Efficient Synthesis of Complex Bridged 1,3-Oxazabicycles via Reactions of N-Alkyl-1,10-phenanthrolinium Halides with Cyclic 1,3-Diketones

高等学校化学研究 ›› 2012, Vol. 28 ›› Issue (5): 847-850 .

Efficient Synthesis of Complex Bridged 1,3-Oxazabicycles via Reactions of N-Alkyl-1,10-phenanthrolinium Halides with Cyclic 1,3-Diketones

WU Ping¹, HUI Li², GAO Xing², YAN Chao-guo²

1. Department of Biochemical Engineering, Yangzhou Polytechnic University, Yangzhou 225000, P. R. China;
2. College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. China

收稿日期:2011-09-14 修回日期:2011-10-04 出版日期:2012-09-25 发布日期:2012-09-07
通讯作者: YAN Chao-guo E-mail:cgyan@yzu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.20972132) and the Fund of the Key Laboratory of Environmental Resource and Material of Jiangsu Province, China.

Efficient Synthesis of Complex Bridged 1,3-Oxazabicycles via Reactions of N-Alkyl-1,10-phenanthrolinium Halides with Cyclic 1,3-Diketones

WU Ping¹, HUI Li², GAO Xing², YAN Chao-guo²

1. Department of Biochemical Engineering, Yangzhou Polytechnic University, Yangzhou 225000, P. R. China;
2. College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. China

Received:2011-09-14 Revised:2011-10-04 Online:2012-09-25 Published:2012-09-07
Supported by:
Supported by the National Natural Science Foundation of China(No.20972132) and the Fund of the Key Laboratory of Environmental Resource and Material of Jiangsu Province, China.

摘要/Abstract

摘要： Complex bridged 1,3-oxazabicycles and 1,4-disubstituted 1,10-phenanthroline derivatives were efficiently prepared by the reactions of N-methyl or N-benzylphenanthrolinium halides with cyclic 1,3-dicarbonyl compounds in a K₂CO₃/CH₃CN system.

关键词: Phenanthroline, Heterocycle, Oxazabicycle, Pyridinium salt, Tandem reaction

Abstract: Complex bridged 1,3-oxazabicycles and 1,4-disubstituted 1,10-phenanthroline derivatives were efficiently prepared by the reactions of N-methyl or N-benzylphenanthrolinium halides with cyclic 1,3-dicarbonyl compounds in a K₂CO₃/CH₃CN system.

Key words: Phenanthroline, Heterocycle, Oxazabicycle, Pyridinium salt, Tandem reaction

WU Ping, HUI Li, GAO Xing, YAN Chao-guo. Efficient Synthesis of Complex Bridged 1,3-Oxazabicycles via Reactions of N-Alkyl-1,10-phenanthrolinium Halides with Cyclic 1,3-Diketones[J]. 高等学校化学研究, 2012, 28(5): 847-850 .

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Efficient Synthesis of Complex Bridged 1,3-Oxazabicycles via Reactions of N-Alkyl-1,10-phenanthrolinium Halides with Cyclic 1,3-Diketones

Efficient Synthesis of Complex Bridged 1,3-Oxazabicycles via Reactions of N-Alkyl-1,10-phenanthrolinium Halides with Cyclic 1,3-Diketones

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