Aliphatic Segmented Poly(ether ester amide)s Synthesized from Hexanediamine, Sebacic Acid and Poly(ethylene glycol)s

doi:10.1007/s40242-016-5387-0

高等学校化学研究 ›› 2016, Vol. 32 ›› Issue (3): 505-511.doi: 10.1007/s40242-016-5387-0

Aliphatic Segmented Poly(ether ester amide)s Synthesized from Hexanediamine, Sebacic Acid and Poly(ethylene glycol)s

ZHAO Yanping, ZHAO Jingbo, ZHANG Zhiyuan, ZHANG Junying

Key Laboratory of Carbon Fiber and Functional Polymers, Ministry of Education, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China

收稿日期:2015-10-08 修回日期:2016-03-30 出版日期:2016-06-01 发布日期:2016-04-20
通讯作者: ZHAO Jingbo E-mail:zhaojb@mail.buct.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21244006, 50873013).

Aliphatic Segmented Poly(ether ester amide)s Synthesized from Hexanediamine, Sebacic Acid and Poly(ethylene glycol)s

ZHAO Yanping, ZHAO Jingbo, ZHANG Zhiyuan, ZHANG Junying

Key Laboratory of Carbon Fiber and Functional Polymers, Ministry of Education, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China

Received:2015-10-08 Revised:2016-03-30 Online:2016-06-01 Published:2016-04-20
Contact: ZHAO Jingbo E-mail:zhaojb@mail.buct.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21244006, 50873013).

摘要/Abstract

摘要：

High molecular weight aliphatic segmented poly(ether ester amide)s(PEEAs) were synthesized via melt polycondensation and chain extension. An oligomeric polyamide(PA) terminated mainly with -COOH groups(HOOC-PA-COOH) was prepared from the reaction of nylon 610 salt with sebacic acid. Melt polycondensation of HOOC-PA-COOH with polyethylene glycol(PEG), such as PEG400, PEG600, PEG1000 and PEG1500, was conducted at 200℃, and several segmented PEEA prepolymers(PrePEEAs) were prepared. Chain extension of PrePEEAs was carried out at 190℃ using 2,2'-(1,4-phenylene)-bis(2-oxazoline) and adipoyl biscaprolactamate as combination chain extenders. Chain extended PEEAs(ExtPEEAs) were characterized by gel permeation chromatography(GPC), Fourier transform infrared spectrophotometer(FTIR), proton nuclear magnetic resonance(¹H NMR), differential scanning calorimetry(DSC), wide angle X-ray scattering(WAXS), thermogravimetry analysis(TGA), and tensile test. The ExtPEEAs exhibited M_n up to 98700, T_m from 164.2℃ to 176.1℃, initial decomposition temperature above 320.6℃, tensile strength up to 34.80 MPa, and strain at break from 111.92% to 353.12%. Aliphatic segmented PEEAs with good thermal and mechanical properties were prepared.

关键词: Copolymer, Segmented, Poly(ester amide), Polycondensation, Chain extension

Abstract:

Key words: Copolymer, Segmented, Poly(ester amide), Polycondensation, Chain extension

ZHAO Yanping, ZHAO Jingbo, ZHANG Zhiyuan, ZHANG Junying. Aliphatic Segmented Poly(ether ester amide)s Synthesized from Hexanediamine, Sebacic Acid and Poly(ethylene glycol)s[J]. 高等学校化学研究, 2016, 32(3): 505-511.

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Aliphatic Segmented Poly(ether ester amide)s Synthesized from Hexanediamine, Sebacic Acid and Poly(ethylene glycol)s

Aliphatic Segmented Poly(ether ester amide)s Synthesized from Hexanediamine, Sebacic Acid and Poly(ethylene glycol)s

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