Freeze-drying-assisted Synthesis of Mesoporous CoMoO4 Nanosheets as Anode Electrode Material for Enhanced Lithium Batteries

doi:10.1007/s40242-019-8316-1

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (2): 261-270.doi: 10.1007/s40242-019-8316-1

Freeze-drying-assisted Synthesis of Mesoporous CoMoO₄ Nanosheets as Anode Electrode Material for Enhanced Lithium Batteries

WANG Wei¹, WANG Tao¹, FAN Xuecheng¹, ZHANG Cuilin¹, HU Jinxing¹, CHEN Hui¹, FANG Zhenxing¹, YAN Jiefeng¹, LIU Bing²

1. College of Science & Technology, Ningbo University, Ningbo 315212, P. R. China;
2. State Key Laboratory of Bio-Fibers and Eco-Textiles, Qingdao University, Qingdao 266071, P. R. China

收稿日期:2018-09-28 修回日期:2018-12-25 出版日期:2019-04-01 发布日期:2019-04-30
通讯作者: WANG Wei, LIU Bing E-mail:wangwei4@nbu.edu.cn;bing_liu@qdu.edu.cn
基金资助:
Supported by the Natural Science Foundation of Zhejiang Province, China(No.LQ18B010001), the Scientific Research Fund of Zhejiang Provincial Education Department, China(Nos.Y201737041, Y201839092), the Scientific Research Fund of Ningbo City, China(Nos.2018A610083, 2017A610299), the Scientific Research Fund of Ningbo University, China(Nos.XYL17007, 2018SRIP0041), the National College Students' Innovation and Entrepreneurship Training Program, China(No.201813277003), the National Natural Science Foundation of China(No.21701095), the Natural Science Foundation of Shandong Province, China(No.ZR2017BEM007), the China Postdoctoral Science Foundation(No.2017M622131) and the Program of Science and Technology for Higher Education in Shandong Province, China(No.J17KA010).

Freeze-drying-assisted Synthesis of Mesoporous CoMoO₄ Nanosheets as Anode Electrode Material for Enhanced Lithium Batteries

WANG Wei¹, WANG Tao¹, FAN Xuecheng¹, ZHANG Cuilin¹, HU Jinxing¹, CHEN Hui¹, FANG Zhenxing¹, YAN Jiefeng¹, LIU Bing²

1. College of Science & Technology, Ningbo University, Ningbo 315212, P. R. China;
2. State Key Laboratory of Bio-Fibers and Eco-Textiles, Qingdao University, Qingdao 266071, P. R. China

Received:2018-09-28 Revised:2018-12-25 Online:2019-04-01 Published:2019-04-30
Contact: WANG Wei, LIU Bing E-mail:wangwei4@nbu.edu.cn;bing_liu@qdu.edu.cn
Supported by:
Supported by the Natural Science Foundation of Zhejiang Province, China(No.LQ18B010001), the Scientific Research Fund of Zhejiang Provincial Education Department, China(Nos.Y201737041, Y201839092), the Scientific Research Fund of Ningbo City, China(Nos.2018A610083, 2017A610299), the Scientific Research Fund of Ningbo University, China(Nos.XYL17007, 2018SRIP0041), the National College Students' Innovation and Entrepreneurship Training Program, China(No.201813277003), the National Natural Science Foundation of China(No.21701095), the Natural Science Foundation of Shandong Province, China(No.ZR2017BEM007), the China Postdoctoral Science Foundation(No.2017M622131) and the Program of Science and Technology for Higher Education in Shandong Province, China(No.J17KA010).

摘要/Abstract

摘要： A facile and green freeze-drying-assisted method was proposed to synthesize CoMoO₄ mesoporous nanosheets(MPNSs). The resulting product exhibits a high specific capacity and good rate performance when evaluated as an anode material for lithium-ion batteries(LIBs). The reversible specific capacity can be kept at 1105.2 mA·h·g^-1 after 100 cycles at a current density of 0.2 A/g. Even at the current densities of 1 and 4 A/g, the CoMoO₄ MPNSs electrode can still retain the reversible capacities of 1148.7 and 540 mA·h·g^-1, respectively. Furthermore, the full cell(LiFePO₄ cathode/CoMoO₄ MPNSs anode) displays a stable discharge capacity of 146.7 mA·h·g^-1 at 0.1 C (1 C=170 mA/g) together with an initial coulombic efficiency of 98.2%. In addition, the CoMoO₄ crystal structure is destroyed and reduced into Co⁰ and Mo⁰ in the first discharge process. In the subsequent cycles, the attractive Li storage properties come from the reversible conversions between Co/Co²⁺ and Mo/Mo⁶⁺. The improved electroche-mical performance of CoMoO₄ MPNSs is mainly attributed to their unique porous structures, which not only possess a good ion diffusion and electronic conduction pathway, but also provide many cavities to alleviate the volume changes during repeated cycling. This work offers a new perspective to the design of other porous electrode materials with a good energy storage performance.

