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高等学校化学研究 ›› 2002, Vol. 18 ›› Issue (4): 405-408.

• Articles • 上一篇    下一篇

Synthesis, Structure and Characterization of a Novel Asymmetrical Half-sandwich Binuclear Iron Carborane Complex [η5-C5H3(t-Bu)2]2Fe2(CO)3Se2C2B10H10

LU Shi-xiang1,2, JIN Guo-xin1, HU Ning-hai1, JIA Heng-qing1   

  1. 1. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China;
    2. College of Chemistry, Jinlin University, Changchun 130023, P. R. China
  • 收稿日期:2001-05-08 出版日期:2002-12-24 发布日期:2011-08-04
  • 基金资助:

    Supported by the National Natural Science Foundation of China(No.29974029, 29925101) and Special Funds for Major State Basic Research Projects of China(G1999064800).

Synthesis, Structure and Characterization of a Novel Asymmetrical Half-sandwich Binuclear Iron Carborane Complex [η5-C5H3(t-Bu)2]2Fe2(CO)3Se2C2B10H10

LU Shi-xiang1,2, JIN Guo-xin1, HU Ning-hai1, JIA Heng-qing1   

  1. 1. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China;
    2. College of Chemistry, Jinlin University, Changchun 130023, P. R. China
  • Received:2001-05-08 Online:2002-12-24 Published:2011-08-04
  • Supported by:

    Supported by the National Natural Science Foundation of China(No.29974029, 29925101) and Special Funds for Major State Basic Research Projects of China(G1999064800).

PDF (PC)

摘要： Halfsandwich iron dicarbonyl complex [η5-C5H3(t-Bu)2]Fe(CO)2Cl(1) reacts with 1, 2-dilithium diseleno carborane Li2Se2C2B10H10(2) to give a binuclear iron carborane complex [η5-C5H3(t-Bu)2]2Fe2(CO)3·Se2C2B10H10(3). The X-ray diffraction analysis of complex 3 reveals that one of the iron atoms is chiral.

关键词: Carborane, Halfsandwich iron complex, Chirality, Molecular structure

Abstract: Halfsandwich iron dicarbonyl complex [η5-C5H3(t-Bu)2]Fe(CO)2Cl(1) reacts with 1, 2-dilithium diseleno carborane Li2Se2C2B10H10(2) to give a binuclear iron carborane complex [η5-C5H3(t-Bu)2]2Fe2(CO)3·Se2C2B10H10(3). The X-ray diffraction analysis of complex 3 reveals that one of the iron atoms is chiral.

Key words: Carborane, Halfsandwich iron complex, Chirality, Molecular structure