Novel Porous Aromatic Framework with Excellent Separation Capability of CO2 in N2 or CH4

doi:10.1007/s40242-014-4100-4

高等学校化学研究 ›› 2014, Vol. 30 ›› Issue (6): 1018-1021.doi: 10.1007/s40242-014-4100-4

Novel Porous Aromatic Framework with Excellent Separation Capability of CO₂ in N₂ or CH₄

WANG Wei¹, YUAN Ye², SUN Fuxing², ZHAO Ming¹, REN Hao², ZHU Guangshan²

1. Key Laboratory of Automobile Materials, Ministry of Education, School of Materials Science and Engineering, Jilin University, Changchun 130022, P. R. China;
2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

收稿日期:2014-03-25 修回日期:2014-06-06 出版日期:2014-12-01 发布日期:2014-07-07
通讯作者: ZHAO Ming, REN Hao E-mail:zhaoming@jlu.edu.cn;renhao@jlu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(No.20831002) and the National Key Basic Research and Development Program of China(No.2010CB63100).

Novel Porous Aromatic Framework with Excellent Separation Capability of CO₂ in N₂ or CH₄

WANG Wei¹, YUAN Ye², SUN Fuxing², ZHAO Ming¹, REN Hao², ZHU Guangshan²

1. Key Laboratory of Automobile Materials, Ministry of Education, School of Materials Science and Engineering, Jilin University, Changchun 130022, P. R. China;
2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2014-03-25 Revised:2014-06-06 Online:2014-12-01 Published:2014-07-07
Contact: ZHAO Ming, REN Hao E-mail:zhaoming@jlu.edu.cn;renhao@jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.20831002) and the National Key Basic Research and Development Program of China(No.2010CB63100).

摘要/Abstract

摘要：

A novel porous aromatic framework, PAF-52, was obtained via the polymerization of tetrahedral monomer tetrakis(4-cyanodiphenyl) methane(TCDPM) with the aid of a facile ionothermal method. PAF-52 has a surface area of 1159 m²/g(BET), and shows a considerable high separation ability of CO₂ in N₂ or CH₄ respectively at room temperature, using gas-chromatography experiments as evidence.

关键词: Porous aromatic framework, CO₂ adsorption separation, Nitrogen-rich framework

Abstract:

Key words: Porous aromatic framework, CO₂ adsorption separation, Nitrogen-rich framework

WANG Wei, YUAN Ye, SUN Fuxing, ZHAO Ming, REN Hao, ZHU Guangshan. Novel Porous Aromatic Framework with Excellent Separation Capability of CO₂ in N₂ or CH₄[J]. 高等学校化学研究, 2014, 30(6): 1018-1021.

WANG Wei, YUAN Ye, SUN Fuxing, ZHAO Ming, REN Hao, ZHU Guangshan. Novel Porous Aromatic Framework with Excellent Separation Capability of CO₂ in N₂ or CH₄[J]. Chemical Research in Chinese Universities, 2014, 30(6): 1018-1021.

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Novel Porous Aromatic Framework with Excellent Separation Capability of CO₂ in N₂ or CH₄

Novel Porous Aromatic Framework with Excellent Separation Capability of CO₂ in N₂ or CH₄

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