Ministry of Education of China(No.201201).

摘要/Abstract

摘要：

Supercritical(SC) CO₂ anti-solvent induced polymer epitaxy(SAIPE) method was used to help prepare nanohybrid carbon nanotubes(CNTs) wrapped with polyvinyl alcohol(PVA) nanocrystals. With the variation of a series of experimental conditions or peripheral effects, such as PVA concentration, CNTs concentration, and SC CO₂ pressure, the optimal experimental variables for PVA-nanocrystals growing on CNTs have been found. The adsorption of polymer on CNTs via multiple weak molecular interactions has been studied by Fourier transform infrared(FTIR) spectroscopy and Raman spectroscopy. The mechanism about the formation of PVA nanocrystals on CNTs can be suggested through the experimental phenomena. These CNTs wrapped with PVA nanocrystals can be directly used as nanofillers to fabricate PVA composite fibers reinforced with CNTs by electrospinning.

关键词: Carbon nanotube, Supercritical CO₂, Polyvinyl alcohol, Electrospinning

Abstract:

Key words: Carbon nanotube, Supercritical CO₂, Polyvinyl alcohol, Electrospinning

CHEN Zhimin, ZHANG Jianan, GUO Yuanlong, ZHANG Hao, CAO Jingjing, XU Qun, WANG Shuxia, WANG Bo, LIU Zhaotie. Effects of Various Factors on the Modification of Carbon Nanotubes with Polyvinyl Alcohol in Supercritical CO₂ and Their Application in Electrospun Fibers[J]. 高等学校化学研究, 2014, 30(4): 690-697.

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Effects of Various Factors on the Modification of Carbon Nanotubes with Polyvinyl Alcohol in Supercritical CO₂ and Their Application in Electrospun Fibers

Effects of Various Factors on the Modification of Carbon Nanotubes with Polyvinyl Alcohol in Supercritical CO₂ and Their Application in Electrospun Fibers

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