Novel Terpyridine-bridged Parallel Dication Metallo-bisviologens and Their Supramolecular Complexes

doi:10.1007/s40242-019-8279-2

高等学校化学研究 ›› 2019, Vol. 35 ›› Issue (2): 229-234.doi: 10.1007/s40242-019-8279-2

Novel Terpyridine-bridged Parallel Dication Metallo-bisviologens and Their Supramolecular Complexes

LIU Qianqian¹, GUO Yuan¹, WU Tun², CHEN Mingzhao¹, XIE Tingzheng², WANG Pingshan^1,2

1. Department of Organic and Polymer Chemistry, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China;
2. Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, Institute of Environmental Research at Greater Bay, Guangzhou University, Guangzhou 510006, P. R. China

收稿日期:2018-09-05 修回日期:2018-11-30 出版日期:2019-04-01 发布日期:2019-04-30
通讯作者: WANG Pingshan E-mail:chemwps@csu.edu.cn
基金资助:
Supported by the Fundamental Research Funds of Central South University, China(No.2018zzts012).

Novel Terpyridine-bridged Parallel Dication Metallo-bisviologens and Their Supramolecular Complexes

LIU Qianqian¹, GUO Yuan¹, WU Tun², CHEN Mingzhao¹, XIE Tingzheng², WANG Pingshan^1,2

1. Department of Organic and Polymer Chemistry, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China;
2. Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, Institute of Environmental Research at Greater Bay, Guangzhou University, Guangzhou 510006, P. R. China

Received:2018-09-05 Revised:2018-11-30 Online:2019-04-01 Published:2019-04-30
Contact: WANG Pingshan E-mail:chemwps@csu.edu.cn
Supported by:
Supported by the Fundamental Research Funds of Central South University, China(No.2018zzts012).

摘要/Abstract

摘要： By utilizing terpyridine-bridged parallel metallo-complexes as dication metallo-bisviologens, herein we present the synthesis and characterization of two novel supramolecular complexes. 1-Methylpyridin-1-ium-terpyridine ligands and their metallo-complexes were first designed and synthesized, and the association of methylpyridiniums with dibenzo-24-crown-8 ether(DB24C8) afforded the desired novel complexes through host-guest interactions. The self-assembly behavior of the supramolecular complexes was comprehensively investigated and could be exploited for further construction of 1D to 3D supramolecular infrastructures.

关键词: Supramolecular complex, Host-guest interaction, Metallo-viologen, Dibenzo-24-crown-8 ether, Terpyridine

Abstract: By utilizing terpyridine-bridged parallel metallo-complexes as dication metallo-bisviologens, herein we present the synthesis and characterization of two novel supramolecular complexes. 1-Methylpyridin-1-ium-terpyridine ligands and their metallo-complexes were first designed and synthesized, and the association of methylpyridiniums with dibenzo-24-crown-8 ether(DB24C8) afforded the desired novel complexes through host-guest interactions. The self-assembly behavior of the supramolecular complexes was comprehensively investigated and could be exploited for further construction of 1D to 3D supramolecular infrastructures.

Key words: Supramolecular complex, Host-guest interaction, Metallo-viologen, Dibenzo-24-crown-8 ether, Terpyridine

LIU Qianqian, GUO Yuan, WU Tun, CHEN Mingzhao, XIE Tingzheng, WANG Pingshan. Novel Terpyridine-bridged Parallel Dication Metallo-bisviologens and Their Supramolecular Complexes[J]. 高等学校化学研究, 2019, 35(2): 229-234.

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Novel Terpyridine-bridged Parallel Dication Metallo-bisviologens and Their Supramolecular Complexes

Novel Terpyridine-bridged Parallel Dication Metallo-bisviologens and Their Supramolecular Complexes

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