Studies on the Coordination Polymer of Copper Electropolyurushiol

高等学校化学研究 ›› 2001, Vol. 17 ›› Issue (3): 318-324.

Studies on the Coordination Polymer of Copper Electropolyurushiol

TANG Jie-yuan, ZHANG Wen-gong, SHEN Guo-cai, GAO Feng

Institute of Polymer Science, Fujian Teachers University, Fuzhou 350007, P. R. China

收稿日期:2000-06-28 出版日期:2001-08-24 发布日期:2011-08-04
基金资助:
Supported by the National Natural Science Foundation of China.

Studies on the Coordination Polymer of Copper Electropolyurushiol

TANG Jie-yuan, ZHANG Wen-gong, SHEN Guo-cai, GAO Feng

Institute of Polymer Science, Fujian Teachers University, Fuzhou 350007, P. R. China

Received:2000-06-28 Online:2001-08-24 Published:2011-08-04
Supported by:
Supported by the National Natural Science Foundation of China.

摘要/Abstract

摘要： The coordination polymer of copper electropolyurushiol(EPU-Cu²⁺) was obtained by the reaction of copper chloride with electropolyurushiol (EPU) in an isopropyl alcohol solution.The properties of EPU-Cu²⁺ were studied by means of ESR, FTIR, XPS, DMTA and TG-DTA.The results of AES show that the content of Cu²⁺ was 8.63%.The electric resistances of EPUCu²⁺ and EPU were determined to be 9.37×10¹⁰Ω and 7.90×10¹⁰Ω respectively.It was also ascertained that in EPU-Cu²⁺ each Cu²⁺ is coordinated with two units hydroxyl in EPU, making the EPU-Cu²⁺ cross-link further.As a result, the title polymer exhibits an insolubility in most of organic solutions, a higher glass transition temperature and thermal resistance.

关键词: Urushiol, Electrochemical polymerization, Coordination polymer

Abstract: The coordination polymer of copper electropolyurushiol(EPU-Cu²⁺) was obtained by the reaction of copper chloride with electropolyurushiol (EPU) in an isopropyl alcohol solution.The properties of EPU-Cu²⁺ were studied by means of ESR, FTIR, XPS, DMTA and TG-DTA.The results of AES show that the content of Cu²⁺ was 8.63%.The electric resistances of EPUCu²⁺ and EPU were determined to be 9.37×10¹⁰Ω and 7.90×10¹⁰Ω respectively.It was also ascertained that in EPU-Cu²⁺ each Cu²⁺ is coordinated with two units hydroxyl in EPU, making the EPU-Cu²⁺ cross-link further.As a result, the title polymer exhibits an insolubility in most of organic solutions, a higher glass transition temperature and thermal resistance.

Key words: Urushiol, Electrochemical polymerization, Coordination polymer

TANG Jie-yuan, ZHANG Wen-gong, SHEN Guo-cai, GAO Feng. Studies on the Coordination Polymer of Copper Electropolyurushiol[J]. 高等学校化学研究, 2001, 17(3): 318-324.

TANG Jie-yuan, ZHANG Wen-gong, SHEN Guo-cai, GAO Feng. Studies on the Coordination Polymer of Copper Electropolyurushiol[J]. Chemical Research in Chinese Universities, 2001, 17(3): 318-324.

[1]	WANG Yue, WANG Jinling, MA Jianxin, ZHANG Yue, XU Na, WANG Xiuli. Multi-functional Photoelectric Sensor Based on a Three-fold Interpenetrated Cd(II) Coordination Polymer for Sensitively Detecting Different Ions[J]. 高等学校化学研究, 2022, 38(4): 1105-1110.
[2]	HUA Chen, YI Pin, LIU Wencong, WANG Mengfan, NIU Zheng, LANG Jianping. Coordination Polymers with Bipyridyl Diene and Triene Ligands: Synthesis, Structures and Luminescent Properties[J]. 高等学校化学研究, 2022, 38(1): 209-216.
[3]	FU Pengyan, MO Junting, SUN Sisi, YIN Shaoyun, WANG Haiping, PAN Mei. Acid-base Vapor Sensing Enabled by ESIPT-attributed Cd(II) Coordination Polymer with Switchable Luminescence[J]. 高等学校化学研究, 2020, 36(5): 755-759.
[4]	QIAN Binbin, CHANG Ze, BU Xian-He. Zinc-coordination Polymers Based on a Donor-acceptor Mix-ligand System: Syntheses, Crystal Structures and Photophysical Properties[J]. 高等学校化学研究, 2020, 36(1): 74-80.
[5]	LU Xue, LIU Guocheng, WANG Xiang, LIN Hongyan, WANG Xiuli. Carboxylate-induced Various Structures of Ni(Ⅱ) Complexes with Fluorescence Sensing and Bifunctional Electrochemical Properties[J]. 高等学校化学研究, 2019, 35(4): 549-555.
[6]	ZHONG Liangxuan, LIU Mingyue, ZHANG Bowei, SUN Yaqiu, XU Yanyan. Syntheses, Crystal Structures, Magnetic and Near-infrared Luminescence Properties of 3d-4f Coordination Polymers Cu₂Pr₂, Cu₂Eu₂ and Cu₄Tb₂[J]. 高等学校化学研究, 2019, 35(4): 693-699.
[7]	KANG Dawei, XIE Jingjing, LIU Yingying, MA Jianfang. Four Coordination Polymers Assembled with a New Biscarboxyl-functionalized Schiff Base Ligand[J]. 高等学校化学研究, 2018, 34(5): 839-843.
[8]	LIU Bo, QIAO Wenqiang, WANG Zhi Yuan. Intense Near- and Mid-infrared Absorbing Films of Electrochemically Crosslinked Multinuclear Metallodithiolene Complex Polymers[J]. 高等学校化学研究, 2016, 32(2): 296-301.
[9]	ZHANG Qingfen, ZHOU Zhongyuan, WANG Xuan, LU Jing. Syntheses, Structures and Magnetic Properties of Two Coordination Polymers Based on 2, 2-Biphenyldicarboxylate Ligand[J]. 高等学校化学研究, 2016, 32(2): 165-171.
[10]	ZHENG Tianxing, HAN Yide, LIU Ningning. A Cobalt Supramolecular Compound Constructed from 4, 6-Di(1-imidazolyl)-1, 3, 5-triazine-2-one: Synthesis, Characterization and Magnetic Property[J]. 高等学校化学研究, 2016, 32(2): 184-187.
[11]	WANG Jing, LUO Xiaolong, YUAN Yang, ZHANG Lirong. Assembly of Two Coordination Polymers Based on 2,2'-Bipyridyl-4,4'-dicarboxylic Acid Ligand[J]. 高等学校化学研究, 2015, 31(4): 503-507.
[12]	XU Jingyao, ZHANG Lei, SHAO Xueman, PAN Chengling, XU Jiqing. Structure and Fluorescence Property of a Two-fold Interpenetrated Three-dimensional Zn(II) Complex Constructed by Terephthalate and 1,3-Dipyridyl Benzene[J]. 高等学校化学研究, 2015, 31(3): 328-331.
[13]	TIAN Ruijing, WANG Fuxiang, DU Chunyu, FENG Lijuan, LIU Ying, ZHANG Cailing, PAN Qinhe. Template-directed Synthesis of Three Metal Oxalates via 4-Connected Building Units[J]. 高等学校化学研究, 2014, 30(6): 889-893.
[14]	LUO Yanan, XU Xianzhu, SUN Fuxing, YU Xiaoyang, ZHANG Xiao, ZHANG Ting, YU Liying. Synthesis, Structure and Properties of Two New Coordination Polymers Based on 4-[(8-Hydroxy-5-quinolinyl)azo]-benzenesulfonic Acid[J]. 高等学校化学研究, 2014, 30(1): 27-31.
[15]	LU Sheng-li, GENG Rui. Efficient Hybrid Photovoltaic Devices Based on in-situ Electrochemical Copolymerization of 3-Methylthiophene and Bithiophene into Pores of Nanocrystalline TiO₂[J]. 高等学校化学研究, 2013, 29(6): 1208-1213.

Studies on the Coordination Polymer of Copper Electropolyurushiol

Studies on the Coordination Polymer of Copper Electropolyurushiol

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价