A Thermochemical Study on Complex Nickel(Ⅱ) L-α-Histidine

高等学校化学研究 ›› 2003, Vol. 19 ›› Issue (2): 227-230.

A Thermochemical Study on Complex Nickel(Ⅱ) L-α-Histidine

GAO Sheng-li, CHEN San-ping, HU Rong-zu, SHI Qi-zhen

Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry, Northwest University, Xi′an 710069, P.R. China

收稿日期:2002-07-09 出版日期:2003-04-24 发布日期:2011-08-06
基金资助:
Supported by the National Natural Science Foundation of China(No.2017036).

A Thermochemical Study on Complex Nickel(Ⅱ) L-α-Histidine

GAO Sheng-li, CHEN San-ping, HU Rong-zu, SHI Qi-zhen

Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry, Northwest University, Xi′an 710069, P.R. China

Received:2002-07-09 Online:2003-04-24 Published:2011-08-06
Supported by:
Supported by the National Natural Science Foundation of China(No.2017036).

摘要/Abstract

摘要： The formation enthalpy of complex nickel(Ⅱ)-histidine(His) in water was determined by means of microcalorimetry in the temperature range of 298.15-323.15 K. The standard enthalpy of the formation of Ni(His)₂²⁺(aq) was calculated. On the basis of the experimental and the calculated results, three thermodynamic parameters(the activation enthalpy, the activation entropy and the activation free energy), the rate constants, three kinetic parameters(the apparent activation energy, the pre-exponential constant and the reaction order) of the formation reaction of the title complex were obtained.

关键词: Nickel chloride, L-&alpha, -Histidine, Complex, Formation reaction, Thermokinetics

Abstract: The formation enthalpy of complex nickel(Ⅱ)-histidine(His) in water was determined by means of microcalorimetry in the temperature range of 298.15-323.15 K. The standard enthalpy of the formation of Ni(His)₂²⁺(aq) was calculated. On the basis of the experimental and the calculated results, three thermodynamic parameters(the activation enthalpy, the activation entropy and the activation free energy), the rate constants, three kinetic parameters(the apparent activation energy, the pre-exponential constant and the reaction order) of the formation reaction of the title complex were obtained.

Key words: Nickel chloride, L-α-Histidine, Complex, Formation reaction, Thermokinetics

GAO Sheng-li, CHEN San-ping, HU Rong-zu, SHI Qi-zhen. A Thermochemical Study on Complex Nickel(Ⅱ) L-α-Histidine[J]. 高等学校化学研究, 2003, 19(2): 227-230.

GAO Sheng-li, CHEN San-ping, HU Rong-zu, SHI Qi-zhen. A Thermochemical Study on Complex Nickel(Ⅱ) L-α-Histidine[J]. Chemical Research in Chinese Universities, 2003, 19(2): 227-230.

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A Thermochemical Study on Complex Nickel(Ⅱ) L-α-Histidine

A Thermochemical Study on Complex Nickel(Ⅱ) L-α-Histidine

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