Syntheses and Photocatalytic Application of Porous Supramolecular Frameworks

doi:10.1007/s40242-025-5074-0

高等学校化学研究 ›› 2025, Vol. 41 ›› Issue (4): 655-665.doi: 10.1007/s40242-025-5074-0

Syntheses and Photocatalytic Application of Porous Supramolecular Frameworks

LU Chongjiu, GONG Yunnan, ZHONG Dichang, LU Tongbu

Institute for New Energy Materials and Low Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, P. R. China

收稿日期:2025-04-21 接受日期:2025-05-26 出版日期:2025-08-01 发布日期:2025-07-24
通讯作者: ZHONG Dichang,dczhong@email.tjut.edu.cn;LU Tongbu,lutongbu@tjut.edu.cn E-mail:dczhong@email.tjut.edu.cn;lutongbu@tjut.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (Nos. 22271218, 22371208), the National Key R&D Program of China (No. 2022YFA1502902), and the Natural Science Foundation of Tianjin City, China (Nos. 24JCZDJC00220, 24JCYBJC00800).

Syntheses and Photocatalytic Application of Porous Supramolecular Frameworks

LU Chongjiu, GONG Yunnan, ZHONG Dichang, LU Tongbu

Institute for New Energy Materials and Low Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, P. R. China

Received:2025-04-21 Accepted:2025-05-26 Online:2025-08-01 Published:2025-07-24
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos. 22271218, 22371208), the National Key R&D Program of China (No. 2022YFA1502902), and the Natural Science Foundation of Tianjin City, China (Nos. 24JCZDJC00220, 24JCYBJC00800).

摘要/Abstract

摘要： Hydrogen-bonded organic frameworks (HOFs) represent a novel class of porous crystalline materials, constructed by linking organic building blocks through hydrogen-bonding interactions. Characterized by well-defined and tailorable architectures, mild synthetic conditions, facile self-healing, and regenerative capabilities, HOFs have garnered substantial attention across diverse research domains, with particular prominence in photocatalysis. This review systematically summarizes the key merits of HOFs and their applications in photocatalytic systems, encompassing CO₂ reduction, hydrogen evolution, hydrogen peroxide generation, and organic transformation reactions. A specific emphasis is placed on analyzing the structure-performance relationships underpinning their catalytic activities. Finally, future research directions for HOFs are discussed, along with the challenges inherent in their practical implementation for photocatalytic applications.

关键词: Hydrogen-bonded organic framework (HOF), Photocatalysis, Porous structure

Abstract: Hydrogen-bonded organic frameworks (HOFs) represent a novel class of porous crystalline materials, constructed by linking organic building blocks through hydrogen-bonding interactions. Characterized by well-defined and tailorable architectures, mild synthetic conditions, facile self-healing, and regenerative capabilities, HOFs have garnered substantial attention across diverse research domains, with particular prominence in photocatalysis. This review systematically summarizes the key merits of HOFs and their applications in photocatalytic systems, encompassing CO₂ reduction, hydrogen evolution, hydrogen peroxide generation, and organic transformation reactions. A specific emphasis is placed on analyzing the structure-performance relationships underpinning their catalytic activities. Finally, future research directions for HOFs are discussed, along with the challenges inherent in their practical implementation for photocatalytic applications.

Key words: Hydrogen-bonded organic framework (HOF), Photocatalysis, Porous structure

LU Chongjiu, GONG Yunnan, ZHONG Dichang, LU Tongbu. Syntheses and Photocatalytic Application of Porous Supramolecular Frameworks[J]. 高等学校化学研究, 2025, 41(4): 655-665.

LU Chongjiu, GONG Yunnan, ZHONG Dichang, LU Tongbu. Syntheses and Photocatalytic Application of Porous Supramolecular Frameworks[J]. Chemical Research in Chinese Universities, 2025, 41(4): 655-665.

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Syntheses and Photocatalytic Application of Porous Supramolecular Frameworks

Syntheses and Photocatalytic Application of Porous Supramolecular Frameworks

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