Preparation of Multilayered 1,2-Ethylene-silica Nanotubes Through a Dual-templating Approach

高等学校化学研究 ›› 2012, Vol. 28 ›› Issue (2): 176-179 .

Preparation of Multilayered 1,2-Ethylene-silica Nanotubes Through a Dual-templating Approach

WU Li-min, BI Li-feng, WANG Si-bing, LI Bao-zong, LI Yi, YANG Yong-gang

College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China

收稿日期:2011-04-07 修回日期:2011-07-13 出版日期:2012-03-25 发布日期:2012-03-08
通讯作者: LI Yi E-mail:liyi@suda.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.21104053, 21074086) and the Natural Science Foundation of Jiangsu Province, China(No.BK2011354).

Preparation of Multilayered 1,2-Ethylene-silica Nanotubes Through a Dual-templating Approach

WU Li-min, BI Li-feng, WANG Si-bing, LI Bao-zong, LI Yi, YANG Yong-gang

College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China

Received:2011-04-07 Revised:2011-07-13 Online:2012-03-25 Published:2012-03-08
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21104053, 21074086) and the Natural Science Foundation of Jiangsu Province, China(No.BK2011354).

摘要/Abstract

摘要： Multilayered 1,2-ethylene-silica nanotubes were prepared with cetyltrimethylammonium bromide(CTAB) as a template and (S)-β-citronellol(CN) as a co-structure-directing agent. For a better understanding of the formation of this structure, the CN/CTAB molar ratio in the reaction mixtures was tuned. With increasing the CN/CTAB molar ratio, a hexagonal to lamellar phase trasformation was observed; and the morphologies of 1,2-ethylene-silica changed from rod to vesicle and then to tubular structure. CN droplets were proposed as the templates for the nanotubes. The obtained samples were characterized by means of X-ray diffraction, nitrogen sorption, field emission scanning electron microscopy and transmission electron microscopy.

关键词: 1,2-Ethylene-silica nanotube, Chiral alcohol, Phase transformation

Abstract: Multilayered 1,2-ethylene-silica nanotubes were prepared with cetyltrimethylammonium bromide(CTAB) as a template and (S)-β-citronellol(CN) as a co-structure-directing agent. For a better understanding of the formation of this structure, the CN/CTAB molar ratio in the reaction mixtures was tuned. With increasing the CN/CTAB molar ratio, a hexagonal to lamellar phase trasformation was observed; and the morphologies of 1,2-ethylene-silica changed from rod to vesicle and then to tubular structure. CN droplets were proposed as the templates for the nanotubes. The obtained samples were characterized by means of X-ray diffraction, nitrogen sorption, field emission scanning electron microscopy and transmission electron microscopy.

Key words: 1,2-Ethylene-silica nanotube, Chiral alcohol, Phase transformation

WU Li-min, BI Li-feng, WANG Si-bing, LI Bao-zong, LI Yi, YANG Yong-gang. Preparation of Multilayered 1,2-Ethylene-silica Nanotubes Through a Dual-templating Approach[J]. 高等学校化学研究, 2012, 28(2): 176-179 .

WU Li-min, BI Li-feng, WANG Si-bing, LI Bao-zong, LI Yi, YANG Yong-gang. Preparation of Multilayered 1,2-Ethylene-silica Nanotubes Through a Dual-templating Approach[J]. Chemical Research in Chinese Universities, 2012, 28(2): 176-179 .

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Preparation of Multilayered 1,2-Ethylene-silica Nanotubes Through a Dual-templating Approach

Preparation of Multilayered 1,2-Ethylene-silica Nanotubes Through a Dual-templating Approach

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