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高等学校化学研究 ›› 2006, Vol. 22 ›› Issue (5): 665-668.doi:

• Research Notes • 上一篇    下一篇

Design and Self-assembly of a Novel Tetranuclear Zinc(Ⅱ) Complex via Reaction of 1,3-Thiazolidine-2-thione(tzdtH) with Zn(NO3)2

WEI Xian-yin1, HUANG Ru-dan1, YU Li-qiong1, ZHU Qin-lei1, ZHANG Zhong-qiang2 and LIU Li-ping1   

    1. Department of Chemistry, School of Science, Beijing Institute of Technology, Beijing 100081, P. R. China;
    2. Department of Chemistry, Hengshui University, Hengshui 053000, P. R. China
  • 收稿日期:2005-12-26 修回日期:1900-01-01 出版日期:2006-09-25 发布日期:2006-09-25
  • 通讯作者: HUANG Ru-dan E-mail:huangrd@bit.edu.cn

Design and Self-assembly of a Novel Tetranuclear Zinc(Ⅱ) Complex via Reaction of 1,3-Thiazolidine-2-thione(tzdtH) with Zn(NO3)2

WEI Xian-yin1, HUANG Ru-dan1, YU Li-qiong1, ZHU Qin-lei1, ZHANG Zhong-qiang2 and LIU Li-ping1
   

    1. Department of Chemistry, School of Science, Beijing Institute of Technology, Beijing 100081, P. R. China;
    2. Department of Chemistry, Hengshui University, Hengshui 053000, P. R. China
  • Received:2005-12-26 Revised:1900-01-01 Online:2006-09-25 Published:2006-09-25
  • Contact: HUANG Ru-dan E-mail:huangrd@bit.edu.cn

Abstract:

In this study, 1,3-thiazolidine-2-thionate was chosen as the multifunctional coordination ligand on the basis of the considerations that it has exocyclic sulfur(Sexo) and endocyclic nitrogen(Nendo) donors that are at the meta position and allow tzdtH to form and support an isolated metal-ligand cluster in the coordination architecture. As a result, a blossomshaped tetranuclear zinc cluster [Zn4(μ4-O)(tzdt)6] was synthesized by the reaction of tzdtH with Zn(NO3)2 under a mild condition for the first time. It was characterized by means of IR spectrometry and elemental analyses. The crystal structure of [Zn4(μ4-O)(tzdt)6] was determined by X-ray diffraction(XRD).

Key words: Self assembly, Tetranuclear cluster, Zinc complex, Crystal structure