Cetyltrimethylammonium Bromide(CTAB)-Ionic Liquid Composite Modified Electrode for Sensitive Cyclic Voltammetric Determination of Bisphenol A

doi:10.1007/s40242-016-6162-y

高等学校化学研究 ›› 2016, Vol. 32 ›› Issue (6): 992-995.doi: 10.1007/s40242-016-6162-y

Cetyltrimethylammonium Bromide(CTAB)-Ionic Liquid Composite Modified Electrode for Sensitive Cyclic Voltammetric Determination of Bisphenol A

LIU Lihong, WANG Chunfeng, ZHUO Kelei

Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, P. R. China

收稿日期:2016-04-25 修回日期:2016-06-30 出版日期:2016-12-01 发布日期:2016-09-05
通讯作者: ZHUO Kelei, E-mail:klzhuo@263.net E-mail:klzhuo@263.net
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21173070, 21573058).

Cetyltrimethylammonium Bromide(CTAB)-Ionic Liquid Composite Modified Electrode for Sensitive Cyclic Voltammetric Determination of Bisphenol A

LIU Lihong, WANG Chunfeng, ZHUO Kelei

Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, P. R. China

Received:2016-04-25 Revised:2016-06-30 Online:2016-12-01 Published:2016-09-05
Contact: ZHUO Kelei, E-mail:klzhuo@263.net E-mail:klzhuo@263.net
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21173070, 21573058).

摘要/Abstract

摘要：

A sensitive electrochemical sensor for determining bisphenol A(BPA) was designed. The sensor was a glassy carbon electrode modified with the surfactant cetyltrimethylammonium bromide and the ionic liquid 1-decyl-3-methylimidazolium tetrafluoroborate. The ability of the new sensor to measure BPA was investigated in cyclic voltammetry experiments. Under optimized conditions, the sensor gave a linear response range for BPA of 2.19×10^-7-3.28×10^-5 mol/L and a detection limit of 7.31×10^-8 mol/L(S/N=3). BPA could be determined with a lower detection limit, a wider linear range, and more sensitivity using the sensor than using other electrochemical sensors or high performance liquid chromatography with UV detection. The new sensor was used to determine BPA in tap water with recoveries of 97.5%-98.7% and a relative standard deviation <2.9%. The results show that the sensor can be used to determine trace BPA concentrations in tap water.

关键词: Bisphenol A, Ionic liquid, Surfactant, Electrochemical sensor

Abstract:

Key words: Bisphenol A, Ionic liquid, Surfactant, Electrochemical sensor

LIU Lihong, WANG Chunfeng, ZHUO Kelei. Cetyltrimethylammonium Bromide(CTAB)-Ionic Liquid Composite Modified Electrode for Sensitive Cyclic Voltammetric Determination of Bisphenol A[J]. 高等学校化学研究, 2016, 32(6): 992-995.

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Cetyltrimethylammonium Bromide(CTAB)-Ionic Liquid Composite Modified Electrode for Sensitive Cyclic Voltammetric Determination of Bisphenol A

Cetyltrimethylammonium Bromide(CTAB)-Ionic Liquid Composite Modified Electrode for Sensitive Cyclic Voltammetric Determination of Bisphenol A

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