Intercalation Effect in NiAl-layered Double Hydroxide Nanosheets for CO2 Reduction Under Visible Light

doi:10.1007/s40242-020-9096-3

高等学校化学研究 ›› 2020, Vol. 36 ›› Issue (1): 127-133.doi: 10.1007/s40242-020-9096-3

Intercalation Effect in NiAl-layered Double Hydroxide Nanosheets for CO₂ Reduction Under Visible Light

KIPKORIR Peter, TAN Ling, REN Jing, ZHAO Yufei, SONG Yu-Fei

State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China

收稿日期:2019-12-11 修回日期:2020-01-02 出版日期:2020-02-01 发布日期:2020-01-20
通讯作者: ZHAO Yufei, SONG Yu-Fei E-mail:zhaoyufei@mail.buct.edu.cn;songyf@mail.buct.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.U1707603, 21625101, 21521005, U1507102 and 21878008), the National Key Research and Development Program of China(No.2017YFB0307303), the National Basic Research Program(973 Program) of China(No.2014CB932104), the Natural Science Foundation of Beijing, China(Nos.2182047, 2202036) and the Fundamental Research Funds for the Central Universities, China(No.XK1802-6).

Intercalation Effect in NiAl-layered Double Hydroxide Nanosheets for CO₂ Reduction Under Visible Light

KIPKORIR Peter, TAN Ling, REN Jing, ZHAO Yufei, SONG Yu-Fei

State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China

Received:2019-12-11 Revised:2020-01-02 Online:2020-02-01 Published:2020-01-20
Contact: ZHAO Yufei, SONG Yu-Fei E-mail:zhaoyufei@mail.buct.edu.cn;songyf@mail.buct.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.U1707603, 21625101, 21521005, U1507102 and 21878008), the National Key Research and Development Program of China(No.2017YFB0307303), the National Basic Research Program(973 Program) of China(No.2014CB932104), the Natural Science Foundation of Beijing, China(Nos.2182047, 2202036) and the Fundamental Research Funds for the Central Universities, China(No.XK1802-6).

摘要/Abstract

摘要： Photocatalytic reduction of CO₂(CO₂PR) to valuable solar fuels is considered as a promising route to the amelioration of fossil fuel conundrum and the mitigation of greenhouse gases. Although progress has been made to enhance CO₂PR performance, the available method that can promote the selectivity of CO₂PR products remains to be a challenge. In this work, we synthesized NO₃^- or CO₃^2- intercalated NiAl-layered double hydroxide(NiAl-LDH) photocatalysts and investigated the performance of CO₂PR in the presence of an electron donor and a photosensitizer. Compared with Ni₂Al-CO₃^2-, Ni₂Al-NO₃^- exhibited superior catalytic performance in the CO₂PR, and the resulted selectivity of CH₄ in Ni₂Al-NO₃^-(6.1%) was 12.2 times that of Ni₂Al-CO₃^2-(0.5%) under visible light irradiation. X-Ray absorption fine structure(XAFS) result reveals a relative abundance of defects in Ni₂Al-NO₃^-, which played as active sites and promoted charge transfer in CO₂PR for the efficient CH₄ evolution.

关键词: Visible light catalysis, CO₂ photoreduction, Layered double hydroxide, Intercalated anion, Defect

Abstract: Photocatalytic reduction of CO₂(CO₂PR) to valuable solar fuels is considered as a promising route to the amelioration of fossil fuel conundrum and the mitigation of greenhouse gases. Although progress has been made to enhance CO₂PR performance, the available method that can promote the selectivity of CO₂PR products remains to be a challenge. In this work, we synthesized NO₃^- or CO₃^2- intercalated NiAl-layered double hydroxide(NiAl-LDH) photocatalysts and investigated the performance of CO₂PR in the presence of an electron donor and a photosensitizer. Compared with Ni₂Al-CO₃^2-, Ni₂Al-NO₃^- exhibited superior catalytic performance in the CO₂PR, and the resulted selectivity of CH₄ in Ni₂Al-NO₃^-(6.1%) was 12.2 times that of Ni₂Al-CO₃^2-(0.5%) under visible light irradiation. X-Ray absorption fine structure(XAFS) result reveals a relative abundance of defects in Ni₂Al-NO₃^-, which played as active sites and promoted charge transfer in CO₂PR for the efficient CH₄ evolution.

Key words: Visible light catalysis, CO₂ photoreduction, Layered double hydroxide, Intercalated anion, Defect

KIPKORIR Peter, TAN Ling, REN Jing, ZHAO Yufei, SONG Yu-Fei. Intercalation Effect in NiAl-layered Double Hydroxide Nanosheets for CO₂ Reduction Under Visible Light[J]. 高等学校化学研究, 2020, 36(1): 127-133.

KIPKORIR Peter, TAN Ling, REN Jing, ZHAO Yufei, SONG Yu-Fei. Intercalation Effect in NiAl-layered Double Hydroxide Nanosheets for CO₂ Reduction Under Visible Light[J]. Chemical Research in Chinese Universities, 2020, 36(1): 127-133.

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Intercalation Effect in NiAl-layered Double Hydroxide Nanosheets for CO₂ Reduction Under Visible Light

Intercalation Effect in NiAl-layered Double Hydroxide Nanosheets for CO₂ Reduction Under Visible Light

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