NiB as a Non-noble Metal Cocatalyst Electronic Bridge to Enhance the Photocatalytic Hydrogen Production of Cd3(C3N3S3)2

doi:10.1007/s40242-025-4257-z

高等学校化学研究 ›› 2025, Vol. 41 ›› Issue (4): 716-725.doi: 10.1007/s40242-025-4257-z

NiB as a Non-noble Metal Cocatalyst Electronic Bridge to Enhance the Photocatalytic Hydrogen Production of Cd₃(C₃N₃S₃)₂

WANG Kangning¹, YANG Tingting¹, Graham DAWSON², ZHANG Jinfeng¹, SHAO Chunfeng¹, DAI Kai¹

1. Anhui Province Key Laboratory of Pollutant Sensitive Materials and Environmental Remediation, School of Physics and Electronic Information, Huaibei Normal University, Huaibei 235000, P. R. China;
2. Department of Chemistry, Xi'an Jiaotong Liverpool University, Suzhou 215123, P. R. China

收稿日期:2024-12-29 接受日期:2025-01-17 出版日期:2025-08-01 发布日期:2025-07-24
通讯作者: DAI Kai,Daikai940@chnu.edu.cn;ZHANG Jinfeng,jfzhang@chnu.edu.cn;SHAO Chunfeng,shaocf@chnu.edu.cn E-mail:Daikai940@chnu.edu.cn;jfzhang@chnu.edu.cn;shaocf@chnu.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (No. 22278169), the Project of the Excellent Scientific Research and Innovation Team of Education Department of Anhui Province, China (No. 2022AH010028), and the Anhui Provincial Quality Engineering Project, China (No. 2022sx134).

NiB as a Non-noble Metal Cocatalyst Electronic Bridge to Enhance the Photocatalytic Hydrogen Production of Cd₃(C₃N₃S₃)₂

WANG Kangning¹, YANG Tingting¹, Graham DAWSON², ZHANG Jinfeng¹, SHAO Chunfeng¹, DAI Kai¹

1. Anhui Province Key Laboratory of Pollutant Sensitive Materials and Environmental Remediation, School of Physics and Electronic Information, Huaibei Normal University, Huaibei 235000, P. R. China;
2. Department of Chemistry, Xi'an Jiaotong Liverpool University, Suzhou 215123, P. R. China

Received:2024-12-29 Accepted:2025-01-17 Online:2025-08-01 Published:2025-07-24
Supported by:
This work was supported by the National Natural Science Foundation of China (No. 22278169), the Project of the Excellent Scientific Research and Innovation Team of Education Department of Anhui Province, China (No. 2022AH010028), and the Anhui Provincial Quality Engineering Project, China (No. 2022sx134).

摘要/Abstract

摘要： In the field of photocatalytic hydrogen production using Cd₃(C₃N₃S₃)₂ (CdTMT), it is essential to find an efficient and cost-effective material to replace noble metals, such as platinum (Pt) as cocatalysts. In this study, we utilized NiB as a substitute for precious metals. NiB acts as an electron bridge, facilitating the directional transfer of photo generated electrons within CdTMT. This process allows electrons to combine with hydrogen ions to produce hydrogen gas, thereby enhancing the photocatalytic hydrogen production efficiency of the material. The 1%NiB/CdTMT exhibited a good hydrogen production efficiency of 19.71 mmol∙g^-1;∙h^-1; in the experiments, which is 14.07 times that of CdTMT alone. Additionally, we demonstrated through photoluminescence spectroscopy, transient photocurrent response, and ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS) that NiB effectively suppresses the recombination of photogenerated electrons and holes, promoting the separation of photogenerated charge carriers. X-Ray photoelectron spectroscopy (XPS) analysis was conducted to further validate the directional transfer of photogenerated electrons from CdTM through NiB. This work provides unique insights for the rational design and construction of non-noble metal cocatalyst electronic bridge heterojunction photocatalysts.

关键词: Cocatalyst, Photocatalytic hydrogen production, Electronic bridge, CdTMT, NiB

Abstract: In the field of photocatalytic hydrogen production using Cd₃(C₃N₃S₃)₂ (CdTMT), it is essential to find an efficient and cost-effective material to replace noble metals, such as platinum (Pt) as cocatalysts. In this study, we utilized NiB as a substitute for precious metals. NiB acts as an electron bridge, facilitating the directional transfer of photo generated electrons within CdTMT. This process allows electrons to combine with hydrogen ions to produce hydrogen gas, thereby enhancing the photocatalytic hydrogen production efficiency of the material. The 1%NiB/CdTMT exhibited a good hydrogen production efficiency of 19.71 mmol∙g^-1;∙h^-1; in the experiments, which is 14.07 times that of CdTMT alone. Additionally, we demonstrated through photoluminescence spectroscopy, transient photocurrent response, and ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS) that NiB effectively suppresses the recombination of photogenerated electrons and holes, promoting the separation of photogenerated charge carriers. X-Ray photoelectron spectroscopy (XPS) analysis was conducted to further validate the directional transfer of photogenerated electrons from CdTM through NiB. This work provides unique insights for the rational design and construction of non-noble metal cocatalyst electronic bridge heterojunction photocatalysts.

Key words: Cocatalyst, Photocatalytic hydrogen production, Electronic bridge, CdTMT, NiB

WANG Kangning, YANG Tingting, Graham DAWSON, ZHANG Jinfeng, SHAO Chunfeng, DAI Kai. NiB as a Non-noble Metal Cocatalyst Electronic Bridge to Enhance the Photocatalytic Hydrogen Production of Cd₃(C₃N₃S₃)₂[J]. 高等学校化学研究, 2025, 41(4): 716-725.

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NiB as a Non-noble Metal Cocatalyst Electronic Bridge to Enhance the Photocatalytic Hydrogen Production of Cd₃(C₃N₃S₃)₂

NiB as a Non-noble Metal Cocatalyst Electronic Bridge to Enhance the Photocatalytic Hydrogen Production of Cd₃(C₃N₃S₃)₂

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