Preparation of Quaternary FeCoMoCu Metal Oxides for Oxygen Evolution Reaction

doi:10.1007/s40242-022-2040-y

高等学校化学研究 ›› 2022, Vol. 38 ›› Issue (3): 823-828.doi: 10.1007/s40242-022-2040-y

Preparation of Quaternary FeCoMoCu Metal Oxides for Oxygen Evolution Reaction

HAO Zhimin¹, LIU Dapeng¹, GE Huaiyun¹, ZUO Xintao¹, FENG Xilan¹, SHAO Mingzhe¹, YU Haohan¹, YUAN Guobao¹, and ZHANG Yu^1,2

1. Key Laboratory of Bio-inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry, Beihang University, Beijing 100191, P. R. China;
2. Beijing Advanced Innovation Center for Biomedical Engineering, Beihang University, Beijing 100191, P. R. China

收稿日期:2022-01-30 修回日期:2022-03-16 出版日期:2022-06-01 发布日期:2022-05-26
通讯作者: LIU Dapeng, ZHANG Yu E-mail:jade@buaa.edu.cn;liudp@buaa.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (Nos.21771013, 51925202, 51972008).

Preparation of Quaternary FeCoMoCu Metal Oxides for Oxygen Evolution Reaction

HAO Zhimin¹, LIU Dapeng¹, GE Huaiyun¹, ZUO Xintao¹, FENG Xilan¹, SHAO Mingzhe¹, YU Haohan¹, YUAN Guobao¹, and ZHANG Yu^1,2

1. Key Laboratory of Bio-inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry, Beihang University, Beijing 100191, P. R. China;
2. Beijing Advanced Innovation Center for Biomedical Engineering, Beihang University, Beijing 100191, P. R. China

Received:2022-01-30 Revised:2022-03-16 Online:2022-06-01 Published:2022-05-26
Contact: LIU Dapeng, ZHANG Yu E-mail:jade@buaa.edu.cn;liudp@buaa.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos.21771013, 51925202, 51972008).

摘要/Abstract

摘要： Molybdenum doping is an effective way to improve the oxygen evolution reaction(OER) properties of catalysts, which can efficiently improve the electronic conductivity, mass transport process, and intrinsic activity of transition metal oxides or hydroxides, especially for those multi-component oxides with more abundant active sites. Herein, we have prepared a quaternary FeCoMoCu metal oxide on Cu foam(FeCoMoCuO_x@Cu) as an efficient OER catalyst. As expected, FeCoMoCuO_x@Cu could exhibit a low overpotential(252 mV at the current density of 10 mA/cm²) and exceptional stability(10000 cycles of CV scans or constant electrolysis for 48 h).

关键词: Oxygen evolution reaction(OER), Electrocatalysis, Transition metal oxide, Molybdenum doping

Abstract: Molybdenum doping is an effective way to improve the oxygen evolution reaction(OER) properties of catalysts, which can efficiently improve the electronic conductivity, mass transport process, and intrinsic activity of transition metal oxides or hydroxides, especially for those multi-component oxides with more abundant active sites. Herein, we have prepared a quaternary FeCoMoCu metal oxide on Cu foam(FeCoMoCuO_x@Cu) as an efficient OER catalyst. As expected, FeCoMoCuO_x@Cu could exhibit a low overpotential(252 mV at the current density of 10 mA/cm²) and exceptional stability(10000 cycles of CV scans or constant electrolysis for 48 h).

Key words: Oxygen evolution reaction(OER), Electrocatalysis, Transition metal oxide, Molybdenum doping

HAO Zhimin, LIU Dapeng, GE Huaiyun, ZUO Xintao, FENG Xilan, SHAO Mingzhe, YU Haohan, YUAN Guobao, and ZHANG Yu. Preparation of Quaternary FeCoMoCu Metal Oxides for Oxygen Evolution Reaction[J]. 高等学校化学研究, 2022, 38(3): 823-828.

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Preparation of Quaternary FeCoMoCu Metal Oxides for Oxygen Evolution Reaction

Preparation of Quaternary FeCoMoCu Metal Oxides for Oxygen Evolution Reaction

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