Assembly of Two Coordination Polymers Based on 2,2'-Bipyridyl-4,4'-dicarboxylic Acid Ligand

doi:10.1007/s40242-015-5015-4

高等学校化学研究 ›› 2015, Vol. 31 ›› Issue (4): 503-507.doi: 10.1007/s40242-015-5015-4

Assembly of Two Coordination Polymers Based on 2,2'-Bipyridyl-4,4'-dicarboxylic Acid Ligand

WANG Jing, LUO Xiaolong, YUAN Yang, ZHANG Lirong

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

收稿日期:2015-01-09 修回日期:2015-02-09 出版日期:2015-08-01 发布日期:2015-03-09
通讯作者: ZHANG Lirong E-mail:zlr@jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.20701015).

Assembly of Two Coordination Polymers Based on 2,2'-Bipyridyl-4,4'-dicarboxylic Acid Ligand

WANG Jing, LUO Xiaolong, YUAN Yang, ZHANG Lirong

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2015-01-09 Revised:2015-02-09 Online:2015-08-01 Published:2015-03-09
Supported by:
Supported by the National Natural Science Foundation of China(No.20701015).

摘要/Abstract

摘要：

Two novel 2D coordination polymers, [Co(BPDC)DMSO]·DMSO(1)(BPDC=2,2'-bipyridyl-4,4'-dicar- boxylic acid) and [Zn(BPDC)DMF]·DMF(2), were synthesized from 2,2'-bipyridyl-4,4'-dicarboxylic acid ligand (H₂BPDC) under solvothermal conditions. Single crystal X-ray diffraction analyses reveal that compound 1 crystallizes in orthorhombic system and Pca2₁ space group with a=1.29628(13) nm, b=1.13721(13) nm, c=1.66457(19) nm, α=90°, β=90°, γ=90°, V=2.4538(5) nm³. Compound 2 crystallizes in monoclinic system and P2₁/c space group with a=0.9429(6) nm, b=1.4757(10) nm, c=1.5980(9) nm, α=90°, β=114°, γ=90°, V=2.030(2) nm³. Compounds 1 and 2 exhibit two different 3-connected hcb and fes topologies, respectively. The structures of the two compounds both contain interesting characters of double-helical chains(left- and right-handed helical chains). Additionally, the magnetic and luminescent properties of the two compounds were studied.

关键词: Coordination polymer, Helical chain, Magnetic property, Luminescent property

Abstract:

Key words: Coordination polymer, Helical chain, Magnetic property, Luminescent property

WANG Jing, LUO Xiaolong, YUAN Yang, ZHANG Lirong. Assembly of Two Coordination Polymers Based on 2,2'-Bipyridyl-4,4'-dicarboxylic Acid Ligand[J]. 高等学校化学研究, 2015, 31(4): 503-507.

WANG Jing, LUO Xiaolong, YUAN Yang, ZHANG Lirong. Assembly of Two Coordination Polymers Based on 2,2'-Bipyridyl-4,4'-dicarboxylic Acid Ligand[J]. Chemical Research in Chinese Universities, 2015, 31(4): 503-507.

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Assembly of Two Coordination Polymers Based on 2,2'-Bipyridyl-4,4'-dicarboxylic Acid Ligand

Assembly of Two Coordination Polymers Based on 2,2'-Bipyridyl-4,4'-dicarboxylic Acid Ligand

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