5,10,15,20-Tetrakis(p-4-fluorobenzoyloxy)phenyl Porphyrin and Its Transition Metal Complexes

高等学校化学研究 ›› 2006, Vol. 22 ›› Issue (4): 419-422.

5,10,15,20-Tetrakis(p-4-fluorobenzoyloxy)phenyl Porphyrin and Its Transition Metal Complexes

LIU Wei¹, SHI Tong-shun², LIU Guo-fa²

1. College of Materials Science and Engineering, Shandong University of Technology, Zibo 255049, P. R. China;
2. College of Chemistry, Jilin University, Changchun 130023, P. R. China

收稿日期:2005-09-05 出版日期:2006-08-24 发布日期:2011-08-06

5,10,15,20-Tetrakis(p-4-fluorobenzoyloxy)phenyl Porphyrin and Its Transition Metal Complexes

LIU Wei¹, SHI Tong-shun², LIU Guo-fa²

1. College of Materials Science and Engineering, Shandong University of Technology, Zibo 255049, P. R. China;
2. College of Chemistry, Jilin University, Changchun 130023, P. R. China

Received:2005-09-05 Online:2006-08-24 Published:2011-08-06

摘要/Abstract

摘要： The properties of porphyrins can be changed through the choice of peripheral substituents and inserted metal ions. To obtain porphyrin complexes with novel structures, 5,10,15,20-tetrakis(p-4-fluorobenzoyloxy) phenyl porphyrin(TFBOPPH₂) and its transition metal complexes {TFBOPPM [M=Mn(Ⅲ), Fe(Ⅲ), Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) and Zn(Ⅱ)]} were synthesized and characterized by means of UV-Vis, IR photoacoustic spectrometry, ¹H NMR, elemental analyses, molar conductance, and XPS methods. A structure is proposed, in which one porphyrin molecule is coordinated with a transition metal ion in a tetradentate fashion, while the chlorine ion is the balanceable anion in Fe(Ⅲ) and Mn(Ⅲ) complexes.

关键词: Porphyrin, Synthesis, Transition metal, Complex

Abstract: The properties of porphyrins can be changed through the choice of peripheral substituents and inserted metal ions. To obtain porphyrin complexes with novel structures, 5,10,15,20-tetrakis(p-4-fluorobenzoyloxy) phenyl porphyrin(TFBOPPH₂) and its transition metal complexes {TFBOPPM [M=Mn(Ⅲ), Fe(Ⅲ), Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) and Zn(Ⅱ)]} were synthesized and characterized by means of UV-Vis, IR photoacoustic spectrometry, ¹H NMR, elemental analyses, molar conductance, and XPS methods. A structure is proposed, in which one porphyrin molecule is coordinated with a transition metal ion in a tetradentate fashion, while the chlorine ion is the balanceable anion in Fe(Ⅲ) and Mn(Ⅲ) complexes.

Key words: Porphyrin, Synthesis, Transition metal, Complex

LIU Wei, SHI Tong-shun, LIU Guo-fa. 5,10,15,20-Tetrakis(p-4-fluorobenzoyloxy)phenyl Porphyrin and Its Transition Metal Complexes[J]. 高等学校化学研究, 2006, 22(4): 419-422.

LIU Wei, SHI Tong-shun, LIU Guo-fa. 5,10,15,20-Tetrakis(p-4-fluorobenzoyloxy)phenyl Porphyrin and Its Transition Metal Complexes[J]. Chemical Research in Chinese Universities, 2006, 22(4): 419-422.

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5,10,15,20-Tetrakis(p-4-fluorobenzoyloxy)phenyl Porphyrin and Its Transition Metal Complexes

5,10,15,20-Tetrakis(p-4-fluorobenzoyloxy)phenyl Porphyrin and Its Transition Metal Complexes

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