高等学校化学研究 ›› 2001, Vol. 17 ›› Issue (S1): 152-153.
A Novel Method for the Resolution of(±)-1,1'-Bi-2-naphthol and Synthesis of 2,2'-Unsyminetrically Substituted Chiral Binaphthyls
WANG Yong, CHEN An-Oi, YE Jian-Jun, RUN Yuan-Ping, ZHOU Zhao-Hui
- Department of Chemistry, Xiamen University, Xiamen, Fujian, China 361005
A Novel Method for the Resolution of(±)-1,1'-Bi-2-naphthol and Synthesis of 2,2'-Unsyminetrically Substituted Chiral Binaphthyls
WANG Yong, CHEN An-Oi, YE Jian-Jun, RUN Yuan-Ping, ZHOU Zhao-Hui
- Department of Chemistry, Xiamen University, Xiamen, Fujian, China 361005
摘要：
Enantiomerically pure 1,1'-bi-2-naphthol(BINOL)1 and its derivatives are important chiral ligands and auxiliaries for a number of asymmetric transformations1 such as aldol condensations,alkylations,Diels-Alder reactions,Michael additions,epoxidations,etc.