Synthesis, Structure and Properties of Co(NH2CSNHNH2)3Cl3·1/2HCl

高等学校化学研究 ›› 1993, Vol. 9 ›› Issue (2): 133-138.

Synthesis, Structure and Properties of Co(NH₂CSNHNH₂)₃Cl₃·1/2HCl

LI Shu-jia,NIU Shu-yun, ZHANG Heng-bin, YANG Guang-di, LI Li, NIE Fu

Department of Chemistry, Institute of Theoretical Chemistry,Jilin University, Changchun 130023

收稿日期:1992-04-13 出版日期:1993-04-24 发布日期:2011-08-17
基金资助:
Supported by the National Natural Science Foundation of China

Synthesis, Structure and Properties of Co(NH₂CSNHNH₂)₃Cl₃·1/2HCl

LI Shu-jia,NIU Shu-yun, ZHANG Heng-bin, YANG Guang-di, LI Li, NIE Fu

Department of Chemistry, Institute of Theoretical Chemistry,Jilin University, Changchun 130023

Received:1992-04-13 Online:1993-04-24 Published:2011-08-17
Supported by:
Supported by the National Natural Science Foundation of China

摘要/Abstract

摘要： The single crystal of title compound was obtained in the solution of DMFand CH₃OHunder the radiation of IRlamp. The crystallographic parameters obtained are as follows: trigonal system, space group P31C, Z=4, a=b=1.0008(2)nm, c=2.4011 nm; final R=0.099, R_w=0.092. The properties of title compound were characterized by IR, UV, EPR, XPSand CVmeasurements.

关键词: Cobalt, Complex, Synthesis, Structure

Abstract: The single crystal of title compound was obtained in the solution of DMFand CH₃OHunder the radiation of IRlamp. The crystallographic parameters obtained are as follows: trigonal system, space group P31C, Z=4, a=b=1.0008(2)nm, c=2.4011 nm; final R=0.099, R_w=0.092. The properties of title compound were characterized by IR, UV, EPR, XPSand CVmeasurements.

Key words: Cobalt, Complex, Synthesis, Structure

LI Shu-jia,NIU Shu-yun, ZHANG Heng-bin, YANG Guang-di, LI Li, NIE Fu. Synthesis, Structure and Properties of Co(NH₂CSNHNH₂)₃Cl₃·1/2HCl[J]. 高等学校化学研究, 1993, 9(2): 133-138.

LI Shu-jia,NIU Shu-yun, ZHANG Heng-bin, YANG Guang-di, LI Li, NIE Fu. Synthesis, Structure and Properties of Co(NH₂CSNHNH₂)₃Cl₃·1/2HCl[J]. Chemical Research in Chinese Universities, 1993, 9(2): 133-138.

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Synthesis, Structure and Properties of Co(NH₂CSNHNH₂)₃Cl₃·1/2HCl

Synthesis, Structure and Properties of Co(NH₂CSNHNH₂)₃Cl₃·1/2HCl

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