A Gas Chromatographic Stationary of Homochiral Metal-peptide Framework Material and Its Applications

doi:10.1007/s40242-017-6270-3

高等学校化学研究 ›› 2017, Vol. 33 ›› Issue (1): 24-30.doi: 10.1007/s40242-017-6270-3

A Gas Chromatographic Stationary of Homochiral Metal-peptide Framework Material and Its Applications

LI Lang, XIE Shengming, ZHANG Junhui, CHEN Ling, ZHU Pengjing, YUAN Liming

Department of Chemistry, Yunnan Normal University, Kunming 650500, P. R. China

收稿日期:2016-06-24 修回日期:2016-09-13 出版日期:2017-02-01 发布日期:2017-01-19
通讯作者: YUAN Liming,E-mail:yuan_limingpd@126.com E-mail:yuan_limingpd@126.com
基金资助:
Supported by the National Natural Science Foundation of China(No.21275126).

A Gas Chromatographic Stationary of Homochiral Metal-peptide Framework Material and Its Applications

LI Lang, XIE Shengming, ZHANG Junhui, CHEN Ling, ZHU Pengjing, YUAN Liming

Department of Chemistry, Yunnan Normal University, Kunming 650500, P. R. China

Received:2016-06-24 Revised:2016-09-13 Online:2017-02-01 Published:2017-01-19
Contact: YUAN Liming,E-mail:yuan_limingpd@126.com E-mail:yuan_limingpd@126.com
Supported by:
Supported by the National Natural Science Foundation of China(No.21275126).

摘要/Abstract

摘要：

Homochiral metal-organic frameworks(HMOFs) have special properties, such as high surface area, fascinating structures and excellent chemical and thermal stability and they have broad application prospects. In this work, we reported the use of HMOF Co-L-GG(L-GG, dipeptide H-Gly-L-Glu) as the stationary phase for separating racemates in gas chromatography. Co-L-GG coated fused silica capillary column(10 m×250 μm i.d.) was prepared via a dynamic coating method. Thirty racemates belonging to different classes of organic compounds were resolved including halohydrocarbons, ketones, esters, ethers, organic acids, epoxyalkanes, alcohols and sulfoxides. When compared with the previously reported chiral MOFs-coated capillary columns, the Co-L-GG coated column exhibited broader chiral resolution ability towards chiral compounds.

关键词: Homochiral metal-organic framework, Stationary phase, Gas chromatography, Chiral separation

Abstract:

Key words: Homochiral metal-organic framework, Stationary phase, Gas chromatography, Chiral separation

LI Lang, XIE Shengming, ZHANG Junhui, CHEN Ling, ZHU Pengjing, YUAN Liming. A Gas Chromatographic Stationary of Homochiral Metal-peptide Framework Material and Its Applications[J]. 高等学校化学研究, 2017, 33(1): 24-30.

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A Gas Chromatographic Stationary of Homochiral Metal-peptide Framework Material and Its Applications

A Gas Chromatographic Stationary of Homochiral Metal-peptide Framework Material and Its Applications

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