Determination of Dioxins in Blood Using Nano-baskets Doped in EmulsionLiquid Membranes

doi:10.1007/s40242-013-2048-4

高等学校化学研究 ›› 2013, Vol. 29 ›› Issue (1): 30-36.doi: 10.1007/s40242-013-2048-4

Determination of Dioxins in Blood Using Nano-baskets Doped in EmulsionLiquid Membranes

MOKHTARI Bahram, POURABDOLLAH Kobra

Razi Chemistry Research Center(RCRC), Shahreza Branch, Islamic Azad University, Shahreza, Iran

收稿日期:2012-02-13 修回日期:2012-08-30 出版日期:2013-02-01 发布日期:2013-01-23
基金资助:
Supported by the Project of Islamic Azad University(Shahreza Branch) and the Iran Nanotechnology Initiative Council, Iran.

Determination of Dioxins in Blood Using Nano-baskets Doped in EmulsionLiquid Membranes

MOKHTARI Bahram, POURABDOLLAH Kobra

Razi Chemistry Research Center(RCRC), Shahreza Branch, Islamic Azad University, Shahreza, Iran

Received:2012-02-13 Revised:2012-08-30 Online:2013-02-01 Published:2013-01-23
Supported by:
Supported by the Project of Islamic Azad University(Shahreza Branch) and the Iran Nanotechnology Initiative Council, Iran.

摘要/Abstract

摘要：

Extraction of dioxins from blood samples was carried out by inclusion-facilitated emulsion liquid membrane process. The novelty of this work is the application of nano-baskets of calixarene and emulsion liquid membranes in the selective and efficient preconcentration of dioxin. For this aim, four derivatives of p-tert-calix[4]arene bearing different sulfonamide moieties were synthesized and their inclusion-extraction parameters were optimized including the calixarene's scaffold and concentration(as the carrier/demulsifier), the diluent type in membrane, the phase and the treat ratio, mixing speed, and initial solute concentration. Determinations were followed by a gas chromatograph and the results reveal that under the optimized operating conditions, the preconcentration of dioxins was improved and the method achieved lower limit of detections(LODs). Under optimal conditions, the figures of merits were determined to be LOD 1.0 pg/L, dynamic range 0.6―112.0 pg/L, RSD 5.5%(n=5), and the maximum enrichment factor and recovery were determined to be 3.3 and 99%, respectively.

关键词: Nano-basket, Dioxin, Inclusion, Calixarene, Emulsion liquid membrane

Abstract:

Key words: Nano-basket, Dioxin, Inclusion, Calixarene, Emulsion liquid membrane

MOKHTARI Bahram, POURABDOLLAH Kobra. Determination of Dioxins in Blood Using Nano-baskets Doped in EmulsionLiquid Membranes[J]. 高等学校化学研究, 2013, 29(1): 30-36.

MOKHTARI Bahram, POURABDOLLAH Kobra. Determination of Dioxins in Blood Using Nano-baskets Doped in EmulsionLiquid Membranes[J]. Chemical Research in Chinese Universities, 2013, 29(1): 30-36.

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Determination of Dioxins in Blood Using Nano-baskets Doped in EmulsionLiquid Membranes

Determination of Dioxins in Blood Using Nano-baskets Doped in EmulsionLiquid Membranes

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