Physicochemical Properties of Bi-containing Ionic Liquid Analogs Based on Choline Chloride

doi:10.1007/s40242-017-7170-2

高等学校化学研究 ›› 2017, Vol. 33 ›› Issue (6): 929-933.doi: 10.1007/s40242-017-7170-2

Physicochemical Properties of Bi-containing Ionic Liquid Analogs Based on Choline Chloride

BU Luxia, LIU Daying, WEI Zhen, MA Zhanlin

Department of Applied Chemistry, College of Basic Science, Tianjin Agricultural University, Tianjin 300384, P. R. China

收稿日期:2017-05-09 修回日期:2017-08-25 出版日期:2017-12-01 发布日期:2017-09-26
通讯作者: BU Luxia,E-mail:buluxia@126.com E-mail:buluxia@126.com
基金资助:
Supported by the Natural Science Foundation of Tianjin City, China(No.15JCQNJC05900).

Physicochemical Properties of Bi-containing Ionic Liquid Analogs Based on Choline Chloride

BU Luxia, LIU Daying, WEI Zhen, MA Zhanlin

Department of Applied Chemistry, College of Basic Science, Tianjin Agricultural University, Tianjin 300384, P. R. China

Received:2017-05-09 Revised:2017-08-25 Online:2017-12-01 Published:2017-09-26
Contact: BU Luxia,E-mail:buluxia@126.com E-mail:buluxia@126.com
Supported by:
Supported by the Natural Science Foundation of Tianjin City, China(No.15JCQNJC05900).

摘要/Abstract

摘要： The preparation and characterization of homogeneous and colorless ionic liquid analogs(ILAs) containing choline chloride(ChCl), malonic acid and bismuth chloride were investigated. The structure of the above mixture was preliminarily analyzed, and then the physicochemical properties including viscosity, conductivity and density were investigated as functions of temperature and composition. Additionally, the thermal stability of the ILAs and the electrochemical behavior of Bi³⁺ ions in the medium were studied. Structure analysis reveals that the synthesis of deep eutectic solvents(DESs) is closely related to the formation of hydrogen bonds between malonic acid and ChCl, with their viscosity, conductivity and density being greatly dependent on the temperature and composition. Thermogravimetric analysis demonstrates that the ILAs are very stable between room temperature and 398.15 K. And the electrochemical experiments indicate that the bismuth films can be successfully deposited from this ILAs and the deposition mechanism of bismuth is a rather irreversible process. The surface morphology of bismuth films deposited on Cu substrates was very compact and smooth. Thus, ChCl-malonic acid DESs were shown to be a good alternative to aqueous solvents for various deposition-related applications.

关键词: Ionic liquid analog, Physicochemical property, Bismuth, Choline chloride, Deposition

Abstract: The preparation and characterization of homogeneous and colorless ionic liquid analogs(ILAs) containing choline chloride(ChCl), malonic acid and bismuth chloride were investigated. The structure of the above mixture was preliminarily analyzed, and then the physicochemical properties including viscosity, conductivity and density were investigated as functions of temperature and composition. Additionally, the thermal stability of the ILAs and the electrochemical behavior of Bi³⁺ ions in the medium were studied. Structure analysis reveals that the synthesis of deep eutectic solvents(DESs) is closely related to the formation of hydrogen bonds between malonic acid and ChCl, with their viscosity, conductivity and density being greatly dependent on the temperature and composition. Thermogravimetric analysis demonstrates that the ILAs are very stable between room temperature and 398.15 K. And the electrochemical experiments indicate that the bismuth films can be successfully deposited from this ILAs and the deposition mechanism of bismuth is a rather irreversible process. The surface morphology of bismuth films deposited on Cu substrates was very compact and smooth. Thus, ChCl-malonic acid DESs were shown to be a good alternative to aqueous solvents for various deposition-related applications.

Key words: Ionic liquid analog, Physicochemical property, Bismuth, Choline chloride, Deposition

BU Luxia, LIU Daying, WEI Zhen, MA Zhanlin. Physicochemical Properties of Bi-containing Ionic Liquid Analogs Based on Choline Chloride[J]. 高等学校化学研究, 2017, 33(6): 929-933.

BU Luxia, LIU Daying, WEI Zhen, MA Zhanlin. Physicochemical Properties of Bi-containing Ionic Liquid Analogs Based on Choline Chloride[J]. Chemical Research in Chinese Universities, 2017, 33(6): 929-933.

