Isomerization and Antiacidolysis Properties of Molybdic Heteropoly Blues with Keggin Structure

高等学校化学研究 ›› 1995, Vol. 11 ›› Issue (2): 98-104.

Isomerization and Antiacidolysis Properties of Molybdic Heteropoly Blues with Keggin Structure

WANG Zuo-ping, XU Lin, SHEN En-hong, WANG En-bo

Department of Chemistry, Northeast Normal University, Changchun, 130024

收稿日期:1994-01-25 出版日期:1995-04-24 发布日期:2011-08-17

Isomerization and Antiacidolysis Properties of Molybdic Heteropoly Blues with Keggin Structure

WANG Zuo-ping, XU Lin, SHEN En-hong, WANG En-bo

Department of Chemistry, Northeast Normal University, Changchun, 130024

Received:1994-01-25 Online:1995-04-24 Published:2011-08-17

摘要/Abstract

摘要： For eight kinds of acidic potassium salts of hetcropoly blues which have not been reported in literature,the isomerization reaction in solution for these two-and four-electron hcteropoly blue solids were investigated by means of polarograms,cyclic voltammetry,³¹P NMR and X-ray diffraction methods.The heteropolynier of PMo₁₂ and AsMo₁₂ converte to their β-isomers during isomerization reaction which were found to have antiacidolysis property.

关键词: Heteropoly blue, Keggin structure, Isomenzation

Abstract: For eight kinds of acidic potassium salts of hetcropoly blues which have not been reported in literature,the isomerization reaction in solution for these two-and four-electron hcteropoly blue solids were investigated by means of polarograms,cyclic voltammetry,³¹P NMR and X-ray diffraction methods.The heteropolynier of PMo₁₂ and AsMo₁₂ converte to their β-isomers during isomerization reaction which were found to have antiacidolysis property.

Key words: Heteropoly blue, Keggin structure, Isomenzation

WANG Zuo-ping, XU Lin, SHEN En-hong, WANG En-bo . Isomerization and Antiacidolysis Properties of Molybdic Heteropoly Blues with Keggin Structure[J]. 高等学校化学研究, 1995, 11(2): 98-104.

WANG Zuo-ping, XU Lin, SHEN En-hong, WANG En-bo . Isomerization and Antiacidolysis Properties of Molybdic Heteropoly Blues with Keggin Structure[J]. Chemical Research in Chinese Universities, 1995, 11(2): 98-104.

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Isomerization and Antiacidolysis Properties of Molybdic Heteropoly Blues with Keggin Structure

Isomerization and Antiacidolysis Properties of Molybdic Heteropoly Blues with Keggin Structure

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