Structure and Orientation of 1-(Hydroxyl)-5-(dodecyloxy)-naphthalene LB Films by Polarized Fluorescence Spectroscopy

高等学校化学研究 ›› 1998, Vol. 14 ›› Issue (4): 395-398.

Structure and Orientation of 1-(Hydroxyl)-5-(dodecyloxy)-naphthalene LB Films by Polarized Fluorescence Spectroscopy

LI Xiao-ling¹, ZHAO Bing¹, WU Yu-qing¹, XU Wei-qing¹, LI Guo-wen¹, WU Ying¹, BAI Fang², CUI Shu-wen³

1. Key Laboratory for Supramolecular Structure and Spectroscopy, Jilin University, Changchun 130023;
2. Shenyang Rust Pro of Packaging Material Company, Shenyang 110032;
3. Medical Academy of Jiamusi University, Jiamusi 154002

收稿日期:1997-06-04 出版日期:1998-12-24 发布日期:2011-08-17
通讯作者: ZHAO Bing
基金资助:
Supported by the National Natural Science Foundation of China(29633010).

Structure and Orientation of 1-(Hydroxyl)-5-(dodecyloxy)-naphthalene LB Films by Polarized Fluorescence Spectroscopy

LI Xiao-ling¹, ZHAO Bing¹, WU Yu-qing¹, XU Wei-qing¹, LI Guo-wen¹, WU Ying¹, BAI Fang², CUI Shu-wen³

1. Key Laboratory for Supramolecular Structure and Spectroscopy, Jilin University, Changchun 130023;
2. Shenyang Rust Pro of Packaging Material Company, Shenyang 110032;
3. Medical Academy of Jiamusi University, Jiamusi 154002

Received:1997-06-04 Online:1998-12-24 Published:2011-08-17

摘要/Abstract

摘要： A new single-chain amphiphile 1-hydroxyl-5-dodecyloxy-naphthalene can be deposited onto substr ates to form LB films by means of the L ang muir-Blodgett technique with pure ater as the subphase.The steady-state fluorescence spectra of the LB films were recorded.The dependence of the relative content of the naphthalene excimers in the films uponag gregation state indicates that the excimer for mation is promoted by increasing the close packing density of the molecules.The molecular orientation in the LB films was studied by fluor escence polarization technique,and the results revealed that the naphthalene chromophores or iented perpendicularly to the layer plane.

关键词: Structure, Orientation, LB film, Polarized fluorescence spectroscopy

Abstract: A new single-chain amphiphile 1-hydroxyl-5-dodecyloxy-naphthalene can be deposited onto substr ates to form LB films by means of the L ang muir-Blodgett technique with pure ater as the subphase.The steady-state fluorescence spectra of the LB films were recorded.The dependence of the relative content of the naphthalene excimers in the films uponag gregation state indicates that the excimer for mation is promoted by increasing the close packing density of the molecules.The molecular orientation in the LB films was studied by fluor escence polarization technique,and the results revealed that the naphthalene chromophores or iented perpendicularly to the layer plane.

Key words: Structure, Orientation, LB film, Polarized fluorescence spectroscopy

LI Xiao-ling, ZHAO Bing, WU Yu-qing, XU Wei-qing, LI Guo-wen, WU Ying, BAI Fang, CUI Shu-wen. Structure and Orientation of 1-(Hydroxyl)-5-(dodecyloxy)-naphthalene LB Films by Polarized Fluorescence Spectroscopy[J]. 高等学校化学研究, 1998, 14(4): 395-398.

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Structure and Orientation of 1-(Hydroxyl)-5-(dodecyloxy)-naphthalene LB Films by Polarized Fluorescence Spectroscopy

Structure and Orientation of 1-(Hydroxyl)-5-(dodecyloxy)-naphthalene LB Films by Polarized Fluorescence Spectroscopy

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