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高等学校化学研究 ›› 2011, Vol. 27 ›› Issue (4): 664-668.

• Articles • 上一篇    下一篇

Solvent-free Synthesis of Flavanone over New Hybrid Mesoporous Base Catalysts

WANG Hui2, NIU Xiao-di1, ZHAO Min1, XIAO Xue-bin1, WANG Hong-su1* and WANG Zhong-dong1*   

  1. 1. Teaching Center of Basic Courses, Jilin University, Changchun 130062, P. R. China;
    2. Department of Chemistry, Mudanjiang Teachers College, Mudanjiang 157012, P. R. China
  • 收稿日期:2011-03-08 修回日期:2011-05-03 出版日期:2011-07-25 发布日期:2011-06-29
  • 通讯作者: WANG Hong-su;WANG Zhong-dong E-mail:wanghs@jlu.edu.cn;wangzd11@sohu.com
  • 基金资助:

    Supported by the Research Startup Fund of Jilin University, China(Nos.4305050102H8, 4305050102B5) and the Basic Research and Operational Costs of Jilin University, China(Nos.421031196604, 450060445293).

Solvent-free Synthesis of Flavanone over New Hybrid Mesoporous Base Catalysts

WANG Hui2, NIU Xiao-di1, ZHAO Min1, XIAO Xue-bin1, WANG Hong-su1* and WANG Zhong-dong1*   

  1. 1. Teaching Center of Basic Courses, Jilin University, Changchun 130062, P. R. China;
    2. Department of Chemistry, Mudanjiang Teachers College, Mudanjiang 157012, P. R. China
  • Received:2011-03-08 Revised:2011-05-03 Online:2011-07-25 Published:2011-06-29
  • Contact: WANG Hong-su;WANG Zhong-dong E-mail:wanghs@jlu.edu.cn;wangzd11@sohu.com
  • Supported by:

    Supported by the Research Startup Fund of Jilin University, China(Nos.4305050102H8, 4305050102B5) and the Basic Research and Operational Costs of Jilin University, China(Nos.421031196604, 450060445293).

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摘要： Benzyl and anthracenemethyl groups were respectively bonded to the N atoms of 3-aminopropyl functionalized mesoporous SBA-15(APS-SBA-15) to obtain two new base catalysts over which the condensation reaction of benzaldehyde and 2'-hydroxyacetophenone was studied. Good catalytic activities and high selectivities for flavanones were obtained in solvent-free reactions, which is attributed to the effect of benzyl and anthracenemetyl groups on the base sites of catalysts and the steric hindrance of futher reaction of flavanone with benzaldehyde.

关键词: APS-SBA-15, Flavanone, Bz-APS-SBA-15, An-APS-SBA-15

Abstract: Benzyl and anthracenemethyl groups were respectively bonded to the N atoms of 3-aminopropyl functionalized mesoporous SBA-15(APS-SBA-15) to obtain two new base catalysts over which the condensation reaction of benzaldehyde and 2'-hydroxyacetophenone was studied. Good catalytic activities and high selectivities for flavanones were obtained in solvent-free reactions, which is attributed to the effect of benzyl and anthracenemetyl groups on the base sites of catalysts and the steric hindrance of futher reaction of flavanone with benzaldehyde.

Key words: APS-SBA-15, Flavanone, Bz-APS-SBA-15, An-APS-SBA-15