Structure-directing Effect on Synthesis of Layered Aluminophosphates with Same Topology

doi:10.1007/s40242-017-7050-9

高等学校化学研究 ›› 2017, Vol. 33 ›› Issue (4): 513-519.doi: 10.1007/s40242-017-7050-9

Structure-directing Effect on Synthesis of Layered Aluminophosphates with Same Topology

WANG Aitian¹, XU Jun², WANG Chao², DENG Feng², XU Ruren¹, YAN Wenfu¹

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071, P. R. China

收稿日期:2017-02-13 修回日期:2017-03-15 出版日期:2017-08-01 发布日期:2017-05-08
通讯作者: YAN Wenfu E-mail:yanw@jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China（Nos.21571075，21320102001，21621001） and the National Key Research and Development Program of China（No.2016YFB0701100）.

Structure-directing Effect on Synthesis of Layered Aluminophosphates with Same Topology

WANG Aitian¹, XU Jun², WANG Chao², DENG Feng², XU Ruren¹, YAN Wenfu¹

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071, P. R. China

Received:2017-02-13 Revised:2017-03-15 Online:2017-08-01 Published:2017-05-08
Contact: YAN Wenfu E-mail:yanw@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China（Nos.21571075，21320102001，21621001） and the National Key Research and Development Program of China（No.2016YFB0701100）.

摘要/Abstract

摘要：

Three layered aluminophosphates(UiO-15, APDAP₁₂-150 and APDAP-150) with same topology were crystallized from an initial mixture with a molar composition of Al₂O₃:1.5P₂O₅:5.5R:227H₂O, where R is ethylenediamine, 1,2-diaminopropane or 1,3-diaminopropane, respectively. The crystallization processes of UiO-15, APDAP₁₂-150 and APDAP-150 were investigated using solid-state NMR in combination with XRD and other characterization techniques. The evolution of the coordination states of Al and P in the solid products was monitored, and the possible starting points of crystallization(core units) of UiO-15, APDAP₁₂-150 and APDAP-150 were obtained and analyzed. The formation of a trimer as well as a hexamer of aluminophosphate, a monomer of PO₄ and a nonamer containing two three-membered rings is critical for the start of crystallization of UiO-15. The formation of a hexamer and a pentamer is critical for the start of crystallization of APDAP₁₂-150. The formation of an AlO₆ monomer and a pentamer containing a three-membered ring is critical for the start of crystallization of APDAP-150. The crystal water played a co-structure-directing role in the formation of APDAP-150.

关键词: Zeolite, Aluminophosphate, Templating effect, Structure-directing effect

Abstract:

Key words: Zeolite, Aluminophosphate, Templating effect, Structure-directing effect

WANG Aitian, XU Jun, WANG Chao, DENG Feng, XU Ruren, YAN Wenfu. Structure-directing Effect on Synthesis of Layered Aluminophosphates with Same Topology[J]. 高等学校化学研究, 2017, 33(4): 513-519.

WANG Aitian, XU Jun, WANG Chao, DENG Feng, XU Ruren, YAN Wenfu. Structure-directing Effect on Synthesis of Layered Aluminophosphates with Same Topology[J]. Chemical Research in Chinese Universities, 2017, 33(4): 513-519.

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Structure-directing Effect on Synthesis of Layered Aluminophosphates with Same Topology

Structure-directing Effect on Synthesis of Layered Aluminophosphates with Same Topology

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