Studies on Mixed Trialkyltm Derivatives Ⅶ——Studies of [(Phenyldimethylsilyl)methyl]-dicyclohexyltin Carboxylates

高等学校化学研究 ›› 1995, Vol. 11 ›› Issue (2): 105-110.

Studies on Mixed Trialkyltm Derivatives Ⅶ——Studies of [(Phenyldimethylsilyl)methyl]-dicyclohexyltin Carboxylates

XIE Qing-lan, SHA Yin-lin, YANG Zhi-qiang

Elemento-organic Chemistry Laboratory, Nankai University, Taijin, 300071

收稿日期:1994-01-30 出版日期:1995-04-24 发布日期:2011-08-17
基金资助:
Supported by the National Natural Science Foundation of China

Studies on Mixed Trialkyltm Derivatives Ⅶ——Studies of [(Phenyldimethylsilyl)methyl]-dicyclohexyltin Carboxylates

XIE Qing-lan, SHA Yin-lin, YANG Zhi-qiang

Elemento-organic Chemistry Laboratory, Nankai University, Taijin, 300071

Received:1994-01-30 Online:1995-04-24 Published:2011-08-17
Supported by:
Supported by the National Natural Science Foundation of China

摘要/Abstract

摘要： Seventeen derivatives of mixed trialkyltin carboxylates with the formula (PhMe₂SiCH₂)Cy₂SnO₂CR have been synthesised.The results of IR NMR(¹H,¹³C,¹¹⁹Sn) and MS showed that this kind of compounds is four-coordinated and that there are two good linear relationships between the δ ¹¹⁹Sn and Hammett constants of para-substitutent of the corresponding aryloxy-acetates and arylcarboxylates.These compounds have a good acaricidal activity in the preliminary bioassay tests.

关键词: Mixed trialkyltin, Organotin, Organosilicon, Carboxylate, Cyclohexyl

Abstract: Seventeen derivatives of mixed trialkyltin carboxylates with the formula (PhMe₂SiCH₂)Cy₂SnO₂CR have been synthesised.The results of IR NMR(¹H,¹³C,¹¹⁹Sn) and MS showed that this kind of compounds is four-coordinated and that there are two good linear relationships between the δ ¹¹⁹Sn and Hammett constants of para-substitutent of the corresponding aryloxy-acetates and arylcarboxylates.These compounds have a good acaricidal activity in the preliminary bioassay tests.

Key words: Mixed trialkyltin, Organotin, Organosilicon, Carboxylate, Cyclohexyl

XIE Qing-lan, SHA Yin-lin, YANG Zhi-qiang . Studies on Mixed Trialkyltm Derivatives Ⅶ——Studies of [(Phenyldimethylsilyl)methyl]-dicyclohexyltin Carboxylates[J]. 高等学校化学研究, 1995, 11(2): 105-110.

XIE Qing-lan, SHA Yin-lin, YANG Zhi-qiang . Studies on Mixed Trialkyltm Derivatives Ⅶ——Studies of [(Phenyldimethylsilyl)methyl]-dicyclohexyltin Carboxylates[J]. Chemical Research in Chinese Universities, 1995, 11(2): 105-110.

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Studies on Mixed Trialkyltm Derivatives Ⅶ——Studies of [(Phenyldimethylsilyl)methyl]-dicyclohexyltin Carboxylates

Studies on Mixed Trialkyltm Derivatives Ⅶ——Studies of [(Phenyldimethylsilyl)methyl]-dicyclohexyltin Carboxylates

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