Synthesis of a Newly Modified Poly-H8-BINOL Ligand and Its Applications in the Asymmetric Addition of Triethylaluminium to Aromatic Aldehydes

doi:10.1007/s40242-017-7093-y

高等学校化学研究 ›› 2017, Vol. 33 ›› Issue (5): 742-745.doi: 10.1007/s40242-017-7093-y

Synthesis of a Newly Modified Poly-H₈-BINOL Ligand and Its Applications in the Asymmetric Addition of Triethylaluminium to Aromatic Aldehydes

LIU Can, OUYANG Kunbing, YANG Nianfa

Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105, P. R. China

收稿日期:2017-03-13 修回日期:2017-04-11 出版日期:2017-10-01 发布日期:2017-07-21
通讯作者: OUYANG Kunbing,E-mail:nfyang@xtu.edu.cn;YANG Nianfa,kbouyang@xtu.edu.cn E-mail:nfyang@xtu.edu.cn;kbouyang@xtu.edu.cn
基金资助:
Supported by the Higher Education Doctoral Science Foundation of China(No.20134301110004).

Synthesis of a Newly Modified Poly-H₈-BINOL Ligand and Its Applications in the Asymmetric Addition of Triethylaluminium to Aromatic Aldehydes

LIU Can, OUYANG Kunbing, YANG Nianfa

Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105, P. R. China

Received:2017-03-13 Revised:2017-04-11 Online:2017-10-01 Published:2017-07-21
Contact: OUYANG Kunbing,E-mail:nfyang@xtu.edu.cn;YANG Nianfa,kbouyang@xtu.edu.cn E-mail:nfyang@xtu.edu.cn;kbouyang@xtu.edu.cn
Supported by:
Supported by the Higher Education Doctoral Science Foundation of China(No.20134301110004).

摘要/Abstract

摘要：

A new H₈-BINOL polymer was synthesized by radical polymerization and proved to be an effective catalyst in enantioselective addition of triethylaluminium to aromatic aldehydes in the presence of titanium isopropoxide. The polymer can be prepared with simple steps and reused without losing its enantioselectivity and catalytic activity.

关键词: H₈-BINOL, Radical polymerization, Triethylaluminium, Asymmetric addition, Enantioselectivity

Abstract:

Key words: H₈-BINOL, Radical polymerization, Triethylaluminium, Asymmetric addition, Enantioselectivity

LIU Can, OUYANG Kunbing, YANG Nianfa. Synthesis of a Newly Modified Poly-H₈-BINOL Ligand and Its Applications in the Asymmetric Addition of Triethylaluminium to Aromatic Aldehydes[J]. 高等学校化学研究, 2017, 33(5): 742-745.

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Synthesis of a Newly Modified Poly-H₈-BINOL Ligand and Its Applications in the Asymmetric Addition of Triethylaluminium to Aromatic Aldehydes

Synthesis of a Newly Modified Poly-H₈-BINOL Ligand and Its Applications in the Asymmetric Addition of Triethylaluminium to Aromatic Aldehydes

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