[H2dab][GaB5O10]: an Acentric Galloborate with a 4-Connected Uninodal Framework

doi:10.1007/s40242-024-4130-5

高等学校化学研究 ›› 2024, Vol. 40 ›› Issue (4): 747-752.doi: 10.1007/s40242-024-4130-5

[H₂dab][GaB₅O₁₀]: an Acentric Galloborate with a 4-Connected Uninodal Framework

LIU Wenfang, CHEN Chongan, YANG Guoyu

School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, P. R. China

收稿日期:2024-05-21 出版日期:2024-08-01 发布日期:2024-07-24
通讯作者: YANG Guoyu,ygy@bit.edu.cn E-mail:ygy@bit.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (Nos. 21831001, 21571016, 91122028) and the National Natural Science Foundation of China for Distinguished Young Scholars (No. 20725101).

[H₂dab][GaB₅O₁₀]: an Acentric Galloborate with a 4-Connected Uninodal Framework

LIU Wenfang, CHEN Chongan, YANG Guoyu

School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, P. R. China

Received:2024-05-21 Online:2024-08-01 Published:2024-07-24
Contact: YANG Guoyu,ygy@bit.edu.cn E-mail:ygy@bit.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos. 21831001, 21571016, 91122028) and the National Natural Science Foundation of China for Distinguished Young Scholars (No. 20725101).

摘要/Abstract

摘要： A new acentric galloborate (GBO) [H₂dab][GaB₅O₁₀] (1, 1,4-dab: 1,4-diaminobutane) has been synthesized under solvothermal conditions. The alternation of 4,4-connected GaO₄ and B₅O₁₀ cluster build up the 3D [GaB₅O₁₀]_n^2n‒ uninodal framework, which contains three pairs of helical channels with 8-member ring (MR) and 7-MR apertures, respectively. Compound 1 exhibits a moderate second harmonic generation (SHG) response of 1.8 times that of KH₂PO₄ (KDP), indicating its potential application in UV regions. The acentric uninodal framework in compound 1 represents a new type of zeolitic framework in the GBOs’ family.

关键词: Galloborate, Solvothermal synthesis, Nonlinear optics, Zeolitic framework

Abstract: A new acentric galloborate (GBO) [H₂dab][GaB₅O₁₀] (1, 1,4-dab: 1,4-diaminobutane) has been synthesized under solvothermal conditions. The alternation of 4,4-connected GaO₄ and B₅O₁₀ cluster build up the 3D [GaB₅O₁₀]_n^2n‒ uninodal framework, which contains three pairs of helical channels with 8-member ring (MR) and 7-MR apertures, respectively. Compound 1 exhibits a moderate second harmonic generation (SHG) response of 1.8 times that of KH₂PO₄ (KDP), indicating its potential application in UV regions. The acentric uninodal framework in compound 1 represents a new type of zeolitic framework in the GBOs’ family.

Key words: Galloborate, Solvothermal synthesis, Nonlinear optics, Zeolitic framework

LIU Wenfang, CHEN Chongan, YANG Guoyu. [H₂dab][GaB₅O₁₀]: an Acentric Galloborate with a 4-Connected Uninodal Framework[J]. 高等学校化学研究, 2024, 40(4): 747-752.

LIU Wenfang, CHEN Chongan, YANG Guoyu. [H₂dab][GaB₅O₁₀]: an Acentric Galloborate with a 4-Connected Uninodal Framework[J]. Chemical Research in Chinese Universities, 2024, 40(4): 747-752.

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[H₂dab][GaB₅O₁₀]: an Acentric Galloborate with a 4-Connected Uninodal Framework

[H₂dab][GaB₅O₁₀]: an Acentric Galloborate with a 4-Connected Uninodal Framework

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