A Fluorescent and Colorimetric Probe Based on Isatin-appended Rhodamine for the Detection of Hg2+

doi:10.1007/s40242-016-6001-1

高等学校化学研究 ›› 2016, Vol. 32 ›› Issue (5): 742-745.doi: 10.1007/s40242-016-6001-1

A Fluorescent and Colorimetric Probe Based on Isatin-appended Rhodamine for the Detection of Hg²⁺

CHEN Jiayi¹, SHU Wei¹, WANG Enju²

1. School of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, P. R. China;
2. Key Laboratory of Tropical Medicinal Plant Chemistry, Ministry of Education, Hainan Normal University, Haikou 571158, P. R. China

收稿日期:2016-01-04 修回日期:2016-05-05 出版日期:2016-10-01 发布日期:2016-06-27
通讯作者: WANG Enju E-mail:enjuwang@163.com
基金资助:
Supported by the National Natural Science Foundation of China(No.21162010).

A Fluorescent and Colorimetric Probe Based on Isatin-appended Rhodamine for the Detection of Hg²⁺

CHEN Jiayi¹, SHU Wei¹, WANG Enju²

1. School of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, P. R. China;
2. Key Laboratory of Tropical Medicinal Plant Chemistry, Ministry of Education, Hainan Normal University, Haikou 571158, P. R. China

Received:2016-01-04 Revised:2016-05-05 Online:2016-10-01 Published:2016-06-27
Contact: WANG Enju E-mail:enjuwang@163.com
Supported by:
Supported by the National Natural Science Foundation of China(No.21162010).

摘要/Abstract

摘要：

A new fluorescent probe for the detection of Hg²⁺ was designed and synthesized via attaching N-methylisatin to rhodamine B hydrazide through an imine linkage. In an ethanol-Tris buffer medium, the addition of Hg²⁺ caused a strong orange fluorescence and a visual color change from colorless to pink. Other coexisting metal ions did not interfere with the detection of Hg²⁺. The research on the detection of Hg²⁺ in natural water suggested the possibility of practical applications in environment monitoring. Based on ESI-MS analysis, the Hg²⁺-sensing mechanism was proposed.

关键词: Fluorescent probe, Isatin, Rhodamine B, Mercury(Ⅱ) ion

Abstract:

Key words: Fluorescent probe, Isatin, Rhodamine B, Mercury(Ⅱ) ion

CHEN Jiayi, SHU Wei, WANG Enju. A Fluorescent and Colorimetric Probe Based on Isatin-appended Rhodamine for the Detection of Hg²⁺[J]. 高等学校化学研究, 2016, 32(5): 742-745.

CHEN Jiayi, SHU Wei, WANG Enju. A Fluorescent and Colorimetric Probe Based on Isatin-appended Rhodamine for the Detection of Hg²⁺[J]. Chemical Research in Chinese Universities, 2016, 32(5): 742-745.

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A Fluorescent and Colorimetric Probe Based on Isatin-appended Rhodamine for the Detection of Hg²⁺

A Fluorescent and Colorimetric Probe Based on Isatin-appended Rhodamine for the Detection of Hg²⁺

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