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高等学校化学研究 ›› 2015, Vol. 31 ›› Issue (5): 688-692.doi: 10.1007/s40242-015-5300-2

• Articles • 上一篇    下一篇

One Step Preparation of Highly Dispersed TiO2 Nanoparticles

LIU Xu, CHEN Yan, JIAO Shihui, PANG Guangsheng   

  1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China
  • 收稿日期:2015-07-23 修回日期:2015-08-15 出版日期:2015-10-01 发布日期:2015-09-02
  • 通讯作者: PANG Guangsheng, E-mail: panggs@jlu.edu.cn E-mail:panggs@jlu.edu.cn
  • 基金资助:

    Supported by the National Natural Science Foundation of China(Nos.21071058, 21371066, 21301067).

One Step Preparation of Highly Dispersed TiO2 Nanoparticles

LIU Xu, CHEN Yan, JIAO Shihui, PANG Guangsheng   

  1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China
  • Received:2015-07-23 Revised:2015-08-15 Online:2015-10-01 Published:2015-09-02
  • Contact: PANG Guangsheng, E-mail: panggs@jlu.edu.cn E-mail:panggs@jlu.edu.cn
  • Supported by:

    Supported by the National Natural Science Foundation of China(Nos.21071058, 21371066, 21301067).

摘要:

A facile approach was developed to prepare highly dispersed TiO2 nanoparticles with selected phase. The crystallization phase of the nanoparticles can be easily tuned from anatase to rutile by the dosage of hydrochloric acid in the reaction system. The crystallite size of the as-prepared anatase TiO2 nanoparticles was ca. 3.2 nm with high dispersion. A transparent TiO2 colloid was obtained by dispersing the as-prepared anatase TiO2 nanoparticles in deionized water without any organic additives added. The concentration of TiO2-H2O colloid can be as high as 1600 g/L. The optical transmittance of TiO2-H2O colloid with a low concentration was nearly 100% in the visible region. Furthermore, anatase TiO2 nanoparticles(TiO2-NPs) showed superior photocatalytic performance compared to rutile TiO2-NPs.

关键词: TiO2 nanoparticle, Water-dispersible, Colloid

Abstract:

A facile approach was developed to prepare highly dispersed TiO2 nanoparticles with selected phase. The crystallization phase of the nanoparticles can be easily tuned from anatase to rutile by the dosage of hydrochloric acid in the reaction system. The crystallite size of the as-prepared anatase TiO2 nanoparticles was ca. 3.2 nm with high dispersion. A transparent TiO2 colloid was obtained by dispersing the as-prepared anatase TiO2 nanoparticles in deionized water without any organic additives added. The concentration of TiO2-H2O colloid can be as high as 1600 g/L. The optical transmittance of TiO2-H2O colloid with a low concentration was nearly 100% in the visible region. Furthermore, anatase TiO2 nanoparticles(TiO2-NPs) showed superior photocatalytic performance compared to rutile TiO2-NPs.

Key words: TiO2 nanoparticle, Water-dispersible, Colloid