参考文献

[1] Ma Y., Wljesekara W., Palmqvist A. E. C., J. Electron. Mater., 2012, 41(6), 1138
[2] Misra D. K., Sumithra S., Chauhan N. S., Nolting W. M., Poudeu P. F. P., Stokes Kevin L., Mat. Sci. Semicon. Proc., 2015, 40, 453
[3] Patil P. B., Mali S. S., Khot K. V., Kondalkar V. V., Ghanwat V. B., Mane R. M., Kharade R. R., Bhosale P. N., Macromol. Symp., 2016, 361(1), 152
[4] Zimmer A., Broch L., Boulanger C., Stein N., Electrochim. Acta, 2015, 174, 376
[5] Zhou J., Lin Q. H., Li H. Y., Cheng X., Mater. Chem. Phys., 2013, 141(1), 401
[6] Wang Z. L., Takahiro A., Tetsuhiko O., Chen Z. C., J. Alloy Compd., 2016, 663, 134
[7] Duan X. K., Jiang Y. Z., Thin Solid Films, 2011, 519(10), 3007
[8] Bu L.X., Wang W., Wang H., Appl. Surf. Sci., 2007, 253(6), 3360
[9] Song Y., Yoo I. J., Heo N. R., Lim D. C., Lee D., Lee J. Y., Lee K. H., Kim K. H., Lim J. H., Curr. Appl. Phys., 2015, 15(3), 261
[10] Suzuki Y., Chen Z. L., Fuwa A., J. Jpn. I. Met., 2014, 78(8), 310
[11] Manzano C. V., Rojas A. A., Decepida M., Abad B., Feliz Y., Caballero-Calero O., Borca-Tasciuc D. A., Martin-Gonzalez M., J. Solid State Electr., 2013, 17(7), 2071
[12] Xu H., Wang W., J. Electron. Mater., 2013, 42(7), 1936
[13] Li F. H., Wang W., Electrochim. Acta, 2010, 55(17), 5000
[14] Golgovici F., Cojocaru A., Nedelcu M., Visan T., J. Electron. Mater., 2010, 39(9), 2079
[15] Paiva A., Craveiro R., Aroso I., Martins M., Reis R. L., Duarte A. R. C., ACS Sustain Chem. Eng., 2014, 2, 1063
[16] Popescu A. M., Constantin V., Chem. Res. Chinese Universities, 2014, 30(1), 119
[17] Adeeb H., Farouq S., Mjalli I. M., Yahya M., J. Mol. Liq., 2013, 178, 137
[18] Abbott A. P., Capper G., Davies D. L., Munro H. L., Rasheed R. K., Tambyrajah V., Chem. Commun., 2001, (19), 2010
[19] Abbott A. P., McKenzie K. J., Phys. Chem. Chem. Phys., 2006, 8, 4265
[20] Wang H. Y., Jia Y. Z., Wang X. H., Yao Y., Jing Y., J. Therm. Anal. Calorim., 2014, 115, 1779
[21] Habibi E., Ghanemi K., Mehdi F., Ali D., Anal. Chim. Acta, 2013, 762, 61
[22] Mccalman D. C., Sun L., Zhang Y., Brennecke J. F., Maginn E. J., Schneider W. F., J. Phys. Chem. B, 2015, 119, 6018
[23] Bougou M., Van Elew A., Steichen M., Buess-Herman C., Doneux T., J. Solid State Electrochem., 2013, 17, 527
[24] Agapescu C., Cojocaru A., Cotarta A., Visan T., J. Appl. Electrochem., 2013, 43, 309
[25] Srivastava M., Yoganandan G., William Grips V. K., Surf. Eng., 2012, 28(6), 424
[26] Cojocaru A., Mares M. L., Prioteasa P., Anicai L., Visan T., J. Solid State Electrochem., 2015, 19, 1001
[27] Protsenko1 V. S., Bobrova1 L. S., Danilov F. I., Ionics, 2017, 23(3), 637
[28] Golgovici F., Visan T., Buda M., Chalcogenide Lett., 2013, 10(6), 197
[29] Kang W. S., Li W. J., Chou W. C., Tseng M. F., Lin C. S., Thin Solid Films, 2017, 623, 90
[30] Gan Y. X., Sweetman J., Lawrence J. G., Mater. Lett., 2010, 64(3), 449
[31] Li F. H., Wang W., Appl. Surf. Sci., 2009, 255(7), 4225
[32] Ebe H., Ueda M., Ohtsuka T., Electrochim. Acta, 2007, 53(1), 100

Physicochemical Properties of Bi-containing Ionic Liquid Analogs Based on Choline Chloride

Physicochemical Properties of Bi-containing Ionic Liquid Analogs Based on Choline Chloride

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