Introduction and Influence of Water in the Preparation of Crosslinked PVC Foam by Isocyanate

doi:10.1007/s40242-023-3067-4

高等学校化学研究 ›› 2023, Vol. 39 ›› Issue (5): 782-789.doi: 10.1007/s40242-023-3067-4

Introduction and Influence of Water in the Preparation of Crosslinked PVC Foam by Isocyanate

BI Xiang¹, LI Minggang², LU Min¹, YOU Jiangan^2,3, XUE Jian², YU Haihui¹, JIANG Zhiwei², TANG Tao^2,3

1. College of Chemical Engineering, Northeast Electric Power University, Jilin 132011, P. R. China;
2. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China;
3. College of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, P. R. China

收稿日期:2023-03-08 出版日期:2023-10-01 发布日期:2023-09-26
通讯作者: TANG Tao, JIANG Zhiwei, YU Haihui E-mail:ttang@ciac.ac.cn;jiangzw@ciac.ac.cn;hhyu@neepu.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (No.52173050) and the National Key Research and Development Program of China (No.2021YFB3702800).

Introduction and Influence of Water in the Preparation of Crosslinked PVC Foam by Isocyanate

BI Xiang¹, LI Minggang², LU Min¹, YOU Jiangan^2,3, XUE Jian², YU Haihui¹, JIANG Zhiwei², TANG Tao^2,3

1. College of Chemical Engineering, Northeast Electric Power University, Jilin 132011, P. R. China;
2. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China;
3. College of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, P. R. China

Received:2023-03-08 Online:2023-10-01 Published:2023-09-26
Contact: TANG Tao, JIANG Zhiwei, YU Haihui E-mail:ttang@ciac.ac.cn;jiangzw@ciac.ac.cn;hhyu@neepu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (No.52173050) and the National Key Research and Development Program of China (No.2021YFB3702800).

摘要/Abstract

摘要： In the preparation process of crosslinked polyvinyl chloride (c-PVC) foam by isocyanate, the formulated mixture is generally required to be carried out under the condition of isolated water, so as to avoid the mixing difficulties caused by the reaction between the introduced water and isocyanate. In this paper, NaHCO₃ was added to the mixture to indirectly introduce water into the system, and the effects of NaHCO₃ on the cell structure and curing time of c-PVC foam were investigated. The results showed that NaHCO₃ not only played a role of foaming agent, but also was a good nucleating agent for cells. At the same time, the introduction of NaHCO₃ held back the exudation of modified diphenylmethane-4,4'-diisocyanate (MDI) on the cell wall. The effects of NaHCO₃ on the cell structure and aggregation structure of c-PVC foam were studied by thermogravimetric analysis, infrared spectroscopy and scanning electron microscopy. The results showed that decomposition of NaHCO₃ occurred during the molding stage, which made small amount of MDI react with water to form polyurea, improved the compatibility of MDI with PVC and inhibited the exudation of MDI.

关键词: Crosslinked PVC foam, Isocyanate, Water, Curing, Sodium bicarbonate

Abstract: In the preparation process of crosslinked polyvinyl chloride (c-PVC) foam by isocyanate, the formulated mixture is generally required to be carried out under the condition of isolated water, so as to avoid the mixing difficulties caused by the reaction between the introduced water and isocyanate. In this paper, NaHCO₃ was added to the mixture to indirectly introduce water into the system, and the effects of NaHCO₃ on the cell structure and curing time of c-PVC foam were investigated. The results showed that NaHCO₃ not only played a role of foaming agent, but also was a good nucleating agent for cells. At the same time, the introduction of NaHCO₃ held back the exudation of modified diphenylmethane-4,4'-diisocyanate (MDI) on the cell wall. The effects of NaHCO₃ on the cell structure and aggregation structure of c-PVC foam were studied by thermogravimetric analysis, infrared spectroscopy and scanning electron microscopy. The results showed that decomposition of NaHCO₃ occurred during the molding stage, which made small amount of MDI react with water to form polyurea, improved the compatibility of MDI with PVC and inhibited the exudation of MDI.

Key words: Crosslinked PVC foam, Isocyanate, Water, Curing, Sodium bicarbonate

BI Xiang, LI Minggang, LU Min, YOU Jiangan, XUE Jian, YU Haihui, JIANG Zhiwei, TANG Tao. Introduction and Influence of Water in the Preparation of Crosslinked PVC Foam by Isocyanate[J]. 高等学校化学研究, 2023, 39(5): 782-789.

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Introduction and Influence of Water in the Preparation of Crosslinked PVC Foam by Isocyanate

Introduction and Influence of Water in the Preparation of Crosslinked PVC Foam by Isocyanate

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