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高等学校化学研究 ›› 2006, Vol. 22 ›› Issue (3): 339-342.

• Articles • 上一篇    下一篇

Highly Selective Preparation of 3-and 6-Modified Mannose/Altrose Derivatives

LIU Xiao-hong1, XIE Dang1,2, CHENG Chang-mei1, WANG Xia-yu2, GUO Xiao-qiang1, ZHAO Yu-fen1   

  1. 1. Key Laboratory of Bioorganic Phosphorous Chemistry and Chemical Biology of Ministry of Education,Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China;

    2. Institute of Polymer Science and Engineering, Xiangtan University, Xiangtan 411105, P. R. China
  • 收稿日期:2005-03-22 出版日期:2006-06-24 发布日期:2011-08-06
  • 基金资助:

    Supported by the National Natural Science Foundation of China(No. 20272031).

Highly Selective Preparation of 3-and 6-Modified Mannose/Altrose Derivatives

LIU Xiao-hong1, XIE Dang1,2, CHENG Chang-mei1, WANG Xia-yu2, GUO Xiao-qiang1, ZHAO Yu-fen1   

  1. 1. Key Laboratory of Bioorganic Phosphorous Chemistry and Chemical Biology of Ministry of Education,Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China;

    2. Institute of Polymer Science and Engineering, Xiangtan University, Xiangtan 411105, P. R. China
  • Received:2005-03-22 Online:2006-06-24 Published:2011-08-06
  • Supported by:

    Supported by the National Natural Science Foundation of China(No. 20272031).

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摘要： A highly efficient method to get 3-and 6-modified mannose/altrose derivatives for oligosaccharide synthesis is described. All the compounds were obtained exclusively with the combinations of 3-and/or 6-hydroxyl protection and/or activation(including the configuration conversion of 3-carbon atom).

关键词: Mannose, Altrose, Selective protection, Selective deprotection

Abstract: A highly efficient method to get 3-and 6-modified mannose/altrose derivatives for oligosaccharide synthesis is described. All the compounds were obtained exclusively with the combinations of 3-and/or 6-hydroxyl protection and/or activation(including the configuration conversion of 3-carbon atom).

Key words: Mannose, Altrose, Selective protection, Selective deprotection