Three New Polyoxometalates Derivatives Decorated by Phenanthroline and Transition-metal Cations(M=ZnII, CoII, NiII)

高等学校化学研究 ›› 2010, Vol. 26 ›› Issue (5): 683-686.

Three New Polyoxometalates Derivatives Decorated by Phenanthroline and Transition-metal Cations(M=ZnII, CoII, NiII)

ZHANG Yong-feng, JIA Yan-yan, NIE Hai-liang, YAN Xing-juan, WANG Li and HUANG Ru-dan*

Department of Chemistry, Beijing Institute of Technology, Beijing 100081, P. R. China

收稿日期:2009-10-29 修回日期:2010-03-09 出版日期:2010-09-25 发布日期:2010-11-26
通讯作者: HUANG Ru-dan. E-mail: huangrd@bit.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(Nos.20771013, 20476011 and 20371007).

Three New Polyoxometalates Derivatives Decorated by Phenanthroline and Transition-metal Cations(M=ZnII, CoII, NiII)

ZHANG Yong-feng, JIA Yan-yan, NIE Hai-liang, YAN Xing-juan, WANG Li and HUANG Ru-dan*

Department of Chemistry, Beijing Institute of Technology, Beijing 100081, P. R. China

Received:2009-10-29 Revised:2010-03-09 Online:2010-09-25 Published:2010-11-26
Contact: HUANG Ru-dan. E-mail: huangrd@bit.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.20771013, 20476011 and 20371007).

摘要/Abstract

摘要： Three new Keggin polyoxometalates, [Zn(phen)3]2[SiW12O40]·5H2O(1), [Co(phen)3]2[SiW12O40](2) and [Ni(phen)3]2[SiW12O40]·2H2O(3)(phen=1,10'-phenanthroline) have been hydrothermally synthesized and characterized by elemental analysis, IR, crystal X-ray diffraction, thermogravimetric analyses(TGA) and fluorescence techniques. Complex 1, crystallized in the triclinic space group P1??, consists of one [SiW12O40]4– anion, two discrete [Zn(phen)3]2+ cations and five crystal water molecules. Complexes 2 and 3 have the similar configuration to complex 1, but they crystallized in the monoclinic space group C2/c. Variable-temperature magnetic susceptibilities of complexess 2 and 3 reveal antiferromagnetism and ferromagnetism, respectively.

关键词: Polyoxometalate, Phen, Organic-inorganic compound, Hydrothermal synthesis

Abstract: Three new Keggin polyoxometalates, [Zn(phen)3]2[SiW12O40]·5H2O(1), [Co(phen)3]2[SiW12O40](2) and [Ni(phen)3]2[SiW12O40]·2H2O(3)(phen=1,10'-phenanthroline) have been hydrothermally synthesized and characterized by elemental analysis, IR, crystal X-ray diffraction, thermogravimetric analyses(TGA) and fluorescence techniques. Complex 1, crystallized in the triclinic space group P1??, consists of one [SiW12O40]4– anion, two discrete [Zn(phen)3]2+ cations and five crystal water molecules. Complexes 2 and 3 have the similar configuration to complex 1, but they crystallized in the monoclinic space group C2/c. Variable-temperature magnetic susceptibilities of complexess 2 and 3 reveal antiferromagnetism and ferromagnetism, respectively.

Key words: Polyoxometalate, Phen, Organic-inorganic compound, Hydrothermal synthesis

ZHANG Yong-feng, JIA Yan-yan, NIE Hai-liang, YAN Xing-juan, WANG Li and HUANG Ru. Three New Polyoxometalates Derivatives Decorated by Phenanthroline and Transition-metal Cations(M=ZnII, CoII, NiII)[J]. 高等学校化学研究, 2010, 26(5): 683-686.

ZHANG Yong-feng, JIA Yan-yan, NIE Hai-liang, YAN Xing-juan, WANG Li and HUANG Ru-dan*. Three New Polyoxometalates Derivatives Decorated by Phenanthroline and Transition-metal Cations(M=ZnII, CoII, NiII)[J]. Chemical Research in Chinese Universities, 2010, 26(5): 683-686.

参考文献

[1] Yaghi O. M., Li H., J. Am. Chem. Soc., 1996, 118, 295 [2] Hagrman D., Haushalter R. C., Zubieta J., Chem. Mater., 1998, 10, 361 [3] Cheetham A. K., Férey G., Loiseau T., Angew. Chem. Int. Ed., 1999, 38, 3268 [4] Peng Z. H., Angew. Chem. Int. Ed., 2004, 43, 930 [5] Hill C. L., Chem. Rev., 1998, 98, 1 [6] Ren Y. P., Kong X. J., Hu X. Y., Sun M., Long L. S., Huang R. B., Zheng L. S., Inorg. Chem., 2006, 45, 4016 [7] Niu J. Y., Wu Q., Wang J. P., J. Chem. Soc. Dalton Trans., 2002, 2512 [8] Lin Z. E., Zhang J., Zhao J. T., Zheng S. T., Pan C. Y., Wang G. M., Yang G. Y., Angew. Chem. Int. Ed., 2005, 44, 6881 [9] Sun Y. Q., Zhang J., Chen Y. M., Yang G. Y., Angew. Chem. Int. Ed., 2005, 44, 5814 [10] Zhang Z. M., Li Y. G., Wang Y. H., Qi Y. F., Wang E. B., Inorg. Chem., 2008, 47, 7615 [11] Bu X. H., Chen W., Du M., Biradha K., Wang W. Z., Zhang R. H., Inorg. Chem., 2002, 41, 437 [12] Hagrman P. J., Bridges C., Greedan J. E., Zubieta J., J. Chem. Soc. Dalton Trans., 1999, 2901 [13] Lu J., Shen E. H., Yuan M., Li Y. G., Wang E. B., Hu C. W., Xu L. Peng J., Inorg. Chem., 2003, 42, 6956 [14] Lu Y., Wang E. B., Yuan M., Luan G. Y., Li Y. G., Zhang H., Hu C. W., Yao Y. G., Qin Y. Y., Chen Y. B., J. Chem. Soc. Dalton Trans., 2002, 3029 [15] Sheldrick G. M., SHELXS 97, Program for Crystal Structure Solution, University of G?ttingen, G?ttingen, 1997 [16] Sheldrick G. M., SHELXL 97, Program for Crystal Structure Refinement, University of G?ttingen, G?ttingen, 1997 [17] Pope M. T., Müller A., Polyoxometalate Chemistry From Topology via Self-Assembly to Applications, Kluwer Academic Publishers, Dordrecht, 2001, 301 [18] Yu L. Q., Huang R. D., Xu Y. Q., Liu T. F., Chu W., Hu C. W., Inorganica Chimica Acta., 2008, 361, 2120 [19] King P., Clérac R., Wernsdorfer W., Anson C. E., Powell A. K., Dalton Trans, 2004, 2670 [20] Fondo M., Ocampo N., García-Deibe A. M., Vicente R., Corbella M., Bermejo M. R., Sanmartin J., Inorg. Chem., 2006, 45, 255 [21] Mbomekalle I. M., Keita B., Nierlich M., Kortzu U., Berthet P., Nadjo L., Inorg. Chem., 2003, 42, 5143

Three New Polyoxometalates Derivatives Decorated by Phenanthroline and Transition-metal Cations(M=ZnII, CoII, NiII)

Three New Polyoxometalates Derivatives Decorated by Phenanthroline and Transition-metal Cations(M=ZnII, CoII, NiII)

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