Syntheses of Novel 5-Alkylamido-1,10-phenanthrolines

高等学校化学研究 ›› 2004, Vol. 20 ›› Issue (2): 149-151.

Syntheses of Novel 5-Alkylamido-1,10-phenanthrolines

SHU Huo-ming, LI Hua-ming, HAN Chang-ri, WANG Peng

Department of Chemistry, Hainan Normal University, Haikou 571158, P. R. China

收稿日期:2003-12-05 出版日期:2004-04-24 发布日期:2011-08-06
基金资助:
Supported by the Natural Science Foundation of Hainan Province(No.80203).

Syntheses of Novel 5-Alkylamido-1,10-phenanthrolines

SHU Huo-ming, LI Hua-ming, HAN Chang-ri, WANG Peng

Department of Chemistry, Hainan Normal University, Haikou 571158, P. R. China

Received:2003-12-05 Online:2004-04-24 Published:2011-08-06
Supported by:
Supported by the Natural Science Foundation of Hainan Province(No.80203).

摘要/Abstract

摘要： 5-Amino-1, 10-phenanthroline and three types of new 5-substituted 1,10-phenanthroline derivatives by different alkyl amides, phen-NHCOR [phen = 1,10-phenanthroline;R＝CH＝CH₂;(CH₂)_nBr, n = 1,3-5;(CH₂)_nCH₃, n = 9-14], were synthesized. They were characterized by means of elemental analyses, infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, and mass spectroscopy. These new compounds are important ligands or the active materials of ruthenium (I) electrochemiluminescent (ECL) sensors.

关键词: 1, 10-Phenanthroline derivative, Synthesis, Characterization

Abstract: 5-Amino-1, 10-phenanthroline and three types of new 5-substituted 1,10-phenanthroline derivatives by different alkyl amides, phen-NHCOR [phen = 1,10-phenanthroline;R＝CH＝CH₂;(CH₂)_nBr, n = 1,3-5;(CH₂)_nCH₃, n = 9-14], were synthesized. They were characterized by means of elemental analyses, infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, and mass spectroscopy. These new compounds are important ligands or the active materials of ruthenium (I) electrochemiluminescent (ECL) sensors.

Key words: 1,10-Phenanthroline derivative, Synthesis, Characterization

SHU Huo-ming, LI Hua-ming, HAN Chang-ri, WANG Peng. Syntheses of Novel 5-Alkylamido-1,10-phenanthrolines[J]. 高等学校化学研究, 2004, 20(2): 149-151.

SHU Huo-ming, LI Hua-ming, HAN Chang-ri, WANG Peng. Syntheses of Novel 5-Alkylamido-1,10-phenanthrolines[J]. Chemical Research in Chinese Universities, 2004, 20(2): 149-151.

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Syntheses of Novel 5-Alkylamido-1,10-phenanthrolines

Syntheses of Novel 5-Alkylamido-1,10-phenanthrolines

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