Hollow Micro-/Nanostructure Reviving Lithium-sulfur Batteries

doi:10.1007/s40242-020-0115-2

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (3): 313-319.doi: 10.1007/s40242-020-0115-2

Hollow Micro-/Nanostructure Reviving Lithium-sulfur Batteries

ZHAO Jilu^1,2, YANG Mei¹, YANG Nailiang^1,2, WANG Jiangyan^1,2, WANG Dan^1,2

1. State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

收稿日期:2020-04-16 修回日期:2020-05-05 出版日期:2020-06-01 发布日期:2020-05-30
通讯作者: WANG Jiangyan, WANG Dan E-mail:jywang@ipe.ac.cn;danwang@ipe.ac.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21820102002, 21590795, 51661165013) and the Scientific Instrument Developing Project of the Chinese Academy of Sciences(No.YZ201623).

Hollow Micro-/Nanostructure Reviving Lithium-sulfur Batteries

ZHAO Jilu^1,2, YANG Mei¹, YANG Nailiang^1,2, WANG Jiangyan^1,2, WANG Dan^1,2

1. State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received:2020-04-16 Revised:2020-05-05 Online:2020-06-01 Published:2020-05-30
Contact: WANG Jiangyan, WANG Dan E-mail:jywang@ipe.ac.cn;danwang@ipe.ac.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21820102002, 21590795, 51661165013) and the Scientific Instrument Developing Project of the Chinese Academy of Sciences(No.YZ201623).

摘要/Abstract

摘要： High-energy-density lithium-sulfur(Li-S) batteries are drawing dramatic research interests to fulfill the ever-increasing demands of electrical vehicles. However, challenges with the insulating property of sulfur and its lithiation products and its large volume expansion, and the shuttle effect of lithium polysulfides, hinder the commercial application of Li-S batteries. Lots of material design concepts have been developed to address the failure modes. Among them, hollow micro-/nanostructures with abundant compositional and geometrical feasibility have been proved fruitful in addressing the current obstacles of Li-S batteries. Here, typical examples of designing hollow micro-/nanostructures to address the problems of Li-S batteries and simultaneously improve the practical capacity and lifespan are highlighted. In particular, the great effect of structural engineering on minimizing volume change, inhibiting the shuttle effect and catalyzing polysulfide conversion are discussed systematically. Finally, future directions of hollow nanostructure design to enhance the progress of Li-S batteries are also provided.

关键词: Hollow, Micro-/nanostructure, Lithium-sulfur battery

Abstract: High-energy-density lithium-sulfur(Li-S) batteries are drawing dramatic research interests to fulfill the ever-increasing demands of electrical vehicles. However, challenges with the insulating property of sulfur and its lithiation products and its large volume expansion, and the shuttle effect of lithium polysulfides, hinder the commercial application of Li-S batteries. Lots of material design concepts have been developed to address the failure modes. Among them, hollow micro-/nanostructures with abundant compositional and geometrical feasibility have been proved fruitful in addressing the current obstacles of Li-S batteries. Here, typical examples of designing hollow micro-/nanostructures to address the problems of Li-S batteries and simultaneously improve the practical capacity and lifespan are highlighted. In particular, the great effect of structural engineering on minimizing volume change, inhibiting the shuttle effect and catalyzing polysulfide conversion are discussed systematically. Finally, future directions of hollow nanostructure design to enhance the progress of Li-S batteries are also provided.

Key words: Hollow, Micro-/nanostructure, Lithium-sulfur battery

ZHAO Jilu, YANG Mei, YANG Nailiang, WANG Jiangyan, WANG Dan. Hollow Micro-/Nanostructure Reviving Lithium-sulfur Batteries[J]. 高等学校化学研究, 2020, 36(3): 313-319.

ZHAO Jilu, YANG Mei, YANG Nailiang, WANG Jiangyan, WANG Dan. Hollow Micro-/Nanostructure Reviving Lithium-sulfur Batteries[J]. Chemical Research in Chinese Universities, 2020, 36(3): 313-319.

参考文献 50

[1]	Ji X. L., Lee K. T., Nazar L. F., Nat. Mater., 2009, 8, 500
[2]	Elazari R., Salitra G., Garsuch A., Panchenko A., Aurbach D., Adv. Mater., 2011, 23, 5641
[3]	Zhao M. Q., Zhang Q., Huang J. Q., Tian G. L., Nie J. Q., Peng H. J., Wei F., Nat. Commun., 2014, 5, 1
[4]	Zhang J., Yang C. P., Yin Y. X., Wan L. J., Guo Y. G., Adv. Mater., 2016, 28, 9539
[5]	Lyu Z. Y., Xu D., Yang L. J., Che R. C., Feng R., Zhao J., Li Y., Wu Q., Wang X. Z., Hu Z., Nano Energy, 2015, 12, 657
[6]	Evers S., Yim T., Nazar L. F., J. Phys. Chem. C, 2012, 116, 19653
[7]	Zhang J., Shi Y., Ding Y., Zhang W. K., Yu G. H., Nano Lett., 2016, 16, 7276
[8]	Shi Y., Peng L. L., Ding Y., Zhao Y., Yu G. H., Chem. Soc. Rev., 2015, 44, 6684
[9]	Lai X. Y., Halpert J. E., Wang D., Energy Environ. Sci., 2012, 5, 5604
[10]	Qi J., Lai X. Y., Wang J. Y., Tang H. J., Ren H., Yang Y., Jin Q., Zhang L. J., Yu R. B., Ma G. H., Su Z. G., Zhao H. J., Wang D., Chem. Soc. Rev., 2015, 44, 6749
[11]	Mao D., Wan J. W., Wang J. Y., Wang D., Adv. Mater., 2019, 31, 1802874
[12]	Wang J. Y., Tang H. J., Zhang L. J., Ren H., Yu R. B., Jin Q., Qi J., Mao D., Yang M., Wang Y., Liu P., Zhang Y., Wen Y. R., Gu L., Ma G. H., Su Z. G., Tang Z. Y., Zhao H. J., Wang D., Nat. Energy, 2016, 1, 16050
[13]	Jiao C. W., Wang Z. M., Zhao X. X., Wang H., Wang J., Yu R. B., Wang D., Angew. Chem. Int. Ed., 2019, 58, 996
[14]	Wang J. Y., Yang N. L., Tang H. J., Dong Z. H., Jin Q., Yang M., Kisailus D., Zhao H. J., Tang Z. Y., Wang D., Angew. Chem. Int. Ed., 2013, 52, 6417
[15]	Ren H., Yu R. B., Wang J. Y., Jin Q., Yang M., Mao D., Kisailus D., Zhao H. J., Wang D., Nano Lett., 2014, 14, 6679
[16]	Zhao X. X., Wang J. Y., Yu R. B., Wang D., J. Am. Chem. Soc., 2018, 140, 17114
[17]	Wang J. Y., Tang H. J., Ren H., Yu R. B., Qi J., Mao D., Zhao H. J., Wang D., Adv. Sci., 2014, 1, 1400011
[18]	Zhao X. X., Yu R. B., Tang H. J., Mao D., Qi J., Wang B., Zhang Y., Zhao H. J., Hu W. P., Wang D., Adv. Mater., 2017, 29, 1700550
[19]	Xu S. M., Hessel C. M., Ren H., Yu R. B., Jin Q., Yang M., Zhao H. J., Wang D., Energy Environ. Sci., 2014, 7, 632
[20]	Wang J. Y.., Tang H. J., Wang H., Yu R. B., Wang D., Mater. Chem. Front., 2017, 1, 414
[21]	Wang D. W., Zeng Q. C., Zhou G. M., Yin L. C., Li F., Cheng H. M., Gentle I. R., Lu G. Q. M., J. Mater. Chem. A, 2013, 1, 9382
[22]	He G., Evers S., Liang X., Cuisinier M., Garsuch A., Nazar L. F., ACS Nano, 2013, 7, 10920
[23]	Zhang C. F., Wu H. B., Yuan C. Z., Guo Z. P., Lou X. W., Angew. Chem. Int. Ed., 2012, 51, 9592
[24]	Seh Z. W., Li W. Y., Cha J. J., Zheng G. Y., Yang Y., McDowell M. T., Hsu P. C., Cui Y., Nat. Commun., 2013, 4, 1331
[25]	Luo D., Li G. R., Deng Y. P., Zhang Z., Li J. D., Liang R. L., Li M., Jiang Y., Zhang W. W., Liu Y. S., Lei W., Yu A. P., Chen Z. W., Adv. Energy Mater., 2019, 9, 1900228
[26]	Mi K., Jiang Y., Feng J. K., Qian Y. T., Xiong S. L., Adv. Funct. Mater., 2016, 26, 1571
[27]	Pei F., An T. H., Zang J., Zhao X. J., Fang X. L., Zheng M. S., Dong Q. F., Zheng N. F., Adv. Energy Mater., 2016, 6, 1502539
[28]	Liang Z., Zheng G. Y., Li W. Y., Seh Z. W., Yao H. B., Yan K., Kong D. S., Cui Y., ACS Nano, 2014, 8, 5249
[29]	Salhabi E. H. M., Zhao J. L., Wang J. Y., Yang M., Wang B., Wang D., Angew. Chem. Int. Ed., 2019, 58, 9078
[30]	Chen T., Ma L. B., Cheng B. R., Chen R. P., Hu Y., Zhu G. Y., Wang Y. R., Liang J., Tie Z. X., Liu J., Jin Z., Nano Energy, 2017, 38, 239
[31]	Gao X. J., Yang X. F., Li M. S., Sun Q., Liang J. N., Luo J., Wang J. W., Li W. H., Liang J. W., Liu Y. L., Wang S. Z., Hu Y. F., Xiao Q. F., Li R. Y., Sham T. K., Sun X. L., Adv. Funct. Mater., 2019, 29, 1806724
[32]	Ye C., Zhang L., Guo C. X., Li D. D., Vasileff A., Wang H. H., Qiao S. Z., Adv. Funct. Mater., 2017, 27, 1702524
[33]	Chung S. H., Manthiram A., J. Phys. Chem. Lett., 2014, 5, 1978
[34]	Fang D. L., Wang Y. L., Liu X. Z., Yu J., Qian C., Chen S. M., Wang X., Zhang S. J., ACS Nano, 2019, 13, 1563
[35]	Chen X. X., Ding X. Y., Wang C. S., Feng Z. Y., Xu L. Q., Gao X., Zhai Y. J., Wang D. B., Nanoscale, 2018, 10, 13694
[36]	Li S. S., Jin B., Li H., Dong C. W., Zhang B., Xu J. H., Jiang Q., J. Electrochem. Soc., 2017, 806, 41
[37]	Ma J. S., Yu M. P., Ye H. Y., Song H. Q., Wang D. X., Zhao Y. T., Gong W., Qiu H., Mater. Chem. Front., 2019, 3, 1807
[38]	Zhou G. M., Li L., Ma C. Q., Wang S. G., Shi Y., Koratkar N., Ren W. C., Li F., Cheng H. M., Nano Energy, 2015, 11, 356
[39]	Du H. P., Zhang Z. H., He J. J., Cui Z. L., Chai J. C., Ma J., Yang Z., Huang C. S., Cui G. L., Small, 2017, 13, 1702277
[40]	Xu F., Tang Z. W., Huang S. Q., Chen L. Y., Liang Y. R., Mai W. C., Zhong H., Fu R. W., Wu D. C., Nat Commun., 2015, 6, 7221
[41]	Dong Y., Ben T., Chem. Res. Chinese Universities, 2019, 35(4), 654
[42]	Paraknowitsch J. P., Thomas A., Energy Environ. Sci., 2013, 6, 2839
[43]	Zhou W. D., Xiao X. C., Cai M., Yang L., Nano Lett., 2014, 14, 5250
[44]	Mi K., Chen S. W., Xi B. J, Kai S. S., Jiang Y., Feng J. K., Qian Y. T, Xiong S. L., Adv. Funct. Mater., 2017, 27, 1604265
[45]	Peng Y. Y., Zhang Y. Y., Huang J. X., Wang Y. H., Li H., Hwang B. J., Zhao J. B., Carbon, 2017, 124, 23
[46]	Zhou G. M., Zhao Y. B., Manthiram A., Adv. Energy Mater., 2015, 5, 1402263
[47]	Wang C., Wang J. Y., Hu W. P., Wang D., Chem. Res. Chinese Universities, 2020, 36(1), 68
[48]	Jeong Y. C., Kim J. H., Nam S., Park C. R., Yang S. J., Adv. Funct. Mater., 2018, 28, 1707411
[49]	Fan W., Zhang L. S., Liu T. X., Mater. Chem. Front., 2018, 2, 235
[50]	Su Y. S., Manthiram A., Nat. Commun., 2012, 3, 1166

Hollow Micro-/Nanostructure Reviving Lithium-sulfur Batteries

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