Co-loading Pd and CeO2 on Silicalite-1 as High-performance Catalyst for Methane Dry Reforming Reaction

doi:10.1007/s40242-024-4194-2

高等学校化学研究 ›› 2025, Vol. 41 ›› Issue (1): 15-20.doi: 10.1007/s40242-024-4194-2

Co-loading Pd and CeO₂ on Silicalite-1 as High-performance Catalyst for Methane Dry Reforming Reaction

XU Jing^1,2, ZHANG Rui^1,2, WANG Ke^1,2, WANG Xiao^1,2, SONG Shuyan^1,2, ZHANG Hongjie^1,2,3

1. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China;
2. School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, P. R. China;
3. Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China

收稿日期:2024-09-21 出版日期:2025-02-01 发布日期:2025-01-18
通讯作者: WANG Xiao,wangxiao@ciac.ac.cn;SONG Shuyan,songsy@ciac.ac.cn;ZHANG Hongjie,hongjie@ciac.ac.cn E-mail:wangxiao@ciac.ac.cn;songsy@ciac.ac.cn;hongjie@ciac.ac.cn
基金资助:
This work was supported by the National Science and Technology Major Project of China (No. 2021YFB3500700), the National Natural Science Foundation of China (Nos. 22020102003, 22025506, 22271274 and U23A20140), and the Science and Technology Development Plan Project of Jilin Province, China (No. 20240402056GH).

Co-loading Pd and CeO₂ on Silicalite-1 as High-performance Catalyst for Methane Dry Reforming Reaction

XU Jing^1,2, ZHANG Rui^1,2, WANG Ke^1,2, WANG Xiao^1,2, SONG Shuyan^1,2, ZHANG Hongjie^1,2,3

1. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China;
2. School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, P. R. China;
3. Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China

Received:2024-09-21 Online:2025-02-01 Published:2025-01-18
Contact: WANG Xiao,wangxiao@ciac.ac.cn;SONG Shuyan,songsy@ciac.ac.cn;ZHANG Hongjie,hongjie@ciac.ac.cn E-mail:wangxiao@ciac.ac.cn;songsy@ciac.ac.cn;hongjie@ciac.ac.cn
Supported by:
This work was supported by the National Science and Technology Major Project of China (No. 2021YFB3500700), the National Natural Science Foundation of China (Nos. 22020102003, 22025506, 22271274 and U23A20140), and the Science and Technology Development Plan Project of Jilin Province, China (No. 20240402056GH).

摘要/Abstract

摘要： The methane dry reforming (DRM) reaction can convert CO₂ and CH₄, both of which contribute to climate change, into syngas, which holds great significance in mitigating specific environmental issues stemming from the greenhouse effect. Nonetheless, the challenges that persist include the substantial energy consumption and the catalyst's susceptibility to deactivation, both of which necessitate solutions. Herein, we developed a catalyst, PdCe/S1, featuring small-sized Pd species and CeO₂ stabilized on pure silicon zeolite (silicalite-1), which is employed in the DRM reaction. It can achieve 97% CH₄ conversion and 98% CO₂ conversion at 750 °C, surpassing binary Pd/CeO₂ and Pd/S1 catalysts. The small size of CeO₂ stabilized by silicalite-1 promotes oxygen defects formation and enhances the CO₂ adsorption capacity. The introduction of silicalite-1 further enhances the interaction between Pd and CeO₂, boosting DRM performance.

关键词: Dry reforming of methane, CeO₂, Zeolite

Abstract: The methane dry reforming (DRM) reaction can convert CO₂ and CH₄, both of which contribute to climate change, into syngas, which holds great significance in mitigating specific environmental issues stemming from the greenhouse effect. Nonetheless, the challenges that persist include the substantial energy consumption and the catalyst's susceptibility to deactivation, both of which necessitate solutions. Herein, we developed a catalyst, PdCe/S1, featuring small-sized Pd species and CeO₂ stabilized on pure silicon zeolite (silicalite-1), which is employed in the DRM reaction. It can achieve 97% CH₄ conversion and 98% CO₂ conversion at 750 °C, surpassing binary Pd/CeO₂ and Pd/S1 catalysts. The small size of CeO₂ stabilized by silicalite-1 promotes oxygen defects formation and enhances the CO₂ adsorption capacity. The introduction of silicalite-1 further enhances the interaction between Pd and CeO₂, boosting DRM performance.

Key words: Dry reforming of methane, CeO₂, Zeolite

XU Jing, ZHANG Rui, WANG Ke, WANG Xiao, SONG Shuyan, ZHANG Hongjie. Co-loading Pd and CeO₂ on Silicalite-1 as High-performance Catalyst for Methane Dry Reforming Reaction[J]. 高等学校化学研究, 2025, 41(1): 15-20.

XU Jing, ZHANG Rui, WANG Ke, WANG Xiao, SONG Shuyan, ZHANG Hongjie. Co-loading Pd and CeO₂ on Silicalite-1 as High-performance Catalyst for Methane Dry Reforming Reaction[J]. Chemical Research in Chinese Universities, 2025, 41(1): 15-20.

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Co-loading Pd and CeO₂ on Silicalite-1 as High-performance Catalyst for Methane Dry Reforming Reaction

Co-loading Pd and CeO₂ on Silicalite-1 as High-performance Catalyst for Methane Dry Reforming Reaction

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