Studies on the Synthesis and Structure of Cycl opentadienylruthenium Derivatives--Crystal and Molecular Structure of (η5-C5Me4Et)2Ru

高等学校化学研究 ›› 1992, Vol. 8 ›› Issue (3): 258-261.

Studies on the Synthesis and Structure of Cycl opentadienylruthenium Derivatives--Crystal and Molecular Structure of (η⁵-C₅Me₄Et)₂Ru

LAI Lu-hua, ZHANG Zhen-ying, SHAO Mei-cheng

Institute, of Physical Chemistry, Peking University, Beijing, 100871

收稿日期:1991-08-25 出版日期:1992-08-24 发布日期:2011-09-09
基金资助:
Supported by the National Natural Science Foundation of China

Studies on the Synthesis and Structure of Cycl opentadienylruthenium Derivatives--Crystal and Molecular Structure of (η⁵-C₅Me₄Et)₂Ru

LAI Lu-hua, ZHANG Zhen-ying, SHAO Mei-cheng

Institute, of Physical Chemistry, Peking University, Beijing, 100871

Received:1991-08-25 Online:1992-08-24 Published:2011-09-09
Supported by:
Supported by the National Natural Science Foundation of China

摘要/Abstract

摘要： The title compound was synthesized by refluxing RuCl₃with cyclopentadiene in methanol. It crystallizes in space group C₅-P_nwith cell dimensions: a=0. 9735(4) nm, b=0. 8604(3) nm, c=1. 2261(6) nm, β=94. 83(3), and Z=2. Structure was solved by Patterson method and Fourier functions, and was refined to final Rvalue of 0. 0365 based on 1872 observable reflections. In contrast to the staggered conformation of decamethylferrocene, this molecule adopts the eclipsed comformation. The conformation difference was explained by the polarizability and metal atom size.

关键词: Synthesis, Structure, Cyclopentadienylruthenium

Abstract: The title compound was synthesized by refluxing RuCl₃with cyclopentadiene in methanol. It crystallizes in space group C₅-P_nwith cell dimensions: a=0. 9735(4) nm, b=0. 8604(3) nm, c=1. 2261(6) nm, β=94. 83(3), and Z=2. Structure was solved by Patterson method and Fourier functions, and was refined to final Rvalue of 0. 0365 based on 1872 observable reflections. In contrast to the staggered conformation of decamethylferrocene, this molecule adopts the eclipsed comformation. The conformation difference was explained by the polarizability and metal atom size.

Key words: Synthesis, Structure, Cyclopentadienylruthenium

LAI Lu-hua, ZHANG Zhen-ying, SHAO Mei-cheng . Studies on the Synthesis and Structure of Cycl opentadienylruthenium Derivatives--Crystal and Molecular Structure of (η⁵-C₅Me₄Et)₂Ru[J]. 高等学校化学研究, 1992, 8(3): 258-261.

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Studies on the Synthesis and Structure of Cycl opentadienylruthenium Derivatives--Crystal and Molecular Structure of (η⁵-C₅Me₄Et)₂Ru

Studies on the Synthesis and Structure of Cycl opentadienylruthenium Derivatives--Crystal and Molecular Structure of (η⁵-C₅Me₄Et)₂Ru

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