关键词: Freeze-drying, Mesoporous nanosheet, CoMoO₄, Anode material, Lithium storage

Abstract: A facile and green freeze-drying-assisted method was proposed to synthesize CoMoO₄ mesoporous nanosheets(MPNSs). The resulting product exhibits a high specific capacity and good rate performance when evaluated as an anode material for lithium-ion batteries(LIBs). The reversible specific capacity can be kept at 1105.2 mA·h·g^-1 after 100 cycles at a current density of 0.2 A/g. Even at the current densities of 1 and 4 A/g, the CoMoO₄ MPNSs electrode can still retain the reversible capacities of 1148.7 and 540 mA·h·g^-1, respectively. Furthermore, the full cell(LiFePO₄ cathode/CoMoO₄ MPNSs anode) displays a stable discharge capacity of 146.7 mA·h·g^-1 at 0.1 C (1 C=170 mA/g) together with an initial coulombic efficiency of 98.2%. In addition, the CoMoO₄ crystal structure is destroyed and reduced into Co⁰ and Mo⁰ in the first discharge process. In the subsequent cycles, the attractive Li storage properties come from the reversible conversions between Co/Co²⁺ and Mo/Mo⁶⁺. The improved electroche-mical performance of CoMoO₄ MPNSs is mainly attributed to their unique porous structures, which not only possess a good ion diffusion and electronic conduction pathway, but also provide many cavities to alleviate the volume changes during repeated cycling. This work offers a new perspective to the design of other porous electrode materials with a good energy storage performance.

Key words: Freeze-drying, Mesoporous nanosheet, CoMoO₄, Anode material, Lithium storage

WANG Wei, WANG Tao, FAN Xuecheng, ZHANG Cuilin, HU Jinxing, CHEN Hui, FANG Zhenxing, YAN Jiefeng, LIU Bing. Freeze-drying-assisted Synthesis of Mesoporous CoMoO₄ Nanosheets as Anode Electrode Material for Enhanced Lithium Batteries[J]. 高等学校化学研究, 2019, 35(2): 261-270.

参考文献

[1] Xin T., Diao F. Y., Li C., Feng H. L., Liu G. J., Zou J. J., Ding Y. H., Liu B., Wang Y. Q., Mater. Res. Bull., 2018, 99, 196
[2] Zou J. J., Liu B., Liu H. Q., Ding Y. H., Xin T., Wang Y. Q., Mater. Res. Bull., 2018, 107, 468
[3] Ding Y. H., Liu B., Zou J. J., Liu H. Q., Xin T., Xia L. H., Wang Y. Q., Mater. Res. Bull., 2018, 106, 7
[4] Wang C., Wu L. X., Wang H., Zuo W. H., Li Y. Y., Liu J. P., Adv. Funct. Mater., 2015, 25, 3524
[5] Wang Z. Y., Madhavi S., Lou X. W., J. Phys. Chem. C, 2012, 116, 12508
[6] Sakaushi K., Thomas J., Kaskel S., Eckert J., Chem. Mater., 2013, 25, 2557
[7] Ahn J. H., Park G. D., Kang Y. C., Lee J. H., Electrochim. Acta, 2015, 174, 102
[8] Cherian C. T., Reddy M. V., Haur S. C., Chowdari B. V. R., ACS Appl. Mater. Interfaces, 2013, 5, 918
[9] Xue R. N., Hong W., Pan Z., Jin W., Zhao H. L., Song Y. H., Zhou J. K., Liu Y., Electrochim. Acta, 2016, 222, 838
[10] Wei H. X., Yang J., Zhang Y. F., Qian Y., Geng H. B., J. Colloid Interf. Sci., 2018, 524, 256
[11] Zhang L. F., He W. J., Ling M., Shen K. C., Liu Y., Guo S. W., Electrochim. Acta, 2017, 252, 322
[12] You J. F., Xin L., Yu X., Zhou X., Liu Y., Appl. Phys. A, 2018, 124, 271
[13] Ju Z. C., Zhang E., Zhao Y. L., Xing Z., Zhuang Q. C., Qiang Y. H., Qian Y. T., Small, 2015, 11, 4753
[14] Liu H. W., Tan L., Ionics, 2010, 16, 57
[15] Ding Y., Wan Y., Min Y. L., Zhang W., Yu S. H., Inorg. Chem., 2008, 47, 7813
[16] Yu H., Guan C., Rui X. H., Ouyang B., Yadian B. L., Huang Y. Z., Zhang H., Hoster H. E., Fan H. J., Yan Q. Y., Nanoscale, 2014, 6, 10556
[17] Ko Y. N., Kang Y. C., Park S. B., RSC Adv., 2014, 4, 17873
[18] Kim J. K., Kim J. H., Kang Y. C., Chem. Eng. J., 2018, 333, 665
[19] Wang Y. S., Sun Y. F., Zhang X., Wen Y. H., Guo J. X., RSC Adv., 2016, 6, 51710
[20] Yao J. Y., Gong Y. J., Yang S. B., Xiao P., Zhang Y. H., Keyshar K., Ye G. L., Ozden S., Vajtai R., Ajayan P. M., ACS Appl. Mater. Interfaces, 2014, 6, 20414
[21] Yang T., Zhang H. N., Luo Y. Z., Mei L., Guo D., Li Q. H., Wang T. H., Electrochim. Acta, 2015, 158, 327
[22] Guo J. X., Zhu H. F., Zhou S. Q., Sun Y. F., Zhang X., Ionics, 2015, 21, 2993
[23] Xu J., Gu S. Z., Fan L., Xu P., Lu B., Electrochim. Acta, 2016, 196, 125
[24] Lyu D. H., Zhang L. L., Wei H. X., Geng H. B., Gu H. W., RSC Adv., 2017, 7, 51506
[25] Chen Y. P., Liu B. R., Jiang W., Liu Q., Liu J. Y., Wang J., Zhang H. S., Jing X. Y., J. Power Sources, 2015, 300, 132
[26] Wang B., Li S. M., Wu X. Y., Liu J. H., Tian W. M., Chen J., New J. Chem., 2016, 40, 2259
[27] Yang Y., Wang S. T., Jiang C. H., Lu Q. C., Tang Z. L., Wang X., Chem. Mater., 2016, 28, 2417
[28] Wang Y. X., Wu Y., Xing L. L., Wang Q., Xue X. Y., J. Alloy. Compd., 2016, 689, 655
[29] Chen Y. Y., Wang Y., Shen X. P., Cai R., Yang H. X., Xu K. Q., Yuan A. H., Ji Z. Y., J. Mater. Chem. A, 2018, 6, 1048
[30] Zhang L., Zheng S. S., Wang L., Tang H., Xue H. G., Wang G. X., Pang H., Small, 2017, 13, 1700917
[31] Wang H., Liu X. Y., Chuah Y. J., Goh J. C. H., Li J. L., Xu H. Y., Chem. Commun., 2013, 49, 1431
[32] Wang W., Sun Y., Liu B., Wang S. G., Cao M. H., Carbon, 2015, 91, 56
[33] Wang W., Qin J. W., Cao M. H., ACS Appl. Mater. Interfaces, 2016, 8, 1388
[34] Cui Z. T., Wang S. G., Zhang Y. H., Cao M. H., Electrochim. Acta, 2015, 182, 507
[35] Yin Z. Y., Zhang X., Cai Y. Q., Chen J. Z., Wong J. I., Tay Y. Y., Chai J. W., Wu J., Zeng Z. Y., Zheng B., Yang H. Y., Zhang H., Angew. Chem. Int. Ed., 2014, 53, 12560
[36] Lei F. C., Sun Y. F., Liu K. T., Gao S., Liang L., Pan B. C., Xie Y., J. Am. Chem. Soc., 2014, 136, 6826
[37] Adamski P., Moszyński D., Komorowska A., Nadziejko M., Sarnecki A., Albrecht A., Inorg. Chem., 2018, 57, 9844
[38] Wang W., Qin J. W., Yin Z. G., Cao M. H., ACS Nano, 2016, 10, 10106
[39] Hy S., Felix F., Rick J., Su W. N., Wang B. J. H., J. Am. Chem. Soc., 2014, 136, 999
[40] He Y. Y., Li A. H., Dong C. F., Li C. C., Xu L. Q., Chem. Eur. J., 2017, 23, 13724
[41] Jin S. X., Yang G. Z., Song H. W., Cui H., Wang C. X., ACS Appl. Mater. Interfaces, 2015, 7, 24932
[42] Ang W. A., Cheah Y. L., Wong C. L., Prasanth R., Hng H. H., Madhavi S., J. Phys. Chem. C, 2013, 117, 16316
[43] Sharma Y., Sharma N., Subba Rao G. V., Chowdari B. V. R., Adv. Funct. Mater., 2007, 17, 2855
[44] Popovic J., Demir Cakan R., Tornow J., Morcrette M., Su D. S., Schlögl R., Antonietti M., Titirici M. M., Small, 2011, 7, 1127

Freeze-drying-assisted Synthesis of Mesoporous CoMoO₄ Nanosheets as Anode Electrode Material for Enhanced Lithium Batteries

Freeze-drying-assisted Synthesis of Mesoporous CoMoO₄ Nanosheets as Anode Electrode Material for Enhanced Lithium Batteries

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