Preparation and Chiral Recognition of Thermosensitive Poly(N-isopropylacrylamide) Microgels Containing Modified L-Phenylalanine Groups

doi:10.1007/s40242-015-4461-3

高等学校化学研究 ›› 2015, Vol. 31 ›› Issue (4): 664-668.doi: 10.1007/s40242-015-4461-3

Preparation and Chiral Recognition of Thermosensitive Poly(N-isopropylacrylamide) Microgels Containing Modified L-Phenylalanine Groups

CHEN Jiaojiao¹, YIN Yue¹, FU Hongjun², LI Qifeng¹, ZOU Jiwei¹

1. State Key Laboratory of Separation Membranes and Membrane Process, School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, P. R. China;
2. Tianjin Key Laboratory of Fiber Modification and Functional Fiber and Textile Division, Tianjin Polytechnic University, Tianjin 300387, P. R. China

收稿日期:2014-12-03 修回日期:2015-04-27 出版日期:2015-08-01 发布日期:2015-05-04
通讯作者: CHEN Jiaojiao E-mail:chenjiaojiao@tjpu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.20904039) and the Tianjin Research Program of Application Foundation and Advanced Technology, China(No.10JCYBJC02900).

Preparation and Chiral Recognition of Thermosensitive Poly(N-isopropylacrylamide) Microgels Containing Modified L-Phenylalanine Groups

CHEN Jiaojiao¹, YIN Yue¹, FU Hongjun², LI Qifeng¹, ZOU Jiwei¹

1. State Key Laboratory of Separation Membranes and Membrane Process, School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, P. R. China;
2. Tianjin Key Laboratory of Fiber Modification and Functional Fiber and Textile Division, Tianjin Polytechnic University, Tianjin 300387, P. R. China

Received:2014-12-03 Revised:2015-04-27 Online:2015-08-01 Published:2015-05-04
Contact: CHEN Jiaojiao E-mail:chenjiaojiao@tjpu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.20904039) and the Tianjin Research Program of Application Foundation and Advanced Technology, China(No.10JCYBJC02900).

摘要/Abstract

摘要：

Thermosensitive poly[N-isopropylacrylamide(NIPAM)-co-N-acryloyl-L-phenylalanine ethyl ester (NALPE)] microgels were prepared by the free radical polymerization of NIPAM and chiral monomer, NALPE. Such microgels exhibited spherical shape and favorable monodispersity. Increasing the content of NALPE units would enhance the average diameter, but decrease the thermosensitivity and volume-phase transition temperatures of the microgels. Compared with PNIPAM microgels, the microgels containing NALPE units performed chiral recognozable capacities for D-phenylalanine and D-tartaric acid, and the enantioselectivity and adsorption capacity of the microgels improved with increasing the temperature and/or the content of NALPE units.

关键词: Thermosensitive microgel, N-Isopropylacrylamide, L-Phenylalanine, Chiral recognition

Abstract:

Key words: Thermosensitive microgel, N-Isopropylacrylamide, L-Phenylalanine, Chiral recognition

CHEN Jiaojiao, YIN Yue, FU Hongjun, LI Qifeng, ZOU Jiwei. Preparation and Chiral Recognition of Thermosensitive Poly(N-isopropylacrylamide) Microgels Containing Modified L-Phenylalanine Groups[J]. 高等学校化学研究, 2015, 31(4): 664-668.

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Preparation and Chiral Recognition of Thermosensitive Poly(N-isopropylacrylamide) Microgels Containing Modified L-Phenylalanine Groups

Preparation and Chiral Recognition of Thermosensitive Poly(N-isopropylacrylamide) Microgels Containing Modified L-Phenylalanine Groups

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