Syn thesis, Characterization of CoAPO-11 Molecular Sieve from a Nonaqueous System

高等学校化学研究 ›› 1999, Vol. 15 ›› Issue (2): 96-99.

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Syn thesis, Characterization of CoAPO-11 Molecular Sieve from a Nonaqueous System

JIAO Xiu-ling, YAO You-wei, PANG Wen-qin, XU Ru-ren

Department of Chemistry, Jilin University, Changchun, 130023

收稿日期:1998-09-09 出版日期:1999-04-24 发布日期:2011-08-17
通讯作者: PANG Wen-qin
基金资助:
Supported by the National Natural Science Foundation of China and the State Key Laboratory of Crystal of Shandong University.

Syn thesis, Characterization of CoAPO-11 Molecular Sieve from a Nonaqueous System

JIAO Xiu-ling, YAO You-wei, PANG Wen-qin, XU Ru-ren

Department of Chemistry, Jilin University, Changchun, 130023

Received:1998-09-09 Online:1999-04-24 Published:2011-08-17
Supported by:
Supported by the National Natural Science Foundation of China and the State Key Laboratory of Crystal of Shandong University.

摘要/Abstract

摘要： CoAPO-11 molecular sieve with a high crystallinity was prepared by hydro thermal syn thesis from a non-aqueous system(EG) in the presence of Et₂NH or i-Pr₂NH as a structuredirecting agent. The X-ray diffraction(XRD) patterns, scanning electron micrographs(SEM) revealed that the product powder was pure, homogenous in particle-size. The X-ray powder diffraction data, compositional analysis, thermal stability analysis, UV-V is diffuse reflectance spectroscopic analysis showed that Co(Ⅱ) ions were incorporated in the aluminophosphate framework, tetrahedrally coordinated in the lattice of asprepared samples.

关键词: Hydro thermal syn thesis, CoAPO-11, Non-aqueous system, Molecular sieve

Abstract: CoAPO-11 molecular sieve with a high crystallinity was prepared by hydro thermal syn thesis from a non-aqueous system(EG) in the presence of Et₂NH or i-Pr₂NH as a structuredirecting agent. The X-ray diffraction(XRD) patterns, scanning electron micrographs(SEM) revealed that the product powder was pure, homogenous in particle-size. The X-ray powder diffraction data, compositional analysis, thermal stability analysis, UV-V is diffuse reflectance spectroscopic analysis showed that Co(Ⅱ) ions were incorporated in the aluminophosphate framework, tetrahedrally coordinated in the lattice of asprepared samples.

Key words: Hydro thermal syn thesis, CoAPO-11, Non-aqueous system, Molecular sieve

JIAO Xiu-ling, YAO You-wei, PANG Wen-qin, XU Ru-ren. Syn thesis, Characterization of CoAPO-11 Molecular Sieve from a Nonaqueous System[J]. 高等学校化学研究, 1999, 15(2): 96-99.

JIAO Xiu-ling, YAO You-wei, PANG Wen-qin, XU Ru-ren. Syn thesis, Characterization of CoAPO-11 Molecular Sieve from a Nonaqueous System[J]. Chemical Research in Chinese Universities, 1999, 15(2): 96-99.

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Syn thesis, Characterization of CoAPO-11 Molecular Sieve from a Nonaqueous System

Syn thesis, Characterization of CoAPO-11 Molecular Sieve from a Nonaqueous System

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