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高等学校化学研究 ›› 2024, Vol. 40 ›› Issue (4): 590-610.doi: 10.1007/s40242-024-4147-9

• Reviews • 上一篇    下一篇

Structure Engineering of Layered Double Hydroxides (LDHs) for Heterogeneous Catalysis

GAO Zhexi1, MA Haoran1, WANG Qian1,2, LI Dianqing1, FENG Junting1,2, DUAN Xue1,2   

  1. 1. State Key Laboratory of Chemical Resource Engineering, Beijing Engineering Center for Hierarchical Catalysts, Beijing University of Chemical Technology, Beijing 100029, P. R. China;
    2. Quzhou Institute for Innovation in Resource Chemical Engineering, Quzhou 324000, P. R. China
  • 收稿日期:2024-06-20 出版日期:2024-08-01 发布日期:2024-07-24
  • 通讯作者: WANG Qian,wq@mail.buct.edu.cn;FENG Junting,fengjt@mail.buct.edu.cn E-mail:wq@mail.buct.edu.cn;fengjt@mail.buct.edu.cn
  • 基金资助:
    This work was supported by the National Key R&D Program of China (Nos. 2023YFA1507800, 2023YFA1507801), the National Natural Science Foundation of China (Nos. 22288102, 22208008), and the Fundamental Research Funds for the Central Universities, China (No. ZY2423).

Structure Engineering of Layered Double Hydroxides (LDHs) for Heterogeneous Catalysis

GAO Zhexi1, MA Haoran1, WANG Qian1,2, LI Dianqing1, FENG Junting1,2, DUAN Xue1,2   

  1. 1. State Key Laboratory of Chemical Resource Engineering, Beijing Engineering Center for Hierarchical Catalysts, Beijing University of Chemical Technology, Beijing 100029, P. R. China;
    2. Quzhou Institute for Innovation in Resource Chemical Engineering, Quzhou 324000, P. R. China
  • Received:2024-06-20 Online:2024-08-01 Published:2024-07-24
  • Contact: WANG Qian,wq@mail.buct.edu.cn;FENG Junting,fengjt@mail.buct.edu.cn E-mail:wq@mail.buct.edu.cn;fengjt@mail.buct.edu.cn
  • Supported by:
    This work was supported by the National Key R&D Program of China (Nos. 2023YFA1507800, 2023YFA1507801), the National Natural Science Foundation of China (Nos. 22288102, 22208008), and the Fundamental Research Funds for the Central Universities, China (No. ZY2423).

摘要: Layered double hydroxide (LDH) is regarded as an advanced platform material in catalysis and attracts vast attrition recently. As a kind of two-dimensional layered material, it exhibits great advantages including cation-tunability in layer, lattice limitation, topological transformation, ion exchange and intercalation characteristics. It also can be used as building blocks for composite catalytic materials. Over 100 years, a large number of works have been accomplished and researchers made great progress on investigating the LDH-based catalytic materials. In this review, we summarize representative achievements and significant progress in recent years, which mainly include constructing high entropy catalytic material, high dispersion/stability and interfacial supported catalytic material, composite catalytic materials and nano-reactor based on LDH. Furthermore, through collecting the excellent works, we conclude the future development potential of LDH and provide a perspective.

关键词: Layered double hydroxide (LDH) material, Heterogeneous catalysis, Structure engineering

Abstract: Layered double hydroxide (LDH) is regarded as an advanced platform material in catalysis and attracts vast attrition recently. As a kind of two-dimensional layered material, it exhibits great advantages including cation-tunability in layer, lattice limitation, topological transformation, ion exchange and intercalation characteristics. It also can be used as building blocks for composite catalytic materials. Over 100 years, a large number of works have been accomplished and researchers made great progress on investigating the LDH-based catalytic materials. In this review, we summarize representative achievements and significant progress in recent years, which mainly include constructing high entropy catalytic material, high dispersion/stability and interfacial supported catalytic material, composite catalytic materials and nano-reactor based on LDH. Furthermore, through collecting the excellent works, we conclude the future development potential of LDH and provide a perspective.

Key words: Layered double hydroxide (LDH) material, Heterogeneous catalysis, Structure engineering