A Convenient Synthesis of Chrysin and Tectochrysin

高等学校化学研究 ›› 2001, Vol. 17 ›› Issue (3): 259-263.

A Convenient Synthesis of Chrysin and Tectochrysin

ZHU Jin-tao¹, CHEN Ying-qi², DAI Li-yan², SUN Li-wen¹, YAO San-jing²

1. Zhejiang Engineering College, Hangzhou 310033, P. R. China;
2. Department of Chemical Engineering, Zhejiang University, Hangzhou 310013, P. R. China

收稿日期:2000-08-02 出版日期:2001-08-24 发布日期:2011-08-04

A Convenient Synthesis of Chrysin and Tectochrysin

ZHU Jin-tao¹, CHEN Ying-qi², DAI Li-yan², SUN Li-wen¹, YAO San-jing²

1. Zhejiang Engineering College, Hangzhou 310033, P. R. China;
2. Department of Chemical Engineering, Zhejiang University, Hangzhou 310013, P. R. China

Received:2000-08-02 Online:2001-08-24 Published:2011-08-04

摘要/Abstract

摘要： Chrysin(1) and tectochrysin(2) were respectively synthesized in four steps from 1,3,5-tri-bromobenzene in an overall yield of 46.8% and that of 37.0% with the key step being theBu4NBr catalyzed hydrolysis of 1-phenyl-3- (2', 4',6'-trimethoxyphenyl)-1,3-propanedione (11) under different conditions.

关键词: Flavone, Chrysin, Tectochrysin, Synthesis

Abstract: Chrysin(1) and tectochrysin(2) were respectively synthesized in four steps from 1,3,5-tri-bromobenzene in an overall yield of 46.8% and that of 37.0% with the key step being theBu4NBr catalyzed hydrolysis of 1-phenyl-3- (2', 4',6'-trimethoxyphenyl)-1,3-propanedione (11) under different conditions.

Key words: Flavone, Chrysin, Tectochrysin, Synthesis

ZHU Jin-tao, CHEN Ying-qi, DAI Li-yan, SUN Li-wen, YAO San-jing. A Convenient Synthesis of Chrysin and Tectochrysin[J]. 高等学校化学研究, 2001, 17(3): 259-263.

ZHU Jin-tao, CHEN Ying-qi, DAI Li-yan, SUN Li-wen, YAO San-jing. A Convenient Synthesis of Chrysin and Tectochrysin[J]. Chemical Research in Chinese Universities, 2001, 17(3): 259-263.

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A Convenient Synthesis of Chrysin and Tectochrysin

A Convenient Synthesis of Chrysin and Tectochrysin